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Hydrogen by photocatalysis with nitrogen codoped titanium dioxide

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  • Samokhvalov, Alexander

Abstract

Titanium dioxide TiO2 remains a benchmark photocatalyst with high stability, low toxicity and cost, but it is active only under the UV light. To increase photocatalytic activity, TiO2 is “doped” with metals and nonmetals; nitrogen doped titania N-TiO2 has been extensively investigated since the early 2000s. In the recent decade, an increased attention has been paid to additional dopant aka “codopant” added to N-TiO2 to increase the photocatalytic rate. This focused critical Review covers the research on N-TiO2 codoped with an additional element for the photocatalytic hydrogen generation, namely: (1) mechanistic studies of charge separation aimed to understand and predict photocatalytic activity; (2) nonmetal codoped N-X-TiO2; (3) base metal codoped N-M-TiO2; (4) noble metal codoped N-M-TiO2. Suitability and limitations of experimental methods for characterization of codoped N-TiO2 are discussed. The following mechanisms of photocatalysis with codoped N-TiO2 are reviewed: (a) excitation of TiO2; (b) excitation of N dopant induced states; c) an increased electron-hole (e-h) separation; (d) lowering over potential of hydrogen reduction; (e) excitation of the surface plasmon resonance (SPR) in N-TiO2 codoped with nanoparticles (NPs) of noble metals. Temporal stability of codoped N-TiO2 in H2 generation and transformation pathways of sacrificial electron donors are discussed as well.

Suggested Citation

  • Samokhvalov, Alexander, 2017. "Hydrogen by photocatalysis with nitrogen codoped titanium dioxide," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 981-1000.
  • Handle: RePEc:eee:rensus:v:72:y:2017:i:c:p:981-1000
    DOI: 10.1016/j.rser.2017.01.024
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    References listed on IDEAS

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    1. Sharma, Sunita & Ghoshal, Sib Krishna, 2015. "Hydrogen the future transportation fuel: From production to applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1151-1158.
    2. Ni, Meng & Leung, Michael K.H. & Leung, Dennis Y.C. & Sumathy, K., 2007. "A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(3), pages 401-425, April.
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