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Mechanisms and kinetics of CO2 hydrogenation to value-added products: A detailed review on current status and future trends

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  • Saeidi, Samrand
  • Najari, Sara
  • Fazlollahi, Farhad
  • Nikoo, Maryam Khoshtinat
  • Sefidkon, Fatemeh
  • Klemeš, Jiří Jaromír
  • Baxter, Larry L.

Abstract

Global warming, fossil fuel depletion and energy security are driving scientists to investigate the mechanism of hydrocarbons production from CO2 hydrogenation. The need for more comprehensive understanding on mechanism of CO2 hydrogenation to hydrocarbons remains controversial because of the complex reaction mechanism and a large number of involved species. The micro mechanism of CO2 hydrogenation to hydrocarbons has been considered as a possible remedy to fulfill the requirements. This review comprehensively discusses two processes: reverse water gas shift (RWGS) and CO2 hydrogenation to hydrocarbons. The review includes reaction mechanisms and catalyst effects on yields and rates. In addition, the review outlines each of the Fischer-Tropsch (FT) micro mechanisms. The review infers some mechanisms from existing work and proposes a new mechanism that improves several predictions. These mechanisms form the design basis for optimal reactor design.

Suggested Citation

  • Saeidi, Samrand & Najari, Sara & Fazlollahi, Farhad & Nikoo, Maryam Khoshtinat & Sefidkon, Fatemeh & Klemeš, Jiří Jaromír & Baxter, Larry L., 2017. "Mechanisms and kinetics of CO2 hydrogenation to value-added products: A detailed review on current status and future trends," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 1292-1311.
  • Handle: RePEc:eee:rensus:v:80:y:2017:i:c:p:1292-1311
    DOI: 10.1016/j.rser.2017.05.204
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    2. Freire Ordóñez, Diego & Shah, Nilay & Guillén-Gosálbez, Gonzalo, 2021. "Economic and full environmental assessment of electrofuels via electrolysis and co-electrolysis considering externalities," Applied Energy, Elsevier, vol. 286(C).
    3. Pavel Tcvetkov, 2021. "Climate Policy Imbalance in the Energy Sector: Time to Focus on the Value of CO 2 Utilization," Energies, MDPI, vol. 14(2), pages 1-22, January.
    4. Shahbeik, Hossein & Peng, Wanxi & Kazemi Shariat Panahi, Hamed & Dehhaghi, Mona & Guillemin, Gilles J. & Fallahi, Alireza & Amiri, Hamid & Rehan, Mohammad & Raikwar, Deepak & Latine, Hannes & Pandalon, 2022. "Synthesis of liquid biofuels from biomass by hydrothermal gasification: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    5. Chen, Lingen & Zhang, Lei & Xia, Shaojun & Sun, Fengrui, 2018. "Entropy generation minimization for CO2 hydrogenation to light olefins," Energy, Elsevier, vol. 147(C), pages 187-196.
    6. Daniel Chuquin-Vasco & Francis Parra & Nelson Chuquin-Vasco & Juan Chuquin-Vasco & Vanesa Lo-Iacono-Ferreira, 2021. "Prediction of Methanol Production in a Carbon Dioxide Hydrogenation Plant Using Neural Networks," Energies, MDPI, vol. 14(13), pages 1-18, July.
    7. Lopes, J.V.M. & Bresciani, A.E. & Carvalho, K.M. & Kulay, L.A. & Alves, R.M.B., 2021. "Multi-criteria decision approach to select carbon dioxide and hydrogen sources as potential raw materials for the production of chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).

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