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Mechanism of Capacity Fading in the LiNi 0.8 Co 0.1 Mn 0.1 O 2 Cathode Material for Lithium-Ion Batteries

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  • Yong-keon Ahn

    (Department of Energy Engineering, Konkuk University, 120 Neungdong-ro, Gwangjin-gu, Seoul 05029, Korea
    These authors contributed equally to this work.)

  • Yong Nam Jo

    (Advanced Batteries Research Center, Korea Electronics Technology Institute, 25, Saenari-ro, Bundang-gu, Seongnam, Gyeonggi-do 13509, Korea
    These authors contributed equally to this work.)

  • Woosuk Cho

    (Advanced Batteries Research Center, Korea Electronics Technology Institute, 25, Saenari-ro, Bundang-gu, Seongnam, Gyeonggi-do 13509, Korea)

  • Ji-Sang Yu

    (Advanced Batteries Research Center, Korea Electronics Technology Institute, 25, Saenari-ro, Bundang-gu, Seongnam, Gyeonggi-do 13509, Korea)

  • Ki Jae Kim

    (Department of Energy Engineering, Konkuk University, 120 Neungdong-ro, Gwangjin-gu, Seoul 05029, Korea)

Abstract

Understanding the capacity fading mechanism of the LiNi 0.8 Co 0.1 Mn 0.1 O 2 (NCM811) cathode materials is crucial for achieving long-lasting lithium-ion batteries with high energy densities. In this study, we investigated the factors affecting the capacity fading of NCM811 during repeated cycling at high temperatures. We found that the change in the c-axis length during charging and discharging is the main cause of the formation and propagation of microcracks in the primary particles of NCM811. In addition, the electrolyte is decomposed on the microcrack surfaces and, consequently, by-products are formed on the particle surface, increasing the impedance and resulting in poor electronic and ionic connectivity between the primary particles of NCM811. In addition, the transition metals in the NCM811 cathode material are dissolved in the electrolyte from the newly formed microcrack surface between primary particles. Therefore, the electrolyte decomposition and transition metal dissolution on the newly formed surface are the major deteriorative effects behind the capacity fading in NCM811.

Suggested Citation

  • Yong-keon Ahn & Yong Nam Jo & Woosuk Cho & Ji-Sang Yu & Ki Jae Kim, 2019. "Mechanism of Capacity Fading in the LiNi 0.8 Co 0.1 Mn 0.1 O 2 Cathode Material for Lithium-Ion Batteries," Energies, MDPI, vol. 12(9), pages 1-10, April.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:9:p:1638-:d:227022
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    References listed on IDEAS

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    1. Darcovich, K. & Henquin, E.R. & Kenney, B. & Davidson, I.J. & Saldanha, N. & Beausoleil-Morrison, I., 2013. "Higher-capacity lithium ion battery chemistries for improved residential energy storage with micro-cogeneration," Applied Energy, Elsevier, vol. 111(C), pages 853-861.
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