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The use of superporous p(AAc (acrylic acid)) cryogels as support for Co and Ni nanoparticle preparation and as reactor in H2 production from sodium borohydride hydrolysis

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  • Sahiner, Nurettin
  • Seven, Fahriye

Abstract

Here, we report for the first time the use of p(AAc (p(acrylic acid)) cryogel for in situ metal nanoparticle preparation, and their use as a superporous reactor for H2 generation from hydrolysis of NaBH4. Superporous p(AAc) cryogels and conventional hydrogels were prepared via free radical polymerization technique at low (−18 °C) and moderate (40 °C) temperatures, respectively. They were characterized by employing various methods such as swelling experiments, optical imaging, and SEM (Scanning Electron Microscopy) analysis. By reducing Co2+ and Ni2+ ions within p(AAc) cryogel and hydrogel matrices, the obtained Co and Ni metal nanoparticles were employed for H2 generation from NaBH4 hydrolysis. Various factors such as porosity, metal type, temperature, and the amount of sodium hydroxide were investigated to determine their effects on hydrogen generation from NaBH4 hydrolysis. Activation energy (Ea), enthalpy (ΔH#) and entropy (ΔS#) for NaBH4 hydrolysis by superporous p(AAc)-Co metal composites were 29.35 kJ mol−1,=36.85 kJ mol−1, and –157.88 J mol−1K−1, respectively. Cryogels showed better catalytic activity than conventional hydrogels in the hydrolysis reaction, and have a higher TOF (turnover frequency) value of 4.10 mol H2 (mol catalyst min)−1 compared to conventional hydrogels, due to its highly porous nature, short diffusion distances and fast response times.

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  • Sahiner, Nurettin & Seven, Fahriye, 2014. "The use of superporous p(AAc (acrylic acid)) cryogels as support for Co and Ni nanoparticle preparation and as reactor in H2 production from sodium borohydride hydrolysis," Energy, Elsevier, vol. 71(C), pages 170-179.
  • Handle: RePEc:eee:energy:v:71:y:2014:i:c:p:170-179
    DOI: 10.1016/j.energy.2014.04.031
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    References listed on IDEAS

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    1. Xu, J. & Li, Y. & Wang, R.Z. & Liu, W., 2014. "Performance investigation of a solar heating system with underground seasonal energy storage for greenhouse application," Energy, Elsevier, vol. 67(C), pages 63-73.
    2. Shih, Yu-Jen & Su, Chia-Chi & Huang, Yao-Hui & Lu, Ming-Chun, 2013. "SiO2-supported ferromagnetic catalysts for hydrogen generation from alkaline NaBH4 (sodium borohydride) solution," Energy, Elsevier, vol. 54(C), pages 263-270.
    3. Huang, Zhen-Ming & Su, Ay & Liu, Ying-Chieh, 2013. "Hydrogen generator system using Ru catalyst for PEMFC (proton exchange membrane fuel cell) applications," Energy, Elsevier, vol. 51(C), pages 230-236.
    4. Lund, Henrik & Andersen, Anders N. & Østergaard, Poul Alberg & Mathiesen, Brian Vad & Connolly, David, 2012. "From electricity smart grids to smart energy systems – A market operation based approach and understanding," Energy, Elsevier, vol. 42(1), pages 96-102.
    5. Mathiesen, Brian Vad & Lund, Henrik & Connolly, David, 2012. "Limiting biomass consumption for heating in 100% renewable energy systems," Energy, Elsevier, vol. 48(1), pages 160-168.
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    Cited by:

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    3. Cai, Haokun & Liu, Liping & Chen, Qiang & Lu, Ping & Dong, Jian, 2016. "Ni-polymer nanogel hybrid particles: A new strategy for hydrogen production from the hydrolysis of dimethylamine-borane and sodium borohydride," Energy, Elsevier, vol. 99(C), pages 129-135.

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    Keywords

    Cryogel–hydrogel; Superporous-template; Metal nanoparticle-embedded cryogel composites; H2 generation; Hydrolysis;
    All these keywords.

    JEL classification:

    • H2 - Public Economics - - Taxation, Subsidies, and Revenue

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