IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v313y2024ics0360544224038635.html
   My bibliography  Save this article

New classification of dry and isentropic working fluids based on the subcooled liquid region in temperature-entropy (T-s) diagram

Author

Listed:
  • Zhang, Xinxin
  • Ding, Jiadi

Abstract

The traditional classification of working fluid, which is based on the characteristics of saturated vapor curve in temperature-entropy (T-s) diagram, focuses more on the output power of organic Rankine cycle (ORC). The performance of an ORC is greatly influenced by pump power consumption, which is closely related to the subcooled region and saturated liquid curve of the working fluid. This paper proposes a new classification method of working fluids, which simultaneously considers the curved triangle area in subcooled region (A1), the slope of saturated liquid curve (k), and the pump power consumption (wp). It is discovered that dry working fluids have a larger area of curved triangle in subcooled region and higher pump power consumption compared to isentropic working fluids. Among all the dry or isentropic working fluids studied, halogenated hydrocarbons have the steepest slope of saturated liquid curve. The more silicon in siloxane, the larger the values of A1 and k, however, the smaller the value of wp. On this basis, the ratio of the curved triangle area in subcooled region (A1) to the curved triangle area in superheated region (A2), which is (A1:A2), is used to evaluate the working fluid characteristics. Additionally, the ratio of the net output power (wnet) to the condenser load (qc), which is (wnet:qc), is used to evaluate the ORC performance. It can be determined that D5 (decamethylcyclopentasiloxane) and MD4M (tetradecamethylhexasiloxane) may be the essential working fluids for future ORC design and operation.

Suggested Citation

  • Zhang, Xinxin & Ding, Jiadi, 2024. "New classification of dry and isentropic working fluids based on the subcooled liquid region in temperature-entropy (T-s) diagram," Energy, Elsevier, vol. 313(C).
    • Handle: RePEc:eee:energy:v:313:y:2024:i:c:s0360544224038635
    DOI: 10.1016/j.energy.2024.134085
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544224038635
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2024.134085?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zhang, Xinxin & Zhang, Yin & Wang, Jingfu, 2020. "New classification of dry and isentropic working fluids and a method used to determine their optimal or worst condensation temperature used in Organic Rankine Cycle," Energy, Elsevier, vol. 201(C).
    2. Yu-Ting Wu & Biao Lei & Chong-Fang Ma & Lei Zhao & Jing-Fu Wang & Hang Guo & Yuan-Wei Lu, 2014. "Study on the Characteristics of Expander Power Output Used for Offsetting Pumping Work Consumption in Organic Rankine Cycles," Energies, MDPI, vol. 7(8), pages 1-15, July.
    3. Zhao, Li & Bao, Junjiang, 2014. "Thermodynamic analysis of organic Rankine cycle using zeotropic mixtures," Applied Energy, Elsevier, vol. 130(C), pages 748-756.
    4. Patrick Linke & Athanasios I. Papadopoulos & Panos Seferlis, 2015. "Systematic Methods for Working Fluid Selection and the Design, Integration and Control of Organic Rankine Cycles—A Review," Energies, MDPI, vol. 8(6), pages 1-47, May.
    5. Kuo, Chi-Ron & Hsu, Sung-Wei & Chang, Kai-Han & Wang, Chi-Chuan, 2011. "Analysis of a 50kW organic Rankine cycle system," Energy, Elsevier, vol. 36(10), pages 5877-5885.
    6. Györke, Gábor & Deiters, Ulrich K. & Groniewsky, Axel & Lassu, Imre & Imre, Attila R., 2018. "Novel classification of pure working fluids for Organic Rankine Cycle," Energy, Elsevier, vol. 145(C), pages 288-300.
    7. Gábor Györke & Axel Groniewsky & Attila R. Imre, 2019. "A Simple Method of Finding New Dry and Isentropic Working Fluids for Organic Rankine Cycle," Energies, MDPI, vol. 12(3), pages 1-11, February.
    8. Attila R. Imre & Réka Kustán & Axel Groniewsky, 2019. "Thermodynamic Selection of the Optimal Working Fluid for Organic Rankine Cycles," Energies, MDPI, vol. 12(10), pages 1-15, May.
    9. Liu, Bo-Tau & Chien, Kuo-Hsiang & Wang, Chi-Chuan, 2004. "Effect of working fluids on organic Rankine cycle for waste heat recovery," Energy, Elsevier, vol. 29(8), pages 1207-1217.
    10. Chen, Huijuan & Goswami, D. Yogi & Stefanakos, Elias K., 2010. "A review of thermodynamic cycles and working fluids for the conversion of low-grade heat," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(9), pages 3059-3067, December.
    11. Badr, O. & Probert, S.D. & O'Callaghan, P.W., 1985. "Selecting a working fluid for a Rankine-cycle engine," Applied Energy, Elsevier, vol. 21(1), pages 1-42.
    12. Desai, Nishith B. & Bandyopadhyay, Santanu, 2009. "Process integration of organic Rankine cycle," Energy, Elsevier, vol. 34(10), pages 1674-1686.
    13. Landelle, Arnaud & Tauveron, Nicolas & Haberschill, Philippe & Revellin, Rémi & Colasson, Stéphane, 2017. "Organic Rankine cycle design and performance comparison based on experimental database," Applied Energy, Elsevier, vol. 204(C), pages 1172-1187.
    14. Kang, Seok Hun, 2012. "Design and experimental study of ORC (organic Rankine cycle) and radial turbine using R245fa working fluid," Energy, Elsevier, vol. 41(1), pages 514-524.
    15. Ping, Xu & Yang, Fubin & Zhang, Hongguang & Xing, Chengda & Yu, Mingzhe & Wang, Yan, 2023. "Investigation and multi-objective optimization of vehicle engine-organic Rankine cycle (ORC) combined system in different driving conditions," Energy, Elsevier, vol. 263(PB).
    16. Su, Wen & Zhao, Li & Deng, Shuai, 2017. "New knowledge on the temperature-entropy saturation boundary slope of working fluids," Energy, Elsevier, vol. 119(C), pages 211-217.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Bao, Junjiang & Zhao, Li, 2013. "A review of working fluid and expander selections for organic Rankine cycle," Renewable and Sustainable Energy Reviews, Elsevier, vol. 24(C), pages 325-342.
    2. Xinxin Zhang & Yin Zhang & Min Cao & Jingfu Wang & Yuting Wu & Chongfang Ma, 2019. "Working Fluid Selection for Organic Rankine Cycle Using Single-Screw Expander," Energies, MDPI, vol. 12(16), pages 1-23, August.
    3. Xinxin Zhang & Yin Zhang & Zhenlei Li & Jingfu Wang & Yuting Wu & Chongfang Ma, 2020. "Zeotropic Mixture Selection for an Organic Rankine Cycle Using a Single Screw Expander," Energies, MDPI, vol. 13(5), pages 1-20, February.
    4. Wang, Dongxiang & Ling, Xiang & Peng, Hao & Liu, Lin & Tao, LanLan, 2013. "Efficiency and optimal performance evaluation of organic Rankine cycle for low grade waste heat power generation," Energy, Elsevier, vol. 50(C), pages 343-352.
    5. Xu, Weicong & Zhao, Li & Mao, Samuel S. & Deng, Shuai, 2020. "Towards novel low temperature thermodynamic cycle: A critical review originated from organic Rankine cycle," Applied Energy, Elsevier, vol. 270(C).
    6. He, Chao & Liu, Chao & Zhou, Mengtong & Xie, Hui & Xu, Xiaoxiao & Wu, Shuangying & Li, Yourong, 2014. "A new selection principle of working fluids for subcritical organic Rankine cycle coupling with different heat sources," Energy, Elsevier, vol. 68(C), pages 283-291.
    7. Zhang, Xinxin & Li, Yingzhen, 2024. "Recommended operating conditions and performance evaluation of commonly used hydrofluoroolefin (HFO) and hydrochlorofluoroolefin (HCFO) refrigerants in organic Rankine cycle," Energy, Elsevier, vol. 299(C).
    8. Tchanche, Bertrand F. & Lambrinos, Gr. & Frangoudakis, A. & Papadakis, G., 2011. "Low-grade heat conversion into power using organic Rankine cycles – A review of various applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3963-3979.
    9. Attila R. Imre & Réka Kustán & Axel Groniewsky, 2020. "Mapping of the Temperature–Entropy Diagrams of van der Waals Fluids," Energies, MDPI, vol. 13(6), pages 1-15, March.
    10. Daniarta, Sindu & Nemś, Magdalena & Kolasiński, Piotr, 2023. "A review on thermal energy storage applicable for low- and medium-temperature organic Rankine cycle," Energy, Elsevier, vol. 278(PA).
    11. Juan A. White & Santiago Velasco, 2019. "Approximating the Temperature–Entropy Saturation Curve of ORC Working Fluids From the Ideal Gas Isobaric Heat Capacity," Energies, MDPI, vol. 12(17), pages 1-14, August.
    12. Steven Lecompte & Sanne Lemmens & Henk Huisseune & Martijn Van den Broek & Michel De Paepe, 2015. "Multi-Objective Thermo-Economic Optimization Strategy for ORCs Applied to Subcritical and Transcritical Cycles for Waste Heat Recovery," Energies, MDPI, vol. 8(4), pages 1-28, April.
    13. Lecompte, Steven & Huisseune, Henk & van den Broek, Martijn & Vanslambrouck, Bruno & De Paepe, Michel, 2015. "Review of organic Rankine cycle (ORC) architectures for waste heat recovery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 47(C), pages 448-461.
    14. Aram Mohammed Ahmed & László Kondor & Attila R. Imre, 2021. "Thermodynamic Efficiency Maximum of Simple Organic Rankine Cycles," Energies, MDPI, vol. 14(2), pages 1-17, January.
    15. González, Johan & Llovell, Fèlix & Garrido, José Matías & Quinteros-Lama, Héctor, 2022. "A rigorous approach for characterising the limiting optimal efficiency of working fluids in organic Rankine cycles," Energy, Elsevier, vol. 254(PA).
    16. Larsen, Ulrik & Pierobon, Leonardo & Haglind, Fredrik & Gabrielii, Cecilia, 2013. "Design and optimisation of organic Rankine cycles for waste heat recovery in marine applications using the principles of natural selection," Energy, Elsevier, vol. 55(C), pages 803-812.
    17. Vélez, Fredy & Segovia, José J. & Martín, M. Carmen & Antolín, Gregorio & Chejne, Farid & Quijano, Ana, 2012. "A technical, economical and market review of organic Rankine cycles for the conversion of low-grade heat for power generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 4175-4189.
    18. Lecompte, S. & Huisseune, H. & van den Broek, M. & De Paepe, M., 2015. "Methodical thermodynamic analysis and regression models of organic Rankine cycle architectures for waste heat recovery," Energy, Elsevier, vol. 87(C), pages 60-76.
    19. Ayachi, Fadhel & Ksayer, Elias Boulawz & Neveu, Pierre & Zoughaib, Assaad, 2016. "Experimental investigation and modeling of a hermetic scroll expander," Applied Energy, Elsevier, vol. 181(C), pages 256-267.
    20. Li, Jing & Alvi, Jahan Zeb & Pei, Gang & Su, Yuehong & Li, Pengcheng & Gao, Guangtao & Ji, Jie, 2016. "Modelling of organic Rankine cycle efficiency with respect to the equivalent hot side temperature," Energy, Elsevier, vol. 115(P1), pages 668-683.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:313:y:2024:i:c:s0360544224038635. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.