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Sequential organosolv fractionation/hydrolysis of sugarcane bagasse: The coupling use of heterogeneous H3PO4-activated carbon as acid promoter and hydrolysis catalyst

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  • Suriyachai, Nopparat
  • Champreda, Verawat
  • Sakdaronnarong, Chularat
  • Shotipruk, Artiwan
  • Laosiripojana, Navadol

Abstract

Separation of lignocellulose constituents and hydrolysis of the polysaccharides fraction to sugars are pre-requites in production of biofuels and chemicals. In this study, a sequential organosolv fractionation of sugarcane bagasse and saccharification of the cellulose-enriched pulp in hot compressed water using a coupled heterogenous acid promoter/catalyst was studied. Among the liquid and solid acids tested, H3PO4-Activated carbon showed a high performance on promoting selectivity and yield in fractionation related to its high BET surface area and acid site density. Fractionation in a ternary mixture of methyl isolbutylketone:methanol:water (16:68:16) at 180 °C for 60 min using 5%w/w H3PO4-Activated carbon resulted in 88.9% recovery of cellulose enriched in the solid, together with 84.6% recovery of the hemicellulose as pentoses in the aqueous-alcohol fraction and 76.0% lignin in the organic phase. With no separation of the solid acid, the cellulose fraction could be further hydrolyzed under hot compressed water conditions at 225 °C for 10 min, resulting in the maximal hexose yield of 58.3% from the starting material. The catalyst retained >80% activity after reusing in five consecutive batch cycles. The work demonstrates an efficient integrated fractionation/hydrolysis process with coupling use of the acid promoter/catalyst, with advantages on its high activity, selectivity and reusability.

Suggested Citation

  • Suriyachai, Nopparat & Champreda, Verawat & Sakdaronnarong, Chularat & Shotipruk, Artiwan & Laosiripojana, Navadol, 2017. "Sequential organosolv fractionation/hydrolysis of sugarcane bagasse: The coupling use of heterogeneous H3PO4-activated carbon as acid promoter and hydrolysis catalyst," Renewable Energy, Elsevier, vol. 113(C), pages 1141-1148.
    • Handle: RePEc:eee:renene:v:113:y:2017:i:c:p:1141-1148
    DOI: 10.1016/j.renene.2017.06.003
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    References listed on IDEAS

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    1. Imman, Saksit & Arnthong, Jantima & Burapatana, Vorakan & Champreda, Verawat & Laosiripojana, Navadol, 2015. "Fractionation of rice straw by a single-step solvothermal process: Effects of solvents, acid promoters, and microwave treatment," Renewable Energy, Elsevier, vol. 83(C), pages 663-673.
    2. Ghatak, Himadri Roy, 2011. "Biorefineries from the perspective of sustainability: Feedstocks, products, and processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 4042-4052.
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    1. Lee, Hye-Min & An, Kay-Hyeok & Chung, Dong-Cul & Jung, Sang-Chul & Park, Young-Kwon & Park, Soo-Jin & Kim, Byung-Joo, 2019. "Comparison studies on pore development mechanisms of activated hard carbons from polymeric resins and their applications for electrode materials," Renewable Energy, Elsevier, vol. 144(C), pages 116-122.
    2. Puengprasert, Punika & Chalobol, Tanida & Sinbuathong, Nusara & Srinophakhun, Penjit & Thanapimmetha, Anusith & Liu, Chen-Guang & Zhao, Xin-Qing & Sakdaronnarong, Chularat, 2020. "A combined cellulosic and starchy ethanol and biomethane production with stillage recycle and respective cost analysis," Renewable Energy, Elsevier, vol. 157(C), pages 444-455.
    3. Intaramas, Kanpichcha & Jonglertjunya, Woranart & Laosiripojana, Navadol & Sakdaronnarong, Chularat, 2018. "Selective conversion of cassava mash to glucose using solid acid catalysts by sequential solid state mixed-milling reaction and thermo-hydrolysis," Energy, Elsevier, vol. 149(C), pages 837-847.
    4. Patricia Portero-Barahona & Enrique Javier Carvajal-Barriga & Jesús Martín-Gil & Pablo Martín-Ramos, 2019. "Sugarcane Bagasse Hydrolysis Enhancement by Microwave-Assisted Sulfolane Pretreatment," Energies, MDPI, vol. 12(9), pages 1-15, May.

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