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Hunting sustainable refrigerants fulfilling technical, environmental, safety and economic requirements

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  • Albà, C.G.
  • Alkhatib, I.I.I.
  • Llovell, F.
  • Vega, L.F.

Abstract

An urgent action to mitigate climate change is the replacement of hydrofluorocarbons used in refrigeration systems, for low-global warming potential (GWP) alternatives, with stringent legislations in place. However, very limited options exist for single-component low-GWP refrigerants with similar technical performance. This work presents an integrated approach for the rational design of low-GWP refrigerant blends, focused on replacing R134a (GWP 1430), and R410A (GWP 2088), used in automotive and domestic air-conditioning, and in high pressure commercial and industrial refrigeration, respectively. A 4 E analysis (energy, exergy, economic and environmental) was employed to select suitable candidates. The molecular polar soft-SAFT theory was used in a predictive manner to fill the gap in thermodynamic data required for evaluating the technical performance based on initial selection criteria including GWP, toxicity, flammability, and degree of azeotropy. Potential candidates from a pool of 432 options were narrowed down and evaluated using a drop-in analysis to replace the working fluids R134a and R410A in today's refrigeration and air conditioning cycles, resulting in seven promising blends. Environmental and cost rate evaluation (geographically dependent based on electricity cost, HFC utilization taxes, and carbon emission factors) quantified the impact associated with their use and emissions, allowing to identify suitable replacements: three blends for replacing R134a: (90/10) wt.% R1243yf + R152a, (90/10) wt.% R1243yf + R134a, and (60/40) wt.% R1243zf + R1234ze(E), and one for replacing R410A: (90/10) wt.% R1123 + R32. This work showcases the importance of using robust thermodynamic models in the search of low-GWP refrigerants blends, considering the 4 E criteria.

Suggested Citation

  • Albà, C.G. & Alkhatib, I.I.I. & Llovell, F. & Vega, L.F., 2023. "Hunting sustainable refrigerants fulfilling technical, environmental, safety and economic requirements," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).
    • Handle: RePEc:eee:rensus:v:188:y:2023:i:c:s1364032123006639
    DOI: 10.1016/j.rser.2023.113806
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    as
    1. Giménez-Prades, P. & Navarro-Esbrí, J. & Arpagaus, C. & Fernández-Moreno, A. & Mota-Babiloni, A., 2022. "Novel molecules as working fluids for refrigeration, heat pump and organic Rankine cycle systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    2. Luo, Dong & Mahmoud, Ahmad & Cogswell, Frederick, 2015. "Evaluation of Low-GWP fluids for power generation with Organic Rankine Cycle," Energy, Elsevier, vol. 85(C), pages 481-488.
    3. Mota-Babiloni, Adrián & Navarro-Esbrí, Joaquín & Barragán-Cervera, Ángel & Molés, Francisco & Peris, Bernardo, 2015. "Drop-in analysis of an internal heat exchanger in a vapour compression system using R1234ze(E) and R450A as alternatives for R134a," Energy, Elsevier, vol. 90(P2), pages 1636-1644.
    4. Arpagaus, Cordin & Bless, Frédéric & Uhlmann, Michael & Schiffmann, Jürg & Bertsch, Stefan S., 2018. "High temperature heat pumps: Market overview, state of the art, research status, refrigerants, and application potentials," Energy, Elsevier, vol. 152(C), pages 985-1010.
    5. Makhnatch, Pavel & Mota-Babiloni, Adrián & López-Belchí, Alejandro & Khodabandeh, Rahmatollah, 2019. "R450A and R513A as lower GWP mixtures for high ambient temperature countries: Experimental comparison with R134a," Energy, Elsevier, vol. 166(C), pages 223-235.
    6. Harby, K., 2017. "Hydrocarbons and their mixtures as alternatives to environmental unfriendly halogenated refrigerants: An updated overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 1247-1264.
    7. Lars T. Ruig & Toon Haer & Hans Moel & Samuel D. Brody & W. J. Wouter Botzen & Jeffrey Czajkowski & Jeroen C. J. H. Aerts, 2022. "Climate-proofing the National Flood Insurance Program," Nature Climate Change, Nature, vol. 12(11), pages 975-976, November.
    8. Abas, Naeem & Kalair, Ali Raza & Khan, Nasrullah & Haider, Aun & Saleem, Zahid & Saleem, Muhammad Shoaib, 2018. "Natural and synthetic refrigerants, global warming: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 557-569.
    9. Mota-Babiloni, Adrián & Navarro-Esbrí, Joaquín & Makhnatch, Pavel & Molés, Francisco, 2017. "Refrigerant R32 as lower GWP working fluid in residential air conditioning systems in Europe and the USA," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 1031-1042.
    10. Wu, Di & Hu, Bin & Wang, R.Z., 2021. "Vapor compression heat pumps with pure Low-GWP refrigerants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    11. Richard S. J. Tol, 2023. "Costs And Benefits Of The Paris Climate Targets," Climate Change Economics (CCE), World Scientific Publishing Co. Pte. Ltd., vol. 14(04), pages 1-18, November.
    12. Ahamed, J.U. & Saidur, R. & Masjuki, H.H., 2011. "A review on exergy analysis of vapor compression refrigeration system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(3), pages 1593-1600, April.
    13. Bolaji, B.O. & Huan, Z., 2013. "Ozone depletion and global warming: Case for the use of natural refrigerant – a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 49-54.
    14. Ryan L. Li & Joshua H. P. Studholme & Alexey V. Fedorov & Trude Storelvmo, 2022. "Precipitation efficiency constraint on climate change," Nature Climate Change, Nature, vol. 12(7), pages 642-648, July.
    15. Mark O. McLinden & J. Steven Brown & Riccardo Brignoli & Andrei F. Kazakov & Piotr A. Domanski, 2017. "Limited options for low-global-warming-potential refrigerants," Nature Communications, Nature, vol. 8(1), pages 1-9, April.
    16. Kasaeian, Alibakhsh & Hosseini, Seyed Mohsen & Sheikhpour, Mojgan & Mahian, Omid & Yan, Wei-Mon & Wongwises, Somchai, 2018. "Applications of eco-friendly refrigerants and nanorefrigerants: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 96(C), pages 91-99.
    17. Ocde, 2022. "L'éducation à l'action climatique," L'enseignement à la loupe 44, OECD Publishing.
    18. Katherine R. H. Wagner, 2022. "Designing insurance for climate change," Nature Climate Change, Nature, vol. 12(12), pages 1070-1072, December.
    19. Mota-Babiloni, Adrián & Belman-Flores, J.M. & Makhnatch, Pavel & Navarro-Esbrí, Joaquín & Barroso-Maldonado, J.M., 2018. "Experimental exergy analysis of R513A to replace R134a in a small capacity refrigeration system," Energy, Elsevier, vol. 162(C), pages 99-110.
    20. ., 2022. "Climate change," Chapters, in: Rethinking Agricultural and Food Policy, chapter 7, pages 119-136, Edward Elgar Publishing.
    21. Sovacool, Benjamin K. & Griffiths, Steve & Kim, Jinsoo & Bazilian, Morgan, 2021. "Climate change and industrial F-gases: A critical and systematic review of developments, sociotechnical systems and policy options for reducing synthetic greenhouse gas emissions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    22. Qin, Yanbin & Li, Nanxi & Zhang, Hua & Liu, Baolin, 2021. "Energy and exergy analysis of a Linde-Hampson refrigeration system using R170, R41 and R1132a as low-GWP refrigerant blend components to replace R23," Energy, Elsevier, vol. 229(C).
    23. Adamson, Keri-Marie & Walmsley, Timothy Gordon & Carson, James K. & Chen, Qun & Schlosser, Florian & Kong, Lana & Cleland, Donald John, 2022. "High-temperature and transcritical heat pump cycles and advancements: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
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