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Comparison of biodiesel production from crude Jatropha oil and Krating oil by supercritical methanol transesterification

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  • Samniang, Amonrat
  • Tipachan, Chuenkhuan
  • Kajorncheappun-ngam, Somjai

Abstract

This work compared the production of biodiesel from two different non-edible oils with relatively high acid values (Jatropha oil and Krating oil). Using non-catalytic supercritical methanol transesterification, high methyl ester yield (85–90%) can be obtained in a very short time (5–10min). However, the dependence of fatty acid methyl ester yield on reaction conditions (i.e., temperature and pressure) and the optimum conditions were different by the source of oils and were correlated to the amount of free fatty acids (FFAs) and unsaturated fatty acid content in oils. Krating oil, which has higher FFAs and unsaturated fatty acid content, gave higher fatty acid methyl ester yield of 90.4% at 260°C, 16MPa, and 10min whereas biodiesel from Jatropha oil gave fatty acid methyl ester yield of 84.6% at 320°C, 15MPa and 5min using the same molar ratio of methanol to oil 40:1. The product quality from crude Krating oil met the biodiesel standard. Pre-processing steps such as degumming or oil purification are not necessary.

Suggested Citation

  • Samniang, Amonrat & Tipachan, Chuenkhuan & Kajorncheappun-ngam, Somjai, 2014. "Comparison of biodiesel production from crude Jatropha oil and Krating oil by supercritical methanol transesterification," Renewable Energy, Elsevier, vol. 68(C), pages 351-355.
    • Handle: RePEc:eee:renene:v:68:y:2014:i:c:p:351-355
    DOI: 10.1016/j.renene.2014.01.039
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    References listed on IDEAS

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    1. Marchetti, J.M. & Miguel, V.U. & Errazu, A.F., 2007. "Possible methods for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(6), pages 1300-1311, August.
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    1. Xiang, Cheng & Liu, Si Yu & Fu, Yan & Chang, Jie, 2019. "A quick method for producing biodiesel from soy sauce residue under supercritical carbon dioxide," Renewable Energy, Elsevier, vol. 134(C), pages 739-744.
    2. Román-Figueroa, Celián & Olivares-Carrillo, Pilar & Paneque, Manuel & Palacios-Nereo, Francisco Javier & Quesada-Medina, Joaquín, 2016. "High-yield production of biodiesel by non-catalytic supercritical methanol transesterification of crude castor oil (Ricinus communis)," Energy, Elsevier, vol. 107(C), pages 165-171.
    3. Vigneshwar, V. & Krishnan, S. Yogesh & Kishna, R. Susanth & Srinath, R. & Ashok, B. & Nanthagopal, K., 2019. "Comprehensive review of Calophyllum inophyllum as a feasible alternate energy for CI engine applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 115(C).
    4. Andreo-Martínez, Pedro & Ortiz-Martínez, Víctor Manuel & García-Martínez, Nuria & de los Ríos, Antonia Pérez & Hernández-Fernández, Francisco José & Quesada-Medina, Joaquín, 2020. "Production of biodiesel under supercritical conditions: State of the art and bibliometric analysis," Applied Energy, Elsevier, vol. 264(C).

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