IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v182y2022icp713-724.html
   My bibliography  Save this article

Cu–Mn–O nano-particle/nano-sheet spinel-type materials as catalysts in methanol steam reforming (MSR) and preferential oxidation (PROX) reaction for purified hydrogen production

Author

Listed:
  • Dasireddy, Venkata D.B.C.
  • Likozar, Blaž

Abstract

Nanocomposite Cu–Mn–O nano-particle (CuMnNP) and nano-sheet (CuMnNS) catalyst were successfully prepared using a one-step hydrothermal method in the absence of any templating reagent. Materials were characterised applying various structural techniques. SEM images showed that composite Cu–Mn oxide sheets were tailor-made synthesised by a one-pot urea-abetted protocol. Conversely, upon replacing carbamate by Na2CO3, oxidised metal Cu–Mn particles could be obtained. The formation of bulk mixed Cu–Mn phases resulted in an enhanced crystal lattice oxygen reactivity in CuMnNS. XPS, XRD and TPR measurements confirmed the presence of the Cu+ and Cu2+ species in nano-catalysts, and CuMnNS nanomaterials possessed more surface defects, thus causing a higher O2 adsorption/storage capacity. CuMnNS presented a superior catalytic activity as opposed to CuMnNP in the preferential oxidation (PROX) pathway of CO. With both CO2 and H2O in feed, a decrease in CO turnover was observed, due to a competitive interface binding of CO, CO2 and H2O. Compared to CuMnNP, CuMnNS also demonstrated a high time-on-stream conversion of methanol for the reforming for all operating conditions.

Suggested Citation

  • Dasireddy, Venkata D.B.C. & Likozar, Blaž, 2022. "Cu–Mn–O nano-particle/nano-sheet spinel-type materials as catalysts in methanol steam reforming (MSR) and preferential oxidation (PROX) reaction for purified hydrogen production," Renewable Energy, Elsevier, vol. 182(C), pages 713-724.
  • Handle: RePEc:eee:renene:v:182:y:2022:i:c:p:713-724
    DOI: 10.1016/j.renene.2021.10.033
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148121014907
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.renene.2021.10.033?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Mohamed, Ziyaad & Dasireddy, Venkata D.B.C. & Singh, Sooboo & Friedrich, Holger B., 2020. "Comparative studies for CO oxidation and hydrogenation over supported Pt catalysts prepared by different synthesis methods," Renewable Energy, Elsevier, vol. 148(C), pages 1041-1053.
    2. Kaur, Gurpreet & Divya, & Khan, Saif A. & Satsangi, Vibha R. & Dass, Sahab & Shrivastav, Rohit, 2021. "Nano-hetero-structured thin films, ZnO/Ag-(α)Fe2O3, with n/n junction, as efficient photoanode for renewable hydrogen generation via photoelectrochemical water splitting," Renewable Energy, Elsevier, vol. 164(C), pages 156-170.
    3. Dasireddy, Venkata D.B.C. & Valand, Jignesh & Likozar, Blaž, 2018. "PROX reaction of CO in H2/H2O/CO2 Water–Gas Shift (WGS) feedstocks over Cu–Mn/Al2O3 and Cu–Ni/Al2O3 catalysts for fuel cell applications," Renewable Energy, Elsevier, vol. 116(PA), pages 75-87.
    4. Kai Man Kerry Yu & Weiyi Tong & Adam West & Kevin Cheung & Tong Li & George Smith & Yanglong Guo & Shik Chi Edman Tsang, 2012. "Non-syngas direct steam reforming of methanol to hydrogen and carbon dioxide at low temperature," Nature Communications, Nature, vol. 3(1), pages 1-7, January.
    5. Bhandari, Ramchandra & Shah, Ronak Rakesh, 2021. "Hydrogen as energy carrier: Techno-economic assessment of decentralized hydrogen production in Germany," Renewable Energy, Elsevier, vol. 177(C), pages 915-931.
    6. Zhong, Jin & Bollen, Math & Rönnberg, Sarah, 2021. "Towards a 100% renewable energy electricity generation system in Sweden," Renewable Energy, Elsevier, vol. 171(C), pages 812-824.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wang, Yadong & Yu, Haoran & Hu, Qing & Huang, Yanpeng & Wang, Ximing & Wang, Yuanhao & Wang, Fenghuan, 2023. "Application of microimpinging stream reactor coupled with ultrasound in Cu/CeZrOx solid solution catalyst preparation for CO2 hydrogenation to methanol," Renewable Energy, Elsevier, vol. 202(C), pages 834-843.
    2. Dasireddy, Venkata D.B.C. & Likozar, Blaž, 2022. "Photocatalytic CO2 reduction to methanol over bismuth promoted BaTiO3 perovskite nanoparticle catalysts," Renewable Energy, Elsevier, vol. 195(C), pages 885-895.
    3. Tang, Xincheng & Wu, Yanxiao & Fang, Zhenchang & Dong, Xinyu & Du, Zhongxuan & Deng, Bicai & Sun, Chunhua & Zhou, Feng & Qiao, Xinqi & Li, Xinling, 2024. "Syntheses, catalytic performances and DFT investigations: A recent review of copper-based catalysts of methanol steam reforming for hydrogen production," Energy, Elsevier, vol. 295(C).
    4. Tang, Xincheng & Fang, Zhenchang & Wu, Yanxiao & Yuan, Zhuoer & Deng, Bicai & Du, Zhongxuan & Sun, Chunhua & Zhou, Feng & Qiao, Xinqi & Li, Xinling, 2024. "Efficiency NiCu/t-zirconia catalysts for methanol steam reforming: Experimental and DFT insights," Energy, Elsevier, vol. 297(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Belessiotis, George V. & Kontos, Athanassios G., 2022. "Plasmonic silver (Ag)-based photocatalysts for H2 production and CO2 conversion: Review, analysis and perspectives," Renewable Energy, Elsevier, vol. 195(C), pages 497-515.
    2. Danieli, Piero & Carraro, Gianluca & Volpato, Gabriele & Cin, Enrico Dal & Lazzaretto, Andrea & Masi, Massimo, 2024. "Guidelines for minimum cost transition planning to a 100% renewable multi-regional energy system," Applied Energy, Elsevier, vol. 357(C).
    3. Calise, Francesco & Cappiello, Francesco Liberato & Cimmino, Luca & Dentice d’Accadia, Massimo & Vicidomini, Maria, 2023. "Renewable smart energy network: A thermoeconomic comparison between conventional lithium-ion batteries and reversible solid oxide fuel cells," Renewable Energy, Elsevier, vol. 214(C), pages 74-95.
    4. González-Arias, Judith & González-Castaño, Miriam & Sánchez, Marta Elena & Cara-Jiménez, Jorge & Arellano-García, Harvey, 2022. "Valorization of biomass-derived CO2 residues with Cu-MnOx catalysts for RWGS reaction," Renewable Energy, Elsevier, vol. 182(C), pages 443-451.
    5. Pastore, Lorenzo Mario & Lo Basso, Gianluigi & Sforzini, Matteo & de Santoli, Livio, 2022. "Technical, economic and environmental issues related to electrolysers capacity targets according to the Italian Hydrogen Strategy: A critical analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 166(C).
    6. Leonhard Povacz & Ramchandra Bhandari, 2023. "Analysis of the Levelized Cost of Renewable Hydrogen in Austria," Sustainability, MDPI, vol. 15(5), pages 1-23, March.
    7. Konstantinos Kappis & Joan Papavasiliou & George Avgouropoulos, 2021. "Methanol Reforming Processes for Fuel Cell Applications," Energies, MDPI, vol. 14(24), pages 1-30, December.
    8. Ye, Yang & Yue, Yi & Lu, Jianfeng & Ding, Jing & Wang, Weilong & Yan, Jinyue, 2021. "Enhanced hydrogen storage of a LaNi5 based reactor by using phase change materials," Renewable Energy, Elsevier, vol. 180(C), pages 734-743.
    9. Zhao, Meng-Jie & He, Qian & Xiang, Ting & Ya, Hua-Qin & Luo, Hao & Wan, Shanhong & Ding, Jun & He, Jian-Bo, 2023. "Automatic operation of decoupled water electrolysis based on bipolar electrode," Renewable Energy, Elsevier, vol. 203(C), pages 583-591.
    10. Superchi, Francesco & Papi, Francesco & Mannelli, Andrea & Balduzzi, Francesco & Ferro, Francesco Maria & Bianchini, Alessandro, 2023. "Development of a reliable simulation framework for techno-economic analyses on green hydrogen production from wind farms using alkaline electrolyzers," Renewable Energy, Elsevier, vol. 207(C), pages 731-742.
    11. Shen, Xiaojun & Li, Xingyi & Yuan, Jiahai & Jin, Yu, 2022. "A hydrogen-based zero-carbon microgrid demonstration in renewable-rich remote areas: System design and economic feasibility," Applied Energy, Elsevier, vol. 326(C).
    12. Abdoulkader Ibrahim Idriss & Ramadan Ali Ahmed & Hamda Abdi Atteyeh & Omar Abdoulkader Mohamed & Haitham Saad Mohamed Ramadan, 2023. "Techno-Economic Potential of Wind-Based Green Hydrogen Production in Djibouti: Literature Review and Case Studies," Energies, MDPI, vol. 16(16), pages 1-19, August.
    13. Armenia Androniceanu & Oana Matilda Sabie, 2022. "Overview of Green Energy as a Real Strategic Option for Sustainable Development," Energies, MDPI, vol. 15(22), pages 1-35, November.
    14. Wang, Jing & Kang, Lixia & Liu, Yongzhong, 2024. "Optimal design of a renewable hydrogen production system by coordinating multiple PV arrays and multiple electrolyzers," Renewable Energy, Elsevier, vol. 225(C).
    15. Bhandari, Ramchandra & Subedi, Subodh, 2023. "Evaluation of surplus hydroelectricity potential in Nepal until 2040 and its use for hydrogen production via electrolysis," Renewable Energy, Elsevier, vol. 212(C), pages 403-414.
    16. Bhandari, Ramchandra, 2022. "Green hydrogen production potential in West Africa – Case of Niger," Renewable Energy, Elsevier, vol. 196(C), pages 800-811.
    17. Marek Jaszczur & Qusay Hassan & Aws Zuhair Sameen & Hayder M. Salman & Olushola Tomilayo Olapade & Szymon Wieteska, 2023. "Massive Green Hydrogen Production Using Solar and Wind Energy: Comparison between Europe and the Middle East," Energies, MDPI, vol. 16(14), pages 1-26, July.
    18. Carlson, Ewa Lazarczyk & Pickford, Kit & Nyga-Łukaszewska, Honorata, 2023. "Green hydrogen and an evolving concept of energy security: Challenges and comparisons," Renewable Energy, Elsevier, vol. 219(P1).
    19. Yar, Adem & Kınas, Zeynep & Karabiber, Abdulkerim & Ozen, Abdurrahman & Okbaz, Abdulkerim & Ozel, Faruk, 2021. "Enhanced performance of triboelectric nanogenerator based on polyamide-silver antimony sulfide nanofibers for energy harvesting," Renewable Energy, Elsevier, vol. 179(C), pages 1781-1792.
    20. Douvartzides, Savvas & Charisiou, Nikolaos D. & Wang, Wen & Papadakis, Vagelis G. & Polychronopoulou, Kyriaki & Goula, Maria A., 2022. "Catalytic fast pyrolysis of agricultural residues and dedicated energy crops for the production of high energy density transportation biofuels. Part I: Chemical pathways and bio-oil upgrading," Renewable Energy, Elsevier, vol. 185(C), pages 483-505.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:182:y:2022:i:c:p:713-724. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.