IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v45y2012i1p256-263.html
   My bibliography  Save this article

Alkanes as fluids in Rankine cycles in comparison to water, benzene and toluene

Author

Listed:
  • Siddiqi, M. Aslam
  • Atakan, Burak

Abstract

Waste heat recovery from the exhaust gases of gas turbines, geothermal resources, and from industrial plants offers a great opportunity for rational energy usage by productively converting the waste energy. In the present communication we report a systematic study starting with the hydrocarbons for the different temperature ranges at which the waste heat is available from high, medium, or low temperature heat sources (viz., 773.15, 623.15 and 523.15 K). In the present work hydrocarbons from n-pentane to n-dodecane were investigated in comparison to water, benzene and toluene. Model calculations have been performed at various boiler pressures. Higher efficiencies are achieved at higher boiler pressures. In the low temperature range (523.15 K) hydrocarbons such as n-hexane, n-pentane are promising. If the heat is available at higher temperature (773.15 K) n-dodecane and toluene are the suitable fluids. In the case studies for the intermediate temperature range (623.15 K), it turns out that for many conditions, octane, heptanes and water are well suited working fluid for cogeneration systems. The results for the total heat recovery efficiency and the surface area of the heat exchanger have been discussed. T–H Diagrams were used to select the best possible conditions.

Suggested Citation

  • Siddiqi, M. Aslam & Atakan, Burak, 2012. "Alkanes as fluids in Rankine cycles in comparison to water, benzene and toluene," Energy, Elsevier, vol. 45(1), pages 256-263.
  • Handle: RePEc:eee:energy:v:45:y:2012:i:1:p:256-263
    DOI: 10.1016/j.energy.2012.06.005
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544212004562
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2012.06.005?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Lai, Ngoc Anh & Wendland, Martin & Fischer, Johann, 2011. "Working fluids for high-temperature organic Rankine cycles," Energy, Elsevier, vol. 36(1), pages 199-211.
    2. Larjola, J., 1995. "Electricity from industrial waste heat using high-speed organic Rankine cycle (ORC)," International Journal of Production Economics, Elsevier, vol. 41(1-3), pages 227-235, October.
    3. Borsukiewicz-Gozdur, Aleksandra & Nowak, Władysław, 2007. "Comparative analysis of natural and synthetic refrigerants in application to low temperature Clausius–Rankine cycle," Energy, Elsevier, vol. 32(4), pages 344-352.
    4. Liu, Bo-Tau & Chien, Kuo-Hsiang & Wang, Chi-Chuan, 2004. "Effect of working fluids on organic Rankine cycle for waste heat recovery," Energy, Elsevier, vol. 29(8), pages 1207-1217.
    5. Saleh, Bahaa & Koglbauer, Gerald & Wendland, Martin & Fischer, Johann, 2007. "Working fluids for low-temperature organic Rankine cycles," Energy, Elsevier, vol. 32(7), pages 1210-1221.
    6. Hung, T.C. & Shai, T.Y. & Wang, S.K., 1997. "A review of organic rankine cycles (ORCs) for the recovery of low-grade waste heat," Energy, Elsevier, vol. 22(7), pages 661-667.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Lecompte, S. & Huisseune, H. & van den Broek, M. & De Paepe, M., 2015. "Methodical thermodynamic analysis and regression models of organic Rankine cycle architectures for waste heat recovery," Energy, Elsevier, vol. 87(C), pages 60-76.
    2. Bao, Junjiang & Zhao, Li, 2013. "A review of working fluid and expander selections for organic Rankine cycle," Renewable and Sustainable Energy Reviews, Elsevier, vol. 24(C), pages 325-342.
    3. Li, Tailu & Zhu, Jialing & Hu, Kaiyong & Kang, Zhenhua & Zhang, Wei, 2014. "Implementation of PDORC (parallel double-evaporator organic Rankine cycle) to enhance power output in oilfield," Energy, Elsevier, vol. 68(C), pages 680-687.
    4. Morais, Pedro Henrique da Silva & Lodi, Andressa & Aoki, Adriana Cristine & Modesto, Marcelo, 2020. "Energy, exergetic and economic analyses of a combined solar-biomass-ORC cooling cogeneration systems for a Brazilian small plant," Renewable Energy, Elsevier, vol. 157(C), pages 1131-1147.
    5. Peter Collings & Zhibin Yu, 2017. "Numerical Analysis of an Organic Rankine Cycle with Adjustable Working Fluid Composition, a Volumetric Expander and a Recuperator," Energies, MDPI, vol. 10(4), pages 1-21, March.
    6. Wang, Enhua & Mao, Jingwen & Zhang, Bo & Wang, Yongzhen, 2023. "On the CAMD method based on PC-SAFT for working fluid design of a high-temperature organic Rankine cycle," Energy, Elsevier, vol. 263(PD).
    7. Zhang, Han & Han, Zhonghe & Wu, Di & Li, Peng & Li, Peng, 2023. "Energy optimization and performance analysis of a novel integrated energy system coupled with solar thermal unit and preheated organic cycle under extended following electric load strategy," Energy, Elsevier, vol. 272(C).
    8. Mohan, Sooraj & Dinesha, P. & Campana, Pietro Elia, 2022. "ANN-PSO aided selection of hydrocarbons as working fluid for low-temperature organic Rankine cycle and thermodynamic evaluation of optimal working fluid," Energy, Elsevier, vol. 259(C).
    9. Fanxiao, Meng & Enhua, Wang & Bo, Zhang, 2021. "Possibility of optimal efficiency prediction of an organic Rankine cycle based on molecular property method for high-temperature exhaust gases," Energy, Elsevier, vol. 222(C).
    10. Zhu, Yilin & Li, Weiyi & Sun, Guanzhong & Li, Haojie, 2018. "Thermo-economic analysis based on objective functions of an organic Rankine cycle for waste heat recovery from marine diesel engine," Energy, Elsevier, vol. 158(C), pages 343-356.
    11. Roskosch, Dennis & Atakan, Burak, 2015. "Reverse engineering of fluid selection for thermodynamic cycles with cubic equations of state, using a compression heat pump as example," Energy, Elsevier, vol. 81(C), pages 202-212.
    12. Shu, Gequn & Gao, Yuanyuan & Tian, Hua & Wei, Haiqiao & Liang, Xingyu, 2014. "Study of mixtures based on hydrocarbons used in ORC (Organic Rankine Cycle) for engine waste heat recovery," Energy, Elsevier, vol. 74(C), pages 428-438.
    13. Shu, Gequn & Li, Xiaoning & Tian, Hua & Liang, Xingyu & Wei, Haiqiao & Wang, Xu, 2014. "Alkanes as working fluids for high-temperature exhaust heat recovery of diesel engine using organic Rankine cycle," Applied Energy, Elsevier, vol. 119(C), pages 204-217.
    14. Liu, Peng & Shu, Gequn & Tian, Hua & Wang, Xuan & Yu, Zhigang, 2018. "Alkanes based two-stage expansion with interheating Organic Rankine cycle for multi-waste heat recovery of truck diesel engine," Energy, Elsevier, vol. 147(C), pages 337-350.
    15. Roskosch, Dennis & Venzik, Valerius & Atakan, Burak, 2020. "Potential analysis of pumped heat electricity storages regarding thermodynamic efficiency," Renewable Energy, Elsevier, vol. 147(P3), pages 2865-2873.
    16. Long Lyu & Wu Chen & Ankang Kan & Yuan Zhang & Song Xue & Jingbin Zeng, 2022. "Investigation of a Dual-Loop ORC for the Waste Heat Recovery of a Marine Main Engine," Energies, MDPI, vol. 15(22), pages 1-22, November.
    17. Ram Mohan, Arun & Turaga, Uday & Shembekar, Vishakha & Elsworth, Derek & Pisupati, Sarma V., 2013. "Utilization of carbon dioxide from coal-based power plants as a heat transfer fluid for electricity generation in enhanced geothermal systems (EGS)," Energy, Elsevier, vol. 57(C), pages 505-512.
    18. Unverdi, Murat & Cerci, Yunus, 2013. "Performance analysis of Germencik Geothermal Power Plant," Energy, Elsevier, vol. 52(C), pages 192-200.
    19. Mondejar, Maria E. & Ahlgren, Fredrik & Thern, Marcus & Genrup, Magnus, 2017. "Quasi-steady state simulation of an organic Rankine cycle for waste heat recovery in a passenger vessel," Applied Energy, Elsevier, vol. 185(P2), pages 1324-1335.
    20. Yang, Kai & Zhang, Hongguang & Wang, Zhen & Zhang, Jian & Yang, Fubin & Wang, Enhua & Yao, Baofeng, 2013. "Study of zeotropic mixtures of ORC (organic Rankine cycle) under engine various operating conditions," Energy, Elsevier, vol. 58(C), pages 494-510.
    21. Panesar, Angad Singh, 2016. "An innovative organic Rankine cycle approach for high temperature applications," Energy, Elsevier, vol. 115(P2), pages 1436-1450.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Bao, Junjiang & Zhao, Li, 2013. "A review of working fluid and expander selections for organic Rankine cycle," Renewable and Sustainable Energy Reviews, Elsevier, vol. 24(C), pages 325-342.
    2. Roy, J.P. & Misra, Ashok, 2012. "Parametric optimization and performance analysis of a regenerative Organic Rankine Cycle using R-123 for waste heat recovery," Energy, Elsevier, vol. 39(1), pages 227-235.
    3. Yang, Lixiang & Gong, Maoqiong & Guo, Hao & Dong, Xueqiang & Shen, Jun & Wu, Jianfeng, 2016. "Effects of critical and boiling temperatures on system performance and fluid selection indicator for low temperature organic Rankine cycles," Energy, Elsevier, vol. 109(C), pages 830-844.
    4. Chen, Huijuan & Goswami, D. Yogi & Stefanakos, Elias K., 2010. "A review of thermodynamic cycles and working fluids for the conversion of low-grade heat," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(9), pages 3059-3067, December.
    5. Tchanche, Bertrand F. & Lambrinos, Gr. & Frangoudakis, A. & Papadakis, G., 2011. "Low-grade heat conversion into power using organic Rankine cycles – A review of various applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3963-3979.
    6. Wang, Z.Q. & Zhou, N.J. & Guo, J. & Wang, X.Y., 2012. "Fluid selection and parametric optimization of organic Rankine cycle using low temperature waste heat," Energy, Elsevier, vol. 40(1), pages 107-115.
    7. Fuhaid Alshammari & Apostolos Karvountzis-Kontakiotis & Apostolos Pesyridis & Muhammad Usman, 2018. "Expander Technologies for Automotive Engine Organic Rankine Cycle Applications," Energies, MDPI, vol. 11(7), pages 1-36, July.
    8. Vélez, Fredy & Segovia, José J. & Martín, M. Carmen & Antolín, Gregorio & Chejne, Farid & Quijano, Ana, 2012. "A technical, economical and market review of organic Rankine cycles for the conversion of low-grade heat for power generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 4175-4189.
    9. Ghasemi, Hadi & Paci, Marco & Tizzanini, Alessio & Mitsos, Alexander, 2013. "Modeling and optimization of a binary geothermal power plant," Energy, Elsevier, vol. 50(C), pages 412-428.
    10. Sarkar, Jahar, 2015. "Review and future trends of supercritical CO2 Rankine cycle for low-grade heat conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 48(C), pages 434-451.
    11. Lecompte, S. & Huisseune, H. & van den Broek, M. & De Paepe, M., 2015. "Methodical thermodynamic analysis and regression models of organic Rankine cycle architectures for waste heat recovery," Energy, Elsevier, vol. 87(C), pages 60-76.
    12. Guo, T. & Wang, H.X. & Zhang, S.J., 2011. "Fluids and parameters optimization for a novel cogeneration system driven by low-temperature geothermal sources," Energy, Elsevier, vol. 36(5), pages 2639-2649.
    13. Li, Jing & Alvi, Jahan Zeb & Pei, Gang & Su, Yuehong & Li, Pengcheng & Gao, Guangtao & Ji, Jie, 2016. "Modelling of organic Rankine cycle efficiency with respect to the equivalent hot side temperature," Energy, Elsevier, vol. 115(P1), pages 668-683.
    14. Vaja, Iacopo & Gambarotta, Agostino, 2010. "Internal Combustion Engine (ICE) bottoming with Organic Rankine Cycles (ORCs)," Energy, Elsevier, vol. 35(2), pages 1084-1093.
    15. Bao, Junjiang & Zhao, Li, 2012. "Exergy analysis and parameter study on a novel auto-cascade Rankine cycle," Energy, Elsevier, vol. 48(1), pages 539-547.
    16. Shalaby, S.M., 2017. "Reverse osmosis desalination powered by photovoltaic and solar Rankine cycle power systems: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 789-797.
    17. Lee, Yuh-Ren & Kuo, Chi-Ron & Wang, Chi-Chuan, 2012. "Transient response of a 50 kW organic Rankine cycle system," Energy, Elsevier, vol. 48(1), pages 532-538.
    18. Steven Lecompte & Sanne Lemmens & Henk Huisseune & Martijn Van den Broek & Michel De Paepe, 2015. "Multi-Objective Thermo-Economic Optimization Strategy for ORCs Applied to Subcritical and Transcritical Cycles for Waste Heat Recovery," Energies, MDPI, vol. 8(4), pages 1-28, April.
    19. Lecompte, Steven & Huisseune, Henk & van den Broek, Martijn & Vanslambrouck, Bruno & De Paepe, Michel, 2015. "Review of organic Rankine cycle (ORC) architectures for waste heat recovery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 47(C), pages 448-461.
    20. Xu, Weicong & Zhao, Li & Mao, Samuel S. & Deng, Shuai, 2020. "Towards novel low temperature thermodynamic cycle: A critical review originated from organic Rankine cycle," Applied Energy, Elsevier, vol. 270(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:45:y:2012:i:1:p:256-263. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.