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Availability analysis of hydrogen/natural gas blends combustion in internal combustion engines

Author

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  • Rakopoulos, C.D.
  • Scott, M.A.
  • Kyritsis, D.C.
  • Giakoumis, E.G.

Abstract

Possibly one of the most significant advantages that hydrogen may have as a fuel is its potential for increased second-law efficiency, due to fundamental differences in the mechanism of entropy generation during combustion with respect to the usual hydrocarbon-based fuels. A computational investigation of this effect is pursued for the case of mixtures of hydrogen and natural gas combusting in a diesel engine cylinder. The terms of the availability balance during engine operation are studied as a function of hydrogen content of the fuel and the operating parameters of the engine. Of particular importance is the confirmation of results provided in earlier work by the authors that combustion irreversibilities during hydrogen combustion can be drastically reduced. A single-zone computational model of the engine operation is used and the hypothesis of chemical equilibrium is invoked for combustion calculations. For the description of engine processes, such as fuel preparation and heat transfer, computational models established for hydrocarbon fuels are used so that a comparison is performed under the assumption that hydrogen combustion will be feasible in conditions that do not depart exceedingly from current engine configurations.

Suggested Citation

  • Rakopoulos, C.D. & Scott, M.A. & Kyritsis, D.C. & Giakoumis, E.G., 2008. "Availability analysis of hydrogen/natural gas blends combustion in internal combustion engines," Energy, Elsevier, vol. 33(2), pages 248-255.
    • Handle: RePEc:eee:energy:v:33:y:2008:i:2:p:248-255
    DOI: 10.1016/j.energy.2007.05.009
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    References listed on IDEAS

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    1. Caton, Jerald A, 2000. "On the destruction of availability (exergy) due to combustion processes — with specific application to internal-combustion engines," Energy, Elsevier, vol. 25(11), pages 1097-1117.
    2. Rakopoulos, C.D. & Giakoumis, E.G., 2004. "Availability analysis of a turbocharged diesel engine operating under transient load conditions," Energy, Elsevier, vol. 29(8), pages 1085-1104.
    3. Rakopoulos, C.D & Kyritsis, D.C, 2001. "Comparative second-law analysis of internal combustion engine operation for methane, methanol, and dodecane fuels," Energy, Elsevier, vol. 26(7), pages 705-722.
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    Citations

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    1. Wu, Horng-Wen & Wu, Zhan-Yi, 2012. "Combustion characteristics and optimal factors determination with Taguchi method for diesel engines port-injecting hydrogen," Energy, Elsevier, vol. 47(1), pages 411-420.
    2. Rakopoulos, C.D. & Kosmadakis, G.M. & Pariotis, E.G., 2009. "Evaluation of a new computational fluid dynamics model for internal combustion engines using hydrogen under motoring conditions," Energy, Elsevier, vol. 34(12), pages 2158-2166.
    3. Deb, Madhujit & Debbarma, Bishop & Majumder, Arindam & Banerjee, Rahul, 2016. "Performance –emission optimization of a diesel-hydrogen dual fuel operation: A NSGA II coupled TOPSIS MADM approach," Energy, Elsevier, vol. 117(P1), pages 281-290.
    4. Chintala, Venkateswarlu & Subramanian, K.A., 2014. "Assessment of maximum available work of a hydrogen fueled compression ignition engine using exergy analysis," Energy, Elsevier, vol. 67(C), pages 162-175.
    5. Rakopoulos, C.D. & Michos, C.N. & Giakoumis, E.G., 2008. "Availability analysis of a syngas fueled spark ignition engine using a multi-zone combustion model," Energy, Elsevier, vol. 33(9), pages 1378-1398.
    6. Wang, Shuofeng & Ji, Changwei & Zhang, Jian & Zhang, Bo, 2011. "Comparison of the performance of a spark-ignited gasoline engine blended with hydrogen and hydrogen–oxygen mixtures," Energy, Elsevier, vol. 36(10), pages 5832-5837.
    7. Poran, Arnon & Tartakovsky, Leonid, 2015. "Energy efficiency of a direct-injection internal combustion engine with high-pressure methanol steam reforming," Energy, Elsevier, vol. 88(C), pages 506-514.
    8. Wang, Xin & Zhang, Hongguang & Yao, Baofeng & Lei, Yan & Sun, Xiaona & Wang, Daojing & Ge, Yunshan, 2012. "Experimental study on factors affecting lean combustion limit of S.I engine fueled with compressed natural gas and hydrogen blends," Energy, Elsevier, vol. 38(1), pages 58-65.
    9. Hongqing, Feng & Huijie, Li, 2010. "Second-law analyses applied to a spark ignition engine under surrogate fuels for gasoline," Energy, Elsevier, vol. 35(9), pages 3551-3556.
    10. Zhu, Sipeng & Deng, Kangyao & Qu, Shuan, 2013. "Energy and exergy analyses of a bottoming Rankine cycle for engine exhaust heat recovery," Energy, Elsevier, vol. 58(C), pages 448-457.
    11. Channapattana, Shylesha V. & Campli, Srinidhi & Madhusudhan, A. & Notla, Srihari & Arkerimath, Rachayya & Tripathi, Mukesh Kumar, 2023. "Energy analysis of DI-CI engine with nickel oxide nanoparticle added azadirachta indica biofuel at different static injection timing based on exergy," Energy, Elsevier, vol. 267(C).
    12. Rakopoulos, Dimitrios C. & Rakopoulos, Constantine D. & Giakoumis, Evangelos G. & Dimaratos, Athanasios M., 2012. "Characteristics of performance and emissions in high-speed direct injection diesel engine fueled with diethyl ether/diesel fuel blends," Energy, Elsevier, vol. 43(1), pages 214-224.
    13. Duan, Xiongbo & Li, Yangyang & Liu, Jingping & Guo, Genmiao & Fu, Jianqin & Zhang, Quanchang & Zhang, Shiheng & Liu, Weiqiang, 2019. "Experimental study the effects of various compression ratios and spark timing on performance and emission of a lean-burn heavy-duty spark ignition engine fueled with methane gas and hydrogen blends," Energy, Elsevier, vol. 169(C), pages 558-571.
    14. Ma, Baodong & Yao, Anren & Yao, Chunde & Wu, Taoyang & Wang, Bin & Gao, Jian & Chen, Chao, 2020. "Exergy loss analysis on diesel methanol dual fuel engine under different operating parameters," Applied Energy, Elsevier, vol. 261(C).
    15. Park, Cheolwoong & Kim, Changgi & Choi, Young & Lee, Janghee, 2013. "Operating strategy for exhaust gas reduction and performance improvement in a heavy-duty hydrogen-natural gas blend engine," Energy, Elsevier, vol. 50(C), pages 262-269.
    16. Rakopoulos, C.D. & Mavropoulos, G.C., 2008. "Experimental evaluation of local instantaneous heat transfer characteristics in the combustion chamber of air-cooled direct injection diesel engine," Energy, Elsevier, vol. 33(7), pages 1084-1099.

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