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Biodiesel with low temperature properties: Enzymatic synthesis of fusel alcohol fatty acid ester in a solvent free system

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  • Wang, Meng
  • Nie, Kaili
  • Yun, Feng
  • Cao, Hao
  • Deng, Li
  • Wang, Fang
  • Tan, Tianwei

Abstract

Poor low temperature behavior, the critical defect of biodiesel, limits its utilization in cold districts. This research provided a new biodiesel production process by enzymatic synthesis using fusel alcohol and fatty acid esters in a solvent free system with a significant effect on the improvement of biodiesel's low temperature performance. The optimal conditions for the enzymatic reaction of fusel alcohol and waste cooking oil (WCO) esters were established: immobilized lipase 14% (w/w), total water content 5% (w/w), 40 °C, three-times feeding daily, shaking speed 200 rpm. The ester yield reached 90.4% under optimal conditions. The cold filter plugging point (CFPP) of the fusel alcohol esters was −11 °C, 16 °C lower than the methyl esters of the WCO. The green enzymatic synthesis process and the CFPP results were examined in this research.

Suggested Citation

  • Wang, Meng & Nie, Kaili & Yun, Feng & Cao, Hao & Deng, Li & Wang, Fang & Tan, Tianwei, 2015. "Biodiesel with low temperature properties: Enzymatic synthesis of fusel alcohol fatty acid ester in a solvent free system," Renewable Energy, Elsevier, vol. 83(C), pages 1020-1025.
    • Handle: RePEc:eee:renene:v:83:y:2015:i:c:p:1020-1025
    DOI: 10.1016/j.renene.2015.05.058
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    10. Mohd Noor, C.W. & Noor, M.M. & Mamat, R., 2018. "Biodiesel as alternative fuel for marine diesel engine applications: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 127-142.
    11. Lam, Man Kee & Yusoff, Mohammad Iqram & Uemura, Yoshimitsu & Lim, Jun Wei & Khoo, Choon Gek & Lee, Keat Teong & Ong, Hwai Chyuan, 2017. "Cultivation of Chlorella vulgaris using nutrients source from domestic wastewater for biodiesel production: Growth condition and kinetic studies," Renewable Energy, Elsevier, vol. 103(C), pages 197-207.
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