IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v254y2022ipbs0360544222012221.html
   My bibliography  Save this article

A computational drop-in assessment of hydrofluoroethers in Organic Rankine Cycles

Author

Listed:
  • Jovell, Daniel
  • Gonzalez-Olmos, Rafael
  • Llovell, Fèlix

Abstract

Organic Rankine Cycles (ORCs) are experiencing a growing interest due to their ability to generate electricity from residual low waste heat sources. HFC-245fa is a representative working fluid for ORC applications, but it has recently been phased-out in new equipment because of its high global warming potential (GWP). In this work, the soft-SAFT molecular-based equation of state is used to evaluate the capacity of nine promising low-GWP hydrofluoroethers (HFEs) as alternative working fluids in ORC applications using different key performance indicators focused on energy efficiency and service fluids consumption. The thermodynamic model has been employed to characterize these fluids by describing saturated densities, vapor pressure, surface tension, temperature-enthalpy, and temperature-entropy diagrams, including further validation with binary mixtures. Then, based on technical criteria focused on the thermal efficiency and working and service fluids consumption, the soft-SAFT model has been used to conduct a feasibility study of HFEs as direct substitutes for HFC-245fa in such applications. Although pure fluids can not reach the same efficiency as the benchmark, HFE-356mmz, HFE-7000, and HFE-7100 appear as promising replacements, capable of approaching system requirements operating at low pressure with low cooling water and heating fluid flow rates, while exhibiting lower GWP values.

Suggested Citation

  • Jovell, Daniel & Gonzalez-Olmos, Rafael & Llovell, Fèlix, 2022. "A computational drop-in assessment of hydrofluoroethers in Organic Rankine Cycles," Energy, Elsevier, vol. 254(PB).
    • Handle: RePEc:eee:energy:v:254:y:2022:i:pb:s0360544222012221
    DOI: 10.1016/j.energy.2022.124319
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544222012221
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2022.124319?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Petr, Philipp & Raabe, Gabriele, 2015. "Evaluation of R-1234ze(Z) as drop-in replacement for R-245fa in Organic Rankine Cycles – From thermophysical properties to cycle performance," Energy, Elsevier, vol. 93(P1), pages 266-274.
    2. Albornoz, Jorge & Mejía, Andrés & Quinteros-Lama, Héctor & Garrido, José Matías, 2018. "A rigorous and accurate approach for predicting the wet-to-dry transition for working mixtures in organic Rankine cycles," Energy, Elsevier, vol. 156(C), pages 509-519.
    3. Garrido, José Matías & Quinteros-Lama, Héctor & Mejía, Andrés & Wisniak, Jaime & Segura, Hugo, 2012. "A rigorous approach for predicting the slope and curvature of the temperature–entropy saturation boundary of pure fluids," Energy, Elsevier, vol. 45(1), pages 888-899.
    4. van Kleef, Luuk M.T. & Oyewunmi, Oyeniyi A. & Markides, Christos N., 2019. "Multi-objective thermo-economic optimization of organic Rankine cycle (ORC) power systems in waste-heat recovery applications using computer-aided molecular design techniques," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    5. Pereira, Luís M.C. & Llovell, Fèlix & Vega, Lourdes F., 2018. "Thermodynamic characterisation of aqueous alkanolamine and amine solutions for acid gas processing by transferable molecular models," Applied Energy, Elsevier, vol. 222(C), pages 687-703.
    6. White, M.T. & Oyewunmi, O.A. & Chatzopoulou, M.A. & Pantaleo, A.M. & Haslam, A.J. & Markides, C.N., 2018. "Computer-aided working-fluid design, thermodynamic optimisation and thermoeconomic assessment of ORC systems for waste-heat recovery," Energy, Elsevier, vol. 161(C), pages 1181-1198.
    7. Eyerer, Sebastian & Dawo, Fabian & Kaindl, Johannes & Wieland, Christoph & Spliethoff, Hartmut, 2019. "Experimental investigation of modern ORC working fluids R1224yd(Z) and R1233zd(E) as replacements for R245fa," Applied Energy, Elsevier, vol. 240(C), pages 946-963.
    8. Oyewunmi, Oyeniyi A. & Taleb, Aly I. & Haslam, Andrew J. & Markides, Christos N., 2016. "On the use of SAFT-VR Mie for assessing large-glide fluorocarbon working-fluid mixtures in organic Rankine cycles," Applied Energy, Elsevier, vol. 163(C), pages 263-282.
    9. Eyerer, Sebastian & Wieland, Christoph & Vandersickel, Annelies & Spliethoff, Hartmut, 2016. "Experimental study of an ORC (Organic Rankine Cycle) and analysis of R1233zd-E as a drop-in replacement for R245fa for low temperature heat utilization," Energy, Elsevier, vol. 103(C), pages 660-671.
    10. Tchanche, Bertrand F. & Lambrinos, Gr. & Frangoudakis, A. & Papadakis, G., 2011. "Low-grade heat conversion into power using organic Rankine cycles – A review of various applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3963-3979.
    11. Yang, Jingye & Ye, Zhenhong & Yu, Binbin & Ouyang, Hongsheng & Chen, Jiangping, 2019. "Simultaneous experimental comparison of low-GWP refrigerants as drop-in replacements to R245fa for Organic Rankine cycle application: R1234ze(Z), R1233zd(E), and R1336mzz(E)," Energy, Elsevier, vol. 173(C), pages 721-731.
    12. Pereira, Luís M.C. & Vega, Lourdes F., 2018. "A systematic approach for the thermodynamic modelling of CO2-amine absorption process using molecular-based models," Applied Energy, Elsevier, vol. 232(C), pages 273-291.
    13. Quoilin, Sylvain & Broek, Martijn Van Den & Declaye, Sébastien & Dewallef, Pierre & Lemort, Vincent, 2013. "Techno-economic survey of Organic Rankine Cycle (ORC) systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 168-186.
    14. Qiu, Guoquan, 2012. "Selection of working fluids for micro-CHP systems with ORC," Renewable Energy, Elsevier, vol. 48(C), pages 565-570.
    15. Chen, Huijuan & Goswami, D. Yogi & Stefanakos, Elias K., 2010. "A review of thermodynamic cycles and working fluids for the conversion of low-grade heat," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(9), pages 3059-3067, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xia, Xiaoxia & Liu, Zhipeng & Wang, Zhiqi & Sun, Tong & Zhang, Hualong, 2023. "Multi-layer performance optimization based on operation parameter-working fluid-heat source for the ORC-VCR system," Energy, Elsevier, vol. 272(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Bamorovat Abadi, Gholamreza & Kim, Kyung Chun, 2017. "Investigation of organic Rankine cycles with zeotropic mixtures as a working fluid: Advantages and issues," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 1000-1013.
    2. Cavazzini, G. & Bari, S. & Pavesi, G. & Ardizzon, G., 2017. "A multi-fluid PSO-based algorithm for the search of the best performance of sub-critical Organic Rankine Cycles," Energy, Elsevier, vol. 129(C), pages 42-58.
    3. Gábor Györke & Axel Groniewsky & Attila R. Imre, 2019. "A Simple Method of Finding New Dry and Isentropic Working Fluids for Organic Rankine Cycle," Energies, MDPI, vol. 12(3), pages 1-11, February.
    4. Schilling, J. & Entrup, M. & Hopp, M. & Gross, J. & Bardow, A., 2021. "Towards optimal mixtures of working fluids: Integrated design of processes and mixtures for Organic Rankine Cycles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    5. van Kleef, Luuk M.T. & Oyewunmi, Oyeniyi A. & Markides, Christos N., 2019. "Multi-objective thermo-economic optimization of organic Rankine cycle (ORC) power systems in waste-heat recovery applications using computer-aided molecular design techniques," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    6. Steven Lecompte & Oyeniyi A. Oyewunmi & Christos N. Markides & Marija Lazova & Alihan Kaya & Martijn Van den Broek & Michel De Paepe, 2017. "Case Study of an Organic Rankine Cycle (ORC) for Waste Heat Recovery from an Electric Arc Furnace (EAF)," Energies, MDPI, vol. 10(5), pages 1-16, May.
    7. Li, Xiaoya & Xu, Bin & Tian, Hua & Shu, Gequn, 2021. "Towards a novel holistic design of organic Rankine cycle (ORC) systems operating under heat source fluctuations and intermittency," Renewable and Sustainable Energy Reviews, Elsevier, vol. 147(C).
    8. Eyerer, Sebastian & Dawo, Fabian & Kaindl, Johannes & Wieland, Christoph & Spliethoff, Hartmut, 2019. "Experimental investigation of modern ORC working fluids R1224yd(Z) and R1233zd(E) as replacements for R245fa," Applied Energy, Elsevier, vol. 240(C), pages 946-963.
    9. Xinxin Zhang & Yin Zhang & Min Cao & Jingfu Wang & Yuting Wu & Chongfang Ma, 2019. "Working Fluid Selection for Organic Rankine Cycle Using Single-Screw Expander," Energies, MDPI, vol. 12(16), pages 1-23, August.
    10. Giuffrida, Antonio, 2018. "A theoretical study on the performance of a scroll expander in an organic Rankine cycle with hydrofluoroolefins (HFOs) in place of R245fa," Energy, Elsevier, vol. 161(C), pages 1172-1180.
    11. Bao, Junjiang & Zhao, Li, 2013. "A review of working fluid and expander selections for organic Rankine cycle," Renewable and Sustainable Energy Reviews, Elsevier, vol. 24(C), pages 325-342.
    12. Wieland, Christoph & Meinel, Dominik & Eyerer, Sebastian & Spliethoff, Hartmut, 2016. "Innovative CHP concept for ORC and its benefit compared to conventional concepts," Applied Energy, Elsevier, vol. 183(C), pages 478-490.
    13. Yang, Jingye & Gao, Lei & Ye, Zhenhong & Hwang, Yunho & Chen, Jiangping, 2021. "Binary-objective optimization of latest low-GWP alternatives to R245fa for organic Rankine cycle application," Energy, Elsevier, vol. 217(C).
    14. Peris, Bernardo & Navarro-Esbrí, Joaquín & Mateu-Royo, Carlos & Mota-Babiloni, Adrián & Molés, Francisco & Gutiérrez-Trashorras, Antonio J. & Amat-Albuixech, Marta, 2020. "Thermo-economic optimization of small-scale Organic Rankine Cycle: A case study for low-grade industrial waste heat recovery," Energy, Elsevier, vol. 213(C).
    15. Attila R. Imre & Réka Kustán & Axel Groniewsky, 2020. "Mapping of the Temperature–Entropy Diagrams of van der Waals Fluids," Energies, MDPI, vol. 13(6), pages 1-15, March.
    16. Zhou, Feng & Joshi, Shailesh N. & Rhote-Vaney, Raphael & Dede, Ercan M., 2017. "A review and future application of Rankine Cycle to passenger vehicles for waste heat recovery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 75(C), pages 1008-1021.
    17. Imran, Muhammad & Haglind, Fredrik & Asim, Muhammad & Zeb Alvi, Jahan, 2018. "Recent research trends in organic Rankine cycle technology: A bibliometric approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 552-562.
    18. Braimakis, Konstantinos & Karellas, Sotirios, 2017. "Integrated thermoeconomic optimization of standard and regenerative ORC for different heat source types and capacities," Energy, Elsevier, vol. 121(C), pages 570-598.
    19. Oko, C.O.C. & Njoku, I.H., 2017. "Performance analysis of an integrated gas-, steam- and organic fluid-cycle thermal power plant," Energy, Elsevier, vol. 122(C), pages 431-443.
    20. Lecompte, S. & Huisseune, H. & van den Broek, M. & De Paepe, M., 2015. "Methodical thermodynamic analysis and regression models of organic Rankine cycle architectures for waste heat recovery," Energy, Elsevier, vol. 87(C), pages 60-76.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:254:y:2022:i:pb:s0360544222012221. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.