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Thermodynamic Selection of the Optimal Working Fluid for Organic Rankine Cycles

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  • Attila R. Imre

    (Department of Energy Engineering, Budapest University of Technology and Economics, Muegyetem rkp. 3, H-1111 Budapest, Hungary
    Centre for Energy Research, Department of Thermohydraulics, Hungarian Academy of Science, P.O. Box 49, H-1525 Budapest, Hungary)

  • Réka Kustán

    (Department of Energy Engineering, Budapest University of Technology and Economics, Muegyetem rkp. 3, H-1111 Budapest, Hungary)

  • Axel Groniewsky

    (Department of Energy Engineering, Budapest University of Technology and Economics, Muegyetem rkp. 3, H-1111 Budapest, Hungary)

Abstract

A novel method proposed to choose the optimal working fluid—solely from the point of view of expansion route—for a given heat source and heat sink (characterized by a maximum and minimum temperature). The basis of this method is the novel classification of working fluids using the sequences of their characteristic points on temperature-entropy space. The most suitable existing working fluid can be selected, where an ideal adiabatic (isentropic) expansion step between a given upper and lower temperature is possible in a way, that the initial and final states are both saturated vapour states and the ideal (isentropic) expansion line runs in the superheated (dry) vapour region all along the expansion. Problems related to the presence of droplets or superheated dry steam in the final expansion state can be avoided or minimized by using the working fluid chosen with this method. Results obtained with real materials are compared with those gained with model (van der Waals) fluids; based on the results obtained with model fluids, erroneous experimental data-sets can be pinpointed. Since most of the known working fluids have optimal expansion routes at low temperatures, presently the method is most suitable to choose working fluids for cryogenic cycles, applied for example for heat recovery during LNG-regasification. Some of the materials, however, can be applied in ranges located at relatively higher temperatures, therefore the method can also be applied in some limited manner for the utilization of other low temperature heat sources (like geothermal or waste heat) as well.

Suggested Citation

  • Attila R. Imre & Réka Kustán & Axel Groniewsky, 2019. "Thermodynamic Selection of the Optimal Working Fluid for Organic Rankine Cycles," Energies, MDPI, vol. 12(10), pages 1-15, May.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:10:p:2028-:d:234699
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    References listed on IDEAS

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    Cited by:

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    3. Piotr Kolasiński, 2020. "Domestic Organic Rankine Cycle-Based Cogeneration Systems as a Way to Reduce Dust Emissions in Municipal Heating," Energies, MDPI, vol. 13(15), pages 1-22, August.
    4. Zoltán Csedő & Botond Sinóros-Szabó & Máté Zavarkó, 2020. "Seasonal Energy Storage Potential Assessment of WWTPs with Power-to-Methane Technology," Energies, MDPI, vol. 13(18), pages 1-21, September.
    5. Juan A. White & Santiago Velasco, 2019. "Approximating the Temperature–Entropy Saturation Curve of ORC Working Fluids From the Ideal Gas Isobaric Heat Capacity," Energies, MDPI, vol. 12(17), pages 1-14, August.
    6. Andrea Arbula Blecich & Paolo Blecich, 2023. "Thermoeconomic Analysis of Subcritical and Supercritical Isobutane Cycles for Geothermal Power Generation," Sustainability, MDPI, vol. 15(11), pages 1-25, May.
    7. Piotr Kolasiński, 2020. "The Method of the Working Fluid Selection for Organic Rankine Cycle (ORC) Systems Employing Volumetric Expanders," Energies, MDPI, vol. 13(3), pages 1-28, January.
    8. Attila R. Imre & Réka Kustán & Axel Groniewsky, 2020. "Mapping of the Temperature–Entropy Diagrams of van der Waals Fluids," Energies, MDPI, vol. 13(6), pages 1-15, March.
    9. Aram Mohammed Ahmed & László Kondor & Attila R. Imre, 2021. "Thermodynamic Efficiency Maximum of Simple Organic Rankine Cycles," Energies, MDPI, vol. 14(2), pages 1-17, January.
    10. Daniarta, Sindu & Nemś, Magdalena & Kolasiński, Piotr, 2023. "A review on thermal energy storage applicable for low- and medium-temperature organic Rankine cycle," Energy, Elsevier, vol. 278(PA).
    11. Xinxin Zhang & Yin Zhang & Min Cao & Jingfu Wang & Yuting Wu & Chongfang Ma, 2019. "Working Fluid Selection for Organic Rankine Cycle Using Single-Screw Expander," Energies, MDPI, vol. 12(16), pages 1-23, August.
    12. Xinxin Zhang & Yin Zhang & Zhenlei Li & Jingfu Wang & Yuting Wu & Chongfang Ma, 2020. "Zeotropic Mixture Selection for an Organic Rankine Cycle Using a Single Screw Expander," Energies, MDPI, vol. 13(5), pages 1-20, February.
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    14. González, Johan & Llovell, Fèlix & Garrido, José Matías & Quinteros-Lama, Héctor, 2022. "A rigorous approach for characterising the limiting optimal efficiency of working fluids in organic Rankine cycles," Energy, Elsevier, vol. 254(PA).

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