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Biodiesel production from canola oil using novel Li/TiO2 as a heterogeneous catalyst prepared via impregnation method

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  • Alsharifi, Mariam
  • Znad, Hussein
  • Hena, Sufia
  • Ang, Ming

Abstract

This study focused on the development of heterogeneous catalyst for transesterification process by implanting lithium onto TiO2 by wet impregnation process. A series of Li/TiO2 was prepared with different amounts of Li (20, 30, 40 wt %) and at different calcination temperatures (450, 600, 750). The Li/TiO2 catalysts were characterized by several spectroscopic and analytical techniques like XRD, FT-IR, BET, TG-DSC and FESEM. The XRD study revealed that the insertion of Li improved the catalyst efficiency without any alteration in structure of TiO2. Li/TiO2 catalysts with 30%w/w Li and calcined at 600 °C was found to be the most efficient with 98% transesterification yield. The best performance of catalyst was achieved with methanol to oil ratio of 24:1, 5 wt % of catalyst loading, at 55 °C reaction temperatures for 3 h of reaction time. The kinetic studies revealed the transesterification process was compatible with the zero order model. However the reusability decreases after every successive use.

Suggested Citation

  • Alsharifi, Mariam & Znad, Hussein & Hena, Sufia & Ang, Ming, 2017. "Biodiesel production from canola oil using novel Li/TiO2 as a heterogeneous catalyst prepared via impregnation method," Renewable Energy, Elsevier, vol. 114(PB), pages 1077-1089.
    • Handle: RePEc:eee:renene:v:114:y:2017:i:pb:p:1077-1089
    DOI: 10.1016/j.renene.2017.07.117
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    1. Saba, Tony & Estephane, Jane & El Khoury, Bilal & El Khoury, Maroulla & Khazma, Mahmoud & El Zakhem, Henri & Aouad, Samer, 2016. "Biodiesel production from refined sunflower vegetable oil over KOH/ZSM5 catalysts," Renewable Energy, Elsevier, vol. 90(C), pages 301-306.
    2. Farooq, Muhammad & Ramli, Anita & Naeem, Abdul, 2015. "Biodiesel production from low FFA waste cooking oil using heterogeneous catalyst derived from chicken bones," Renewable Energy, Elsevier, vol. 76(C), pages 362-368.
    3. Olutoye, M.A. & Wong, S.W. & Chin, L.H. & Amani, H. & Asif, M. & Hameed, B.H., 2016. "Synthesis of fatty acid methyl esters via the transesterification of waste cooking oil by methanol with a barium-modified montmorillonite K10 catalyst," Renewable Energy, Elsevier, vol. 86(C), pages 392-398.
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    1. Das, Bikashbindu & Mohanty, Kaustubha, 2019. "A review on advances in sustainable energy production through various catalytic processes by using catalysts derived from waste red mud," Renewable Energy, Elsevier, vol. 143(C), pages 1791-1811.
    2. Al-Saadi, Ali & Mathan, Bobby & He, Yinghe, 2020. "Esterification and transesterification over SrO–ZnO/Al2O3 as a novel bifunctional catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 158(C), pages 388-399.
    3. Pandit, Priti R. & Fulekar, M.H., 2019. "Biodiesel production from microalgal biomass using CaO catalyst synthesized from natural waste material," Renewable Energy, Elsevier, vol. 136(C), pages 837-845.
    4. AlSharifi, Mariam & Znad, Hussein, 2019. "Development of a lithium based chicken bone (Li-Cb) composite as an efficient catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 136(C), pages 856-864.
    5. Zik, N.A.F.A. & Sulaiman, S. & Jamal, P., 2020. "Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bed reactor," Renewable Energy, Elsevier, vol. 155(C), pages 267-277.
    6. AlSharifi, Mariam & Znad, Hussein, 2020. "Transesterification of waste canola oil by lithium/zinc composite supported on waste chicken bone as an effective catalyst," Renewable Energy, Elsevier, vol. 151(C), pages 740-749.
    7. Yusuff, Adeyinka Sikiru & Gbadamosi, Afeez Olayinka & Atray, Neeraj, 2022. "Development of a zeolite supported CaO derived from chicken eggshell as active base catalyst for used cooking oil biodiesel production," Renewable Energy, Elsevier, vol. 197(C), pages 1151-1162.
    8. Li, Hui & Wang, Yongbo & Ma, Xiaoling & Guo, Min & Li, Yan & Li, Guoning & Cui, Ping & Zhou, Shoujun & Yu, Mingzhi, 2022. "Synthesis of CaO/ZrO2 based catalyst by using UiO–66(Zr) and calcium acetate for biodiesel production," Renewable Energy, Elsevier, vol. 185(C), pages 970-977.

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