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Kinetic and thermodynamic studies of biomass pseudo-components under thermo-oxidative degradation conditions using asymmetric function of Bi-Gaussian as deconvolution technique

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Listed:
  • Li, Weizhen
  • Huang, Yanqin
  • Liu, Huacai
  • Zhang, Yan
  • Jiang, Yang
  • Wang, Yan
  • Wan, Junfeng
  • Yin, Xiuli

Abstract

This work aimed at investigating the kinetic and thermodynamic characteristics of components of pine sawdust (PS), edible fungi spent substrate (FVSS) and their blend during thermo-oxidative degradation. The novelty focused on applying deconvolution technique to distinguish an overlapped peak into three individual peaks corresponding to pseudo-hemicellulose, pseudo-cellulose and pseudo-lignin, respectively. Particularly, the function of Bi-Gaussian was employed to capture the asymmetric reaction shapes. Mass loss was recorded using a thermal analyzer at heating rates of 10, 20 and 30 K min−1 in air atmosphere. Methods of Starink and master-plots were used for estimating kinetic triplet. The average activation energies of FVSS are lower than PS, with an order of pseudo-lignin > pseudo-hemicellulose > pseudo-cellulose corresponding to the ranges of 211.70–342.78, 139.00–172.53 and 128.08–146.99 kJ mol−1, respectively. The pre-exponential factor are all higher than E+10 s−1 demonstrating some simple complex chemical reactions occurred. Models of D2 and A1 dominate the degradation of pseudo-hemicellulose and pseudo-cellulose, respectively, in PS and the blend. The average values of ΔS, ΔH and ΔG are −51.62-146.31 J mol−1, 122.99–335 kJ mol−1 and 78 144.87–216.59 kJ mol−1, showing the non-spontaneous process and need energy to maintain.

Suggested Citation

  • Li, Weizhen & Huang, Yanqin & Liu, Huacai & Zhang, Yan & Jiang, Yang & Wang, Yan & Wan, Junfeng & Yin, Xiuli, 2022. "Kinetic and thermodynamic studies of biomass pseudo-components under thermo-oxidative degradation conditions using asymmetric function of Bi-Gaussian as deconvolution technique," Renewable Energy, Elsevier, vol. 188(C), pages 491-503.
  • Handle: RePEc:eee:renene:v:188:y:2022:i:c:p:491-503
    DOI: 10.1016/j.renene.2022.02.024
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    References listed on IDEAS

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    1. Van de Velden, Manon & Baeyens, Jan & Brems, Anke & Janssens, Bart & Dewil, Raf, 2010. "Fundamentals, kinetics and endothermicity of the biomass pyrolysis reaction," Renewable Energy, Elsevier, vol. 35(1), pages 232-242.
    2. Azargohar, Ramin & Nanda, Sonil & Kang, Kang & Bond, Toby & Karunakaran, Chithra & Dalai, Ajay K. & Kozinski, Janusz A., 2019. "Effects of bio-additives on the physicochemical properties and mechanical behavior of canola hull fuel pellets," Renewable Energy, Elsevier, vol. 132(C), pages 296-307.
    3. Brems, Anke & Baeyens, Jan & Beerlandt, Johan & Dewil, Raf, 2011. "Thermogravimetric pyrolysis of waste polyethylene-terephthalate and polystyrene: A critical assessment of kinetics modelling," Resources, Conservation & Recycling, Elsevier, vol. 55(8), pages 772-781.
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    1. Xie, Wen & Su, Jing & Zhang, Xiangkun & Li, Tan & Wang, Cong & Yuan, Xiangzhou & Wang, Kaige, 2023. "Investigating kinetic behavior and reaction mechanism on autothermal pyrolysis of polyethylene plastic," Energy, Elsevier, vol. 269(C).

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