IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v90y2015ip2p2070-2084.html
   My bibliography  Save this article

Performance characterization and modelling of syngas-fed SOFCs (solid oxide fuel cells) varying fuel composition

Author

Listed:
  • Baldinelli, Arianna
  • Barelli, Linda
  • Bidini, Gianni

Abstract

SOFCs (solid oxide fuel cells) are a promising technology for electric power generation, because of their high efficiency and fuel flexibility. Relative to more mature technologies, they appear very competitive starting from small-scale applications. The aim of this study is to map SOFC performances varying fuel composition, reproducing gases of technical interest (biomass air and oxy-gasification, water and carbon dioxide co-electrolysis, steam methane reforming) and to provide a forecasting tool to predict performance upon the fuel composition occurring in any application. Therefore, at first commercial SOFC are tested using several fuel gas mixtures produced by means of the chosen technologies (H2, CO, CH4 molar fractions ranges are respectively 8–50%, 0–42%, 1–8%). Secondly, experimental data are used to build a mathematical tool to predict SOFC characteristic curve from the fuel composition. This result is interesting from the point of view of system-level modelling, because it allows characterizing commercial SOFCs performances in many technical applications. Forecast error is less than 1%. Because of its accuracy, the model can be implemented to assess properly SOFC performance as a consequence of any particular hybridization, whereas fuel composition falls into the range already defined.

Suggested Citation

  • Baldinelli, Arianna & Barelli, Linda & Bidini, Gianni, 2015. "Performance characterization and modelling of syngas-fed SOFCs (solid oxide fuel cells) varying fuel composition," Energy, Elsevier, vol. 90(P2), pages 2070-2084.
    • Handle: RePEc:eee:energy:v:90:y:2015:i:p2:p:2070-2084
    DOI: 10.1016/j.energy.2015.07.126
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S036054421501021X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2015.07.126?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Yan, Linbo & He, Boshu & Pei, Xiaohui & Li, Xusheng & Wang, Chaojun, 2013. "Energy and exergy analyses of a Zero emission coal system," Energy, Elsevier, vol. 55(C), pages 1094-1103.
    2. Facchinetti, Emanuele & Gassner, Martin & D’Amelio, Matilde & Marechal, François & Favrat, Daniel, 2012. "Process integration and optimization of a solid oxide fuel cell – Gas turbine hybrid cycle fueled with hydrothermally gasified waste biomass," Energy, Elsevier, vol. 41(1), pages 408-419.
    3. Choudhury, Arnab & Chandra, H. & Arora, A., 2013. "Application of solid oxide fuel cell technology for power generation—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 20(C), pages 430-442.
    4. Bang-Møller, C. & Rokni, M. & Elmegaard, B. & Ahrenfeldt, J. & Henriksen, U.B., 2013. "Decentralized combined heat and power production by two-stage biomass gasification and solid oxide fuel cells," Energy, Elsevier, vol. 58(C), pages 527-537.
    5. Seitarides, Th. & Athanasiou, C. & Zabaniotou, A., 2008. "Modular biomass gasification-based solid oxide fuel cells (SOFC) for sustainable development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(5), pages 1251-1276, June.
    6. Saebea, Dang & Authayanun, Suthida & Patcharavorachot, Yaneeporn & Paengjuntuek, Woranee & Arpornwichanop, Amornchai, 2013. "Use of different renewable fuels in a steam reformer integrated into a solid oxide fuel cell: Theoretical analysis and performance comparison," Energy, Elsevier, vol. 51(C), pages 305-313.
    7. Tseng, Phillip & Lee, John & Friley, Paul, 2005. "A hydrogen economy: opportunities and challenges," Energy, Elsevier, vol. 30(14), pages 2703-2720.
    8. Liu, Ming & Woudstra, T. & Promes, E.J.O. & Restrepo, S.Y.G. & Aravind, P.V., 2014. "System development and self-sustainability analysis for upgrading human waste to power," Energy, Elsevier, vol. 68(C), pages 377-384.
    9. Carton, J.G. & Lawlor, V. & Olabi, A.G. & Hochenauer, C. & Zauner, G., 2012. "Water droplet accumulation and motion in PEM (Proton Exchange Membrane) fuel cell mini-channels," Energy, Elsevier, vol. 39(1), pages 63-73.
    10. Fryda, L. & Panopoulos, K.D. & Karl, J. & Kakaras, E., 2008. "Exergetic analysis of solid oxide fuel cell and biomass gasification integration with heat pipes," Energy, Elsevier, vol. 33(2), pages 292-299.
    11. Lv, Pengmei & Yuan, Zhenhong & Ma, Longlong & Wu, Chuangzhi & Chen, Yong & Zhu, Jingxu, 2007. "Hydrogen-rich gas production from biomass air and oxygen/steam gasification in a downdraft gasifier," Renewable Energy, Elsevier, vol. 32(13), pages 2173-2185.
    12. Bellomare, Filippo & Rokni, Masoud, 2013. "Integration of a municipal solid waste gasification plant with solid oxide fuel cell and gas turbine," Renewable Energy, Elsevier, vol. 55(C), pages 490-500.
    13. Rokni, Masoud, 2013. "Thermodynamic analysis of SOFC (solid oxide fuel cell)–Stirling hybrid plants using alternative fuels," Energy, Elsevier, vol. 61(C), pages 87-97.
    14. Rokni, Masoud, 2014. "Biomass gasification integrated with a solid oxide fuel cell and Stirling engine," Energy, Elsevier, vol. 77(C), pages 6-18.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Rashid, Kashif & Dong, Sang Keun & Mehran, Muhammad Taqi, 2017. "Numerical investigations to determine the optimal operating conditions for 1 kW-class flat-tubular solid oxide fuel cell stack," Energy, Elsevier, vol. 141(C), pages 673-691.
    2. Pongratz, Gernot & Subotić, Vanja & Hochenauer, Christoph & Scharler, Robert & Anca-Couce, Andrés, 2022. "Solid oxide fuel cell operation with biomass gasification product gases: Performance- and carbon deposition risk evaluation via a CFD modelling approach," Energy, Elsevier, vol. 244(PB).
    3. Jienkulsawad, Prathak & Arpornwichanop, Amornchai, 2016. "Investigating the performance of a solid oxide fuel cell and a molten carbonate fuel cell combined system," Energy, Elsevier, vol. 107(C), pages 843-853.
    4. Subotić, Vanja & Baldinelli, Arianna & Barelli, Linda & Scharler, Robert & Pongratz, Gernot & Hochenauer, Christoph & Anca-Couce, Andrés, 2019. "Applicability of the SOFC technology for coupling with biomass-gasifier systems: Short- and long-term experimental study on SOFC performance and degradation behaviour," Applied Energy, Elsevier, vol. 256(C).
    5. Habibollahzade, Ali & Rosen, Marc A., 2021. "Syngas-fueled solid oxide fuel cell functionality improvement through appropriate feedstock selection and multi-criteria optimization using Air/O2-enriched-air gasification agents," Applied Energy, Elsevier, vol. 286(C).
    6. Chatrattanawet, Narissara & Saebea, Dang & Authayanun, Suthida & Arpornwichanop, Amornchai & Patcharavorachot, Yaneeporn, 2018. "Performance and environmental study of a biogas-fuelled solid oxide fuel cell with different reforming approaches," Energy, Elsevier, vol. 146(C), pages 131-140.
    7. Meiting Guo & Xiao Ru & Zijing Lin & Guoping Xiao & Jianqiang Wang, 2020. "Optimization Design of Rib Width and Performance Analysis of Solid Oxide Electrolysis Cell," Energies, MDPI, vol. 13(20), pages 1-18, October.
    8. Santhanam, S. & Schilt, C. & Turker, B. & Woudstra, T. & Aravind, P.V., 2016. "Thermodynamic modeling and evaluation of high efficiency heat pipe integrated biomass Gasifier–Solid Oxide Fuel Cells–Gas Turbine systems," Energy, Elsevier, vol. 109(C), pages 751-764.
    9. Pongratz, G. & Subotić, V. & Schroettner, H. & Hochenauer, C. & Skrzypkiewicz, M. & Kupecki, Jakub & Anca-Couce, A. & Scharler, R., 2021. "Analysis of H2S-related short-term degradation and regeneration of anode- and electrolyte supported solid oxide fuel cells fueled with biomass steam gasifier product gas," Energy, Elsevier, vol. 218(C).
    10. Yang, JiaJun & Yan, Dong & Huang, Wei & Li, Jun & Pu, Jian & Chi, Bo & Jian, Li, 2018. "Improvement on durability and thermal cycle performance for solid oxide fuel cell stack with external manifold structure," Energy, Elsevier, vol. 149(C), pages 903-913.
    11. Dang, Zheng & Xu, Han, 2016. "Pore scale investigation of gaseous mixture flow in porous anode of solid oxide fuel cell," Energy, Elsevier, vol. 107(C), pages 295-304.
    12. Abedinia, Oveis & Shakibi, Hamid & Shokri, Afshar & Sobhani, Behnam & Sobhani, Behrouz & Yari, Mortaza & Bagheri, Mehdi, 2024. "Optimization of a syngas-fueled SOFC-based multigeneration system: Enhanced performance with biomass and gasification agent selection," Renewable and Sustainable Energy Reviews, Elsevier, vol. 199(C).
    13. Cavalli, A. & Fernandes, A. & Aravind, P.V., 2021. "Thermodynamic analysis of an improved integrated biomass gasifier solid oxide fuel cell micro combined heat and power system," Energy, Elsevier, vol. 231(C).
    14. Orlando Corigliano & Leonardo Pagnotta & Petronilla Fragiacomo, 2022. "On the Technology of Solid Oxide Fuel Cell (SOFC) Energy Systems for Stationary Power Generation: A Review," Sustainability, MDPI, vol. 14(22), pages 1-73, November.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Buonomano, Annamaria & Calise, Francesco & d’Accadia, Massimo Dentice & Palombo, Adolfo & Vicidomini, Maria, 2015. "Hybrid solid oxide fuel cells–gas turbine systems for combined heat and power: A review," Applied Energy, Elsevier, vol. 156(C), pages 32-85.
    2. Azizi, Mohammad Ali & Brouwer, Jacob, 2018. "Progress in solid oxide fuel cell-gas turbine hybrid power systems: System design and analysis, transient operation, controls and optimization," Applied Energy, Elsevier, vol. 215(C), pages 237-289.
    3. Naraharisetti, Pavan Kumar & Lakshminarayanan, S. & Karimi, I.A., 2014. "Design of biomass and natural gas based IGFC using multi-objective optimization," Energy, Elsevier, vol. 73(C), pages 635-652.
    4. Khani, Leyla & Mahmoudi, S. Mohammad S. & Chitsaz, Ata & Rosen, Marc A., 2016. "Energy and exergoeconomic evaluation of a new power/cooling cogeneration system based on a solid oxide fuel cell," Energy, Elsevier, vol. 94(C), pages 64-77.
    5. Vialetto, Giulio & Rokni, Masoud, 2015. "Innovative household systems based on solid oxide fuel cells for a northern European climate," Renewable Energy, Elsevier, vol. 78(C), pages 146-156.
    6. Rokni, Masoud, 2014. "Thermodynamic and thermoeconomic analysis of a system with biomass gasification, solid oxide fuel cell (SOFC) and Stirling engine," Energy, Elsevier, vol. 76(C), pages 19-31.
    7. Yuan, Zhenyu & Yang, Jie & Zhang, Yufeng, 2015. "A self-adaptive supply method of micro direct methanol fuel cell," Energy, Elsevier, vol. 91(C), pages 1064-1069.
    8. Rokni, M., 2017. "Addressing fuel recycling in solid oxide fuel cell systems fed by alternative fuels," Energy, Elsevier, vol. 137(C), pages 1013-1025.
    9. Mazzucco, Andrea & Rokni, Masoud, 2014. "Thermo-economic analysis of a solid oxide fuel cell and steam injected gas turbine plant integrated with woodchips gasification," Energy, Elsevier, vol. 76(C), pages 114-129.
    10. Xing, Lei & Du, Shangfeng & Chen, Rui & Mamlouk, Mohamed & Scott, Keith, 2016. "Anode partial flooding modelling of proton exchange membrane fuel cells: Model development and validation," Energy, Elsevier, vol. 96(C), pages 80-95.
    11. Ramadhani, F. & Hussain, M.A. & Mokhlis, H. & Hajimolana, S., 2017. "Optimization strategies for Solid Oxide Fuel Cell (SOFC) application: A literature survey," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 460-484.
    12. Udomsirichakorn, Jakkapong & Salam, P. Abdul, 2014. "Review of hydrogen-enriched gas production from steam gasification of biomass: The prospect of CaO-based chemical looping gasification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 565-579.
    13. Ud Din, Zia & Zainal, Z.A., 2016. "Biomass integrated gasification–SOFC systems: Technology overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1356-1376.
    14. Singh, Surinder P. & Ohara, Brandon & Ku, Anthony Y., 2021. "Prospects for cost-competitive integrated gasification fuel cell systems," Applied Energy, Elsevier, vol. 290(C).
    15. Eom, Seongyong & Ahn, Seongyool & Rhie, Younghoon & Kang, Kijoong & Sung, Yonmo & Moon, Cheoreon & Choi, Gyungmin & Kim, Duckjool, 2014. "Influence of devolatilized gases composition from raw coal fuel in the lab scale DCFC (direct carbon fuel cell) system," Energy, Elsevier, vol. 74(C), pages 734-740.
    16. Xenos, Dionysios P. & Hofmann, Philipp & Panopoulos, Kyriakos D. & Kakaras, Emmanuel, 2015. "Detailed transient thermal simulation of a planar SOFC (solid oxide fuel cell) using gPROMS™," Energy, Elsevier, vol. 81(C), pages 84-102.
    17. Wang, Yuan & Cai, Ling & Liu, Tie & Wang, Junyi & Chen, Jincan, 2015. "An efficient strategy exploiting the waste heat in a solid oxide fuel cell system," Energy, Elsevier, vol. 93(P1), pages 900-907.
    18. Choudhary, Tushar & Sanjay,, 2017. "Thermodynamic assessment of SOFC-ICGT hybrid cycle: Energy analysis and entropy generation minimization," Energy, Elsevier, vol. 134(C), pages 1013-1028.
    19. Amedi, Hamid Reza & Bazooyar, Bahamin & Pishvaie, Mahmoud Reza, 2015. "Control of anode supported SOFCs (solid oxide fuel cells): Part I. mathematical modeling and state estimation within one cell," Energy, Elsevier, vol. 90(P1), pages 605-621.
    20. Mounir, Hamid & Belaiche, Mohamed & El Marjani, Abdellatif & El Gharad, Abdellah, 2014. "Thermal stress and probability of survival investigation in a multi-bundle integrated-planar solid oxide fuel cells IP-SOFC (integrated-planar solid oxide fuel cell)," Energy, Elsevier, vol. 66(C), pages 378-386.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:90:y:2015:i:p2:p:2070-2084. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.