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Dealing with the surplus of glycerol production from biodiesel industry through catalytic upgrading to polyglycerols and other value-added products

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  • Gholami, Zahra
  • Abdullah, Ahmad Zuhairi
  • Lee, Keat-Teong

Abstract

An increase in glycerol production is expected because of the increasing use of fuel additives such as methyl esters. This increase can enhance the importance of glycerol as a cheap raw material for producing value-added products. Future scenarios for worldwide glycerol market will mostly be related to the supply and demand of glycerol and its application in other industries. Much research have been developed and continuously investigated to convert low-value glycerol using different strategies and approaches. Due to the unique structure of glycerol, properties and renewability feature of it, new opportunities for the transformation of glycerol into high-valued chemicals have merged in recent years. This paper provides a review on glycerol, global market of glycerol and conversion of glycerol to value-added products. Catalytic etherification of glycerol to value-added products such as polyglycerols is particularly reviewed.

Suggested Citation

  • Gholami, Zahra & Abdullah, Ahmad Zuhairi & Lee, Keat-Teong, 2014. "Dealing with the surplus of glycerol production from biodiesel industry through catalytic upgrading to polyglycerols and other value-added products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 39(C), pages 327-341.
    • Handle: RePEc:eee:rensus:v:39:y:2014:i:c:p:327-341
    DOI: 10.1016/j.rser.2014.07.092
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    Cited by:

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    2. Okoye, Patrick U. & Wang, Song & Khanday, Waheed Ahmad & Li, Sanxi & Tang, Tao & Zhang, Linnan, 2020. "Box-Behnken optimization of glycerol transesterification reaction to glycerol carbonate over calcined oil palm fuel ash derived catalyst," Renewable Energy, Elsevier, vol. 146(C), pages 2676-2687.
    3. He, Quan (Sophia) & McNutt, Josiah & Yang, Jie, 2017. "Utilization of the residual glycerol from biodiesel production for renewable energy generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 63-76.
    4. Jinling Wang & Xingchao Dai & Hualin Wang & Honglai Liu & Jabor Rabeah & Angelika Brückner & Feng Shi & Ming Gong & Xuejing Yang, 2021. "Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    5. Okoye, P.U. & Hameed, B.H., 2016. "Review on recent progress in catalytic carboxylation and acetylation of glycerol as a byproduct of biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 558-574.
    6. Jia, Guangxin & He, Beibei & Ma, Wenlin & Sun, Yifan, 2019. "Thermodynamic analysis based on simultaneous chemical and phase equilibrium for dehydration of glycerol with methanol," Energy, Elsevier, vol. 188(C).
    7. Budzianowski, Wojciech M., 2017. "High-value low-volume bioproducts coupled to bioenergies with potential to enhance business development of sustainable biorefineries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 793-804.
    8. Hejna, Aleksander & Kosmela, Paulina & Formela, Krzysztof & Piszczyk, Łukasz & Haponiuk, Józef T., 2016. "Potential applications of crude glycerol in polymer technology–Current state and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 66(C), pages 449-475.
    9. Lapuerta, Magín & Rodríguez-Fernández, José & García-Contreras, Reyes, 2015. "Effect of a glycerol-derived advanced biofuel –FAGE (fatty acid formal glycerol ester)– on the emissions of a diesel engine tested under the New European Driving Cycle," Energy, Elsevier, vol. 93(P1), pages 568-579.
    10. Monteiro, Marcos Roberto & Kugelmeier, Cristie Luis & Pinheiro, Rafael Sanaiotte & Batalha, Mario Otávio & da Silva César, Aldara, 2018. "Glycerol from biodiesel production: Technological paths for sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 109-122.
    11. Lam, Su Shiung & Liew, Rock Keey & Jusoh, Ahmad & Chong, Cheng Tung & Ani, Farid Nasir & Chase, Howard A., 2016. "Progress in waste oil to sustainable energy, with emphasis on pyrolysis techniques," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 741-753.

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