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Electrocatalytic activity of Pt–Pd electrocatalysts for the oxygen reduction reaction in proton exchange membrane fuel cells: Effect of supports

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  • Limpattayanate, Siripong
  • Hunsom, Mali

Abstract

Pt–Pd electrocatalysts supported on different types of support including domestic Hicon Black (HB), multi-walled carbon nanotubes (MWCNT) and titania (TiO2) were prepared by a combined approach of impregnation and seeding, and compared to that prepared using the commercial Vulcan XC-72 (C). Their oxygen reduction reaction (ORR) activities in an acid electrolyte (0.5 M H2SO4) and in a single proton exchange membrane (PEM) fuel cell were evaluated. The type of support was found to affect the Pt–Pd electrocatalyst morphology and ORR activity. The Pt–Pd/C electrocatalyst had the smallest Pt particle size, better catalyst dispersion and a higher Pt:Pd M ratio compared to that of other types of supported Pt–Pd electrocatalysts. However, both in the acid solution and in a single PEM fuel cell, the ORR activities of the Pt–Pd/HB and Pt–Pd/CNT electrocatalysts were comparable to that of the Pt–Pd/C one. The ORR pathway of all supported Pt–Pd electrocatalysts were close to the four-electron pathway.

Suggested Citation

  • Limpattayanate, Siripong & Hunsom, Mali, 2014. "Electrocatalytic activity of Pt–Pd electrocatalysts for the oxygen reduction reaction in proton exchange membrane fuel cells: Effect of supports," Renewable Energy, Elsevier, vol. 63(C), pages 205-211.
    • Handle: RePEc:eee:renene:v:63:y:2014:i:c:p:205-211
    DOI: 10.1016/j.renene.2013.09.014
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    References listed on IDEAS

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    1. Trongchuankij, Wiruyn & Poochinda, Kunakorn & Pruksathorn, Kejvalee & Hunsom, Mali, 2010. "A study on novel combined processes for preparation of high performance Pt–Co/C electrocatalyst for oxygen reduction in PEM fuel cell," Renewable Energy, Elsevier, vol. 35(12), pages 2839-2843.
    2. Guangli Che & Brinda B. Lakshmi & Ellen R. Fisher & Charles R. Martin, 1998. "Carbon nanotubule membranes for electrochemical energy storage and production," Nature, Nature, vol. 393(6683), pages 346-349, May.
    3. Trongchuankij, Wiruyn & Pruksathorn, Kejvalee & Hunsom, Mali, 2011. "Preparation of a high performance Pt-Co/C electrocatalyst for oxygen reduction in PEM fuel cell via a combined process of impregnation and seeding," Applied Energy, Elsevier, vol. 88(3), pages 974-980, March.
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    Cited by:

    1. Shiva Kumar, S. & Himabindu, V., 2020. "Boron-Doped Carbon nanoparticles supported palladium as an efficient hydrogen evolution electrode in PEM water electrolysis," Renewable Energy, Elsevier, vol. 146(C), pages 2281-2290.

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