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Non-isothermal pyrolytic kinetics of milk dust powder using thermogravimetric analysis

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  • Vikraman, V. Karuppasamy
  • Boopathi, G.
  • Kumar, D. Praveen
  • Mythili, R.
  • Subramanian, P.

Abstract

Milk dust is a prominent remnant of the milk powder packaging industry. The present study reports the thermal degradation pattern and pyrolytic kinetics of milk dust powder (MDP). Thermogravimetric studies were conducted at multiple heating rates (10, 20, 30, and 40 °C min−1) and the obtained biochars were characterized by FTIR, SEM, and XRD. Kinetic analysis was performed using model-free and model-fitting methods. The activation energy obtained by Starink and Friedman methods were 228.29 and 232.46 kJ mol−1, respectively. The frequency factor was found to be in the range between 2.69 × 1010 and 4.37 × 1032 s−1 as determined using the Kissinger method. The MDP pyrolysis followed diffusion (α = 0.05 to 0.2) ensued by higher-order (α = 0.6 to 0.95) reaction mechanism as predicted by the master plots. The change in enthalpy (144.88–405.42 kJ mol−1) and Gibb's free energy (176.98 and 182.21 kJ mol−1) implied the endothermic nature and non-spontaneity of MDP pyrolysis. Whereas ΔS values were negative in the conversion range (0.05–0.3) indicating that the process was spontaneous at initial conversions. The kinetic and thermodynamic analysis results confirm the suitability of milk dust powder as a potential candidate for energy conversion through pyrolysis.

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  • Vikraman, V. Karuppasamy & Boopathi, G. & Kumar, D. Praveen & Mythili, R. & Subramanian, P., 2021. "Non-isothermal pyrolytic kinetics of milk dust powder using thermogravimetric analysis," Renewable Energy, Elsevier, vol. 180(C), pages 838-849.
    • Handle: RePEc:eee:renene:v:180:y:2021:i:c:p:838-849
    DOI: 10.1016/j.renene.2021.08.099
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    1. Hong, Yu & Xie, Chengrui & Chen, Wanru & Luo, Xiang & Shi, Kaiqi & Wu, Tao, 2020. "Kinetic study of the pyrolysis of microalgae under nitrogen and CO2 atmosphere," Renewable Energy, Elsevier, vol. 145(C), pages 2159-2168.
    2. Siddiqi, Hammad & Bal, Manisha & Kumari, Usha & Meikap, B.C., 2020. "In-depth physiochemical characterization and detailed thermo-kinetic study of biomass wastes to analyze its energy potential," Renewable Energy, Elsevier, vol. 148(C), pages 756-771.
    3. Navarro, M.V. & López, J.M. & Veses, A. & Callén, M.S. & García, T., 2018. "Kinetic study for the co-pyrolysis of lignocellulosic biomass and plastics using the distributed activation energy model," Energy, Elsevier, vol. 165(PA), pages 731-742.
    4. Zhang, Xin & Deng, Honghu & Hou, Xueyi & Qiu, Rongliang & Chen, Zhihua, 2019. "Pyrolytic behavior and kinetic of wood sawdust at isothermal and non-isothermal conditions," Renewable Energy, Elsevier, vol. 142(C), pages 284-294.
    5. Merdun, Hasan & Laougé, Zakari Boubacar, 2021. "Kinetic and thermodynamic analyses during co-pyrolysis of greenhouse wastes and coal by TGA," Renewable Energy, Elsevier, vol. 163(C), pages 453-464.
    6. Shah, Syed Asfand Yar & Zeeshan, Muhammad & Farooq, Muhammad Zohaib & Ahmed, Naveed & Iqbal, Naseem, 2019. "Co-pyrolysis of cotton stalk and waste tire with a focus on liquid yield quantity and quality," Renewable Energy, Elsevier, vol. 130(C), pages 238-244.
    7. Cai, Junmeng & Xu, Di & Dong, Zhujun & Yu, Xi & Yang, Yang & Banks, Scott W. & Bridgwater, Anthony V., 2018. "Processing thermogravimetric analysis data for isoconversional kinetic analysis of lignocellulosic biomass pyrolysis: Case study of corn stalk," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2705-2715.
    8. Gong, Zhiqiang & Fang, Peiwen & Wang, Zhenbo & Li, Qiang & Li, Xiaoyu & Meng, Fanzhi & Zhang, Haoteng & Liu, Lei, 2020. "Catalytic pyrolysis of chemical extraction residue from microalgae biomass," Renewable Energy, Elsevier, vol. 148(C), pages 712-719.
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