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Alkaline tetrahydrofurfuryl alcohol pretreatment technology to achieve value-added co-liquefaction of biomass

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  • Wu, Haijun
  • Wang, Biao
  • Geng, Fanhui
  • Zhang, Kai
  • Lv, Quanwei
  • Xu, Jian

Abstract

Although it is promising to convert biomass into high yield/high quality bio-oil through hydrothermal liquefaction (HTL), it still faces many challenges. Hence, a novel approach was proposed here to improve the yield and quality of bio-oil. The effect of alkaline tetrahydrofurfuryl alcohol (ATA) pretreatment on the preparation of bio-oil from walnut shell (WS) adopting isopropanol/water co-liquefaction was studied. By optimizing the concentration of pretreatment alkali, the ratio of liquefied solvent, reaction temperature and residence time, the results indicated that a 50/50 co-solvent ratio had the best liquefaction effect. Under conditions of 280 °C, 30 min, and 1%-ATA, the maximum yield and energy recovery rate (ERR) of total bio-oil were 62.76 % and 34.07 %, respectively. Various high-sensitivity characterization techniques were used to analyze the physicochemical properties of WS pretreatment and liquefaction products, confirming that ATA pretreatment effectively breaks the structural barrier of WS and promotes its conversion to bio-oil.

Suggested Citation

  • Wu, Haijun & Wang, Biao & Geng, Fanhui & Zhang, Kai & Lv, Quanwei & Xu, Jian, 2025. "Alkaline tetrahydrofurfuryl alcohol pretreatment technology to achieve value-added co-liquefaction of biomass," Renewable Energy, Elsevier, vol. 239(C).
    • Handle: RePEc:eee:renene:v:239:y:2025:i:c:s0960148124021657
    DOI: 10.1016/j.renene.2024.122097
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    References listed on IDEAS

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    1. Kumar, Mayank & Olajire Oyedun, Adetoyese & Kumar, Amit, 2018. "A review on the current status of various hydrothermal technologies on biomass feedstock," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 1742-1770.
    2. Wu, Haijun & Li, Xinlong & Zhang, Quan & Zhang, Kai & Xu, Xia & Xu, Jian, 2022. "Promoting the conversion of poplar to bio-oil based on the synergistic effect of alkaline hydrogen peroxide," Renewable Energy, Elsevier, vol. 192(C), pages 107-117.
    3. Tyagi, Vinay Kumar & Lo, Shang-Lien, 2013. "Sludge: A waste or renewable source for energy and resources recovery?," Renewable and Sustainable Energy Reviews, Elsevier, vol. 25(C), pages 708-728.
    4. Hu, Yulin & Gong, Mengyue & Feng, Shanghuan & Xu, Chunbao (Charles) & Bassi, Amarjeet, 2019. "A review of recent developments of pre-treatment technologies and hydrothermal liquefaction of microalgae for bio-crude oil production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 476-492.
    5. Kaur, Ravneet & Gera, Poonam & Jha, Mithilesh Kumar & Bhaskar, Thallada, 2019. "Reaction parameters effect on hydrothermal liquefaction of castor (Ricinus Communis) residue for energy and valuable hydrocarbons recovery," Renewable Energy, Elsevier, vol. 141(C), pages 1026-1041.
    6. Tan, Minghui & Ma, Liang & Rehman, Muhamamd Saif Ur & Ahmed, Muhammad Ajaz & Sajid, Muhammad & Xu, Xia & Sun, Yong & Cui, Ping & Xu, Jian, 2019. "Screening of acidic and alkaline pretreatments for walnut shell and corn stover biorefining using two way heterogeneity evaluation," Renewable Energy, Elsevier, vol. 132(C), pages 950-958.
    7. Yan, Mi & Liu, Yu & Wen, Xiaoqiang & Yang, Yayong & Cui, Jintao & Chen, Feng & Hantoko, Dwi, 2023. "Effect of operating conditions on hydrothermal liquefaction of kitchen waste with ethanol-water as a co-solvent for bio-oil production," Renewable Energy, Elsevier, vol. 215(C).
    8. Haijun Wu & Usama Shakeel & Quan Zhang & Kai Zhang & Xia Xu & Jian Xu, 2022. "Ethanol-Assisted Hydrothermal Liquefaction of Poplar Using Fe-Co/Al 2 O 3 as Catalyst," Energies, MDPI, vol. 15(9), pages 1-16, April.
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