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Production of bio-hydrogenated kerosene by catalytic hydrocracking from refined bleached deodorised palm/ palm kernel oils

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  • Dujjanutat, Praepilas
  • Kaewkannetra, Pakawadee

Abstract

In this work, refined bleached deodorised palm oil (RPO) and palm kernel oil (PKO) obtained from palm oil refinery, were used as feedstocks to investigate the production of bio-hydrogenated kerosene (BHK) via hydrocracking reaction. A statistical tool of box-behnken design (BBD) was applied to consider the effects of reaction temperature, pressure and liquid hourly space velocity (LHSV) on biofuel production from RPO. The results revealed that the temperature was strongly significant effect on the yield and the optimal condition was found at 477 °C, 5.6 MPa and 1.5 h−1 of LHSV. Subsequently, crude biofuel was separated by fractional distillation, the biofuel yield was obtained at approximately 90% and providing 49.59% kerosene selectivity. Curiously, another feedstock of PKO which has lauric acid as the main composition whereas RPO contained palmitic and oleic acids, was used to produce BHK by using operating condition based-on RPO optimal condition. The biofuel yield derived from PKO reached at the same quantity. On the other hand, kerosene selectivity obtained was higher than in case of RPO (55.35%). However, high oxygen content was found in PKO-derived BHK, and this affected to freezing point and total acid number.

Suggested Citation

  • Dujjanutat, Praepilas & Kaewkannetra, Pakawadee, 2020. "Production of bio-hydrogenated kerosene by catalytic hydrocracking from refined bleached deodorised palm/ palm kernel oils," Renewable Energy, Elsevier, vol. 147(P1), pages 464-472.
    • Handle: RePEc:eee:renene:v:147:y:2020:i:p1:p:464-472
    DOI: 10.1016/j.renene.2019.09.015
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    References listed on IDEAS

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    1. Chuck, Christopher J. & Donnelly, Joseph, 2014. "The compatibility of potential bioderived fuels with Jet A-1 aviation kerosene," Applied Energy, Elsevier, vol. 118(C), pages 83-91.
    2. Liu, Guangrui & Yan, Beibei & Chen, Guanyi, 2013. "Technical review on jet fuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 25(C), pages 59-70.
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    5. Verma, Vikas & Mishra, Ankit & Anand, Mohit & Farooqui, Saleem Akhtar & Sinha, Anil Kumar, 2022. "Catalytic hydrocracking of inedible palm stearin for the production of drop-in aviation fuel and comparison with other inedible oils," Renewable Energy, Elsevier, vol. 199(C), pages 1440-1450.
    6. Gómez-Castro, F.I. & Gutiérrez-Antonio, C. & Romero-Izquierdo, A.G. & May-Vázquez, M.M. & Hernández, S., 2023. "Intensified technologies for the production of triglyceride-based biofuels: Current status and future trends," Renewable and Sustainable Energy Reviews, Elsevier, vol. 184(C).
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