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Influence of Specific Power on the Solid and Liquid Products Obtained in the Microwave-Assisted Pyrolysis of End-of-Life Tires

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  • María Teresa Martín

    (Cátedra de Medio Ambiente, Facultad de Ciencias, Universidad de Alcalá, 28871 Alcalá de Henares, Spain
    Environment and Bioproducts Group, Facultad de Ciencias, Universidad de Alcalá, 28871 Alcalá de Henares, Spain)

  • Juan Luis Aguirre

    (Cátedra de Medio Ambiente, Facultad de Ciencias, Universidad de Alcalá, 28871 Alcalá de Henares, Spain
    Environment and Bioproducts Group, Facultad de Ciencias, Universidad de Alcalá, 28871 Alcalá de Henares, Spain)

  • Juan Baena-González

    (Cátedra de Medio Ambiente, Facultad de Ciencias, Universidad de Alcalá, 28871 Alcalá de Henares, Spain
    Environment and Bioproducts Group, Facultad de Ciencias, Universidad de Alcalá, 28871 Alcalá de Henares, Spain)

  • Sergio González

    (Cátedra de Medio Ambiente, Facultad de Ciencias, Universidad de Alcalá, 28871 Alcalá de Henares, Spain
    Environment and Bioproducts Group, Facultad de Ciencias, Universidad de Alcalá, 28871 Alcalá de Henares, Spain)

  • Roberto Pérez-Aparicio

    (Sistema Colectivo de Gestión de Neumáticos Fuera de Uso (SIGNUS), 28033 Madrid, Spain)

  • Leticia Saiz-Rodríguez

    (Sistema Colectivo de Gestión de Neumáticos Fuera de Uso (SIGNUS), 28033 Madrid, Spain)

Abstract

In this work, chemical recycling as an alternative to conventional end-of-life treatments was studied. Two different types of end-of-life tires (ELT), truck tires and mix tires (50:50 mixture of passenger car and truck tires), were pyrolyzed in a batch microwave reactor. The influence of specific power (10, 20, and 30 W/g) on mass distribution was analyzed. The maximum liquid yield was attained at 10 W/g, while the maximum gas yield is obtained at 30 W/g. Liquid fractions were characterized by gas chromatography/quadrupole mass spectrometry (GC/qMS) to identify the main components, and major compounds were quantified. In all samples, limonene (3.76 ± 0.31–6.80 ± 2.37 wt. %) and BTEX (3.83 ± 0.20–1.19 ± 2.80 wt. %) were the main components. Major limonene concentration is obtained in oil produced from truck ELT while higher yields of aromatic compounds are obtained from mix ELT. The maximum BTEX concentration is obtained at 10 W/g being toluene the main compound with a concentration of 2.07 ± 0.42 and 4.63 ± 1.29 for truck and mix ELT, respectively. The separation and purification of these compounds will confer important value to these fractions. Higher yields of the solid fraction are produced when mix tires are pyrolyzed due to the higher concentration of ash in this type of ELT. Recovered carbon black was characterized by measuring the surface area.

Suggested Citation

  • María Teresa Martín & Juan Luis Aguirre & Juan Baena-González & Sergio González & Roberto Pérez-Aparicio & Leticia Saiz-Rodríguez, 2022. "Influence of Specific Power on the Solid and Liquid Products Obtained in the Microwave-Assisted Pyrolysis of End-of-Life Tires," Energies, MDPI, vol. 15(6), pages 1-17, March.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:6:p:2128-:d:771042
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    References listed on IDEAS

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    1. Anna Matuszewska & Marlena Owczuk & Krzysztof Biernat, 2022. "Current Trends in Waste Plastics’ Liquefaction into Fuel Fraction: A Review," Energies, MDPI, vol. 15(8), pages 1-32, April.

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