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Co-pyrolysis of cotton stalk and waste tire with a focus on liquid yield quantity and quality

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  • Shah, Syed Asfand Yar
  • Zeeshan, Muhammad
  • Farooq, Muhammad Zohaib
  • Ahmed, Naveed
  • Iqbal, Naseem

Abstract

In this study, effect of waste tire (WT) addition to cotton stalk (CS) pyrolysis is investigated with a focus on liquid co-pyrolysis yield quantity and quality. Various blend ratios (i.e. CS/WT 1:0, 4:1, 3:2, 2:3, 0:1) of the two feedstocks were experimented in a fixed bed reactor at 20 °C/min heating ramp rate up to 550 °C with 50 ml/min flowrate of nitrogen as sweeping gas. Blend ratio CS/WT (2:3) showed maximum oil yield (48 wt%) with organic phase (OP) above 78 wt% of the total liquid yield (OP + aqueous phase, AP). OP of CS/WT (2:3) along with those of CS/WT (1:0) and (0:1) were further analyzed qualitatively using analytical techniques including, FTIR, GC-MS, bomb calorimetry and elemental analyzer. Significant increase in carbon and decrease in oxygen content of the CS/WT (2:3) pyrolytic oil was observed which improved its calorific value to 41 MJ/kg. Among the three OP samples, only CS/WT (2:3) oil showed significant presence of alkanes in GC-MS results, which is, thus, associated with the synergistic effect of the co-pyrolysis process. Addition of WT to CS pyrolysis feedstock improved liquid yield and its quality, thus requiring lesser further processing for its commercial use as compared to that of CS/WT (1:0) oil.

Suggested Citation

  • Shah, Syed Asfand Yar & Zeeshan, Muhammad & Farooq, Muhammad Zohaib & Ahmed, Naveed & Iqbal, Naseem, 2019. "Co-pyrolysis of cotton stalk and waste tire with a focus on liquid yield quantity and quality," Renewable Energy, Elsevier, vol. 130(C), pages 238-244.
    • Handle: RePEc:eee:renene:v:130:y:2019:i:c:p:238-244
    DOI: 10.1016/j.renene.2018.06.045
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    References listed on IDEAS

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    2. Vikraman, V. Karuppasamy & Boopathi, G. & Kumar, D. Praveen & Mythili, R. & Subramanian, P., 2021. "Non-isothermal pyrolytic kinetics of milk dust powder using thermogravimetric analysis," Renewable Energy, Elsevier, vol. 180(C), pages 838-849.
    3. Sun, Ce & Li, Wenlong & Chen, Xiaojian & Li, Changxin & Tan, Haiyan & Zhang, Yanhua, 2021. "Synergistic interactions for saving energy and promoting the co-pyrolysis of polylactic acid and wood flour," Renewable Energy, Elsevier, vol. 171(C), pages 254-265.

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