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Catalytic cracking of biomass tar using Ni nanoparticles embedded carbon nanofiber/porous carbon catalysts

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  • Zhang, Shuping
  • Yin, Haoxin
  • Wang, Jiaxing
  • Zhu, Shuguang
  • Xiong, Yuanquan

Abstract

The major obstacles for catalytic cracking of biomass tar have been known as the low tar removal efficiency and catalyst deactivation. In view of this, the novel Ni nanoparticles embedded carbon nanofiber/porous carbon catalysts were synthesized by the method of hydrothermal treatment combined with carbothermal reduction. The properties of catalysts were evaluated by characterization of N2 adsorption-desorption, SEM, XRD, TEM, H2-TPRand Raman, meanwhile the evolutionary mechanism of catalysts was also proposed. The tar catalytic cracking tests indicated that the Ni0.30@CF/PCs exhibited the favorable catalytic activity with the high tar conversion efficiency (94.78%) as well as the better catalytic stability at the catalytic cracking temperature of 700 °C compared to other catalysts. In the case of Ni0.30@CF/PCs, the carbon nanofiber/porous carbon composites with hierarchical micro-mesoporous structure and high graphitization degree as well as the Ni nanoparticles embedded in catalyst support with the strong metal-support interaction exhibited the favorable activity-structure relationship. In addition, the Ni0.30@CF/PCs catalyst also presented the high tar conversion efficiency of 93.31% after 10 cycles, which was due to the high resistance towards coke deposition and sintering of metallic Ni covered by graphite layer from the carbothermal reduction process.

Suggested Citation

  • Zhang, Shuping & Yin, Haoxin & Wang, Jiaxing & Zhu, Shuguang & Xiong, Yuanquan, 2021. "Catalytic cracking of biomass tar using Ni nanoparticles embedded carbon nanofiber/porous carbon catalysts," Energy, Elsevier, vol. 216(C).
    • Handle: RePEc:eee:energy:v:216:y:2021:i:c:s0360544220323926
    DOI: 10.1016/j.energy.2020.119285
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    1. Lee, Jechan & Kim, Ki-Hyun & Kwon, Eilhann E., 2017. "Biochar as a Catalyst," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 70-79.
    2. Anis, Samsudin & Zainal, Z.A., 2011. "Tar reduction in biomass producer gas via mechanical, catalytic and thermal methods: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(5), pages 2355-2377, June.
    3. Shen, Yafei, 2015. "Chars as carbonaceous adsorbents/catalysts for tar elimination during biomass pyrolysis or gasification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 281-295.
    4. Hu, Mian & Laghari, Mahmood & Cui, Baihui & Xiao, Bo & Zhang, Beiping & Guo, Dabin, 2018. "Catalytic cracking of biomass tar over char supported nickel catalyst," Energy, Elsevier, vol. 145(C), pages 228-237.
    5. Zhang, Zhikun & Liu, Lina & Shen, Boxiong & Wu, Chunfei, 2018. "Preparation, modification and development of Ni-based catalysts for catalytic reforming of tar produced from biomass gasification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 1086-1109.
    6. Park, Seo Yun & Oh, Gunung & Kim, Kwangyul & Seo, Myung Won & Ra, Ho Won & Mun, Tae Young & Lee, Jae Goo & Yoon, Sang Jun, 2017. "Deactivation characteristics of Ni and Ru catalysts in tar steam reforming," Renewable Energy, Elsevier, vol. 105(C), pages 76-83.
    7. Ravenni, G. & Elhami, O.H. & Ahrenfeldt, J. & Henriksen, U.B. & Neubauer, Y., 2019. "Adsorption and decomposition of tar model compounds over the surface of gasification char and active carbon within the temperature range 250–800 °C," Applied Energy, Elsevier, vol. 241(C), pages 139-151.
    8. Du, Boyu & Liu, Chao & Wang, Xing & Han, Ying & Guo, Yanzhu & Li, Haiming & Zhou, Jinghui, 2020. "Renewable lignin-based carbon nanofiber as Ni catalyst support for depolymerization of lignin to phenols in supercritical ethanol/water," Renewable Energy, Elsevier, vol. 147(P1), pages 1331-1339.
    9. Wang, Keliang & Cao, Yuhe & Wang, Xiaomin & Kharel, Parashu Ram & Gibbons, William & Luo, Bing & Gu, Zhengrong & Fan, Qihua & Metzger, Lloyd, 2016. "Nickel catalytic graphitized porous carbon as electrode material for high performance supercapacitors," Energy, Elsevier, vol. 101(C), pages 9-15.
    10. Cheng, Long & Wu, Zhiqiang & Zhang, Zhiguo & Guo, Changqing & Ellis, Naoko & Bi, Xiaotao & Paul Watkinson, A. & Grace, John R., 2020. "Tar elimination from biomass gasification syngas with bauxite residue derived catalysts and gasification char," Applied Energy, Elsevier, vol. 258(C).
    11. Zou, Xuehua & Chen, Tianhu & Zhang, Ping & Chen, Dong & He, Junkai & Dang, Yanliu & Ma, Zhiyuan & Chen, Ye & Toloueinia, Panteha & Zhu, Chengzhu & Xie, Jingjing & Liu, Haibo & Suib, Steven L., 2018. "High catalytic performance of Fe-Ni/Palygorskite in the steam reforming of toluene for hydrogen production," Applied Energy, Elsevier, vol. 226(C), pages 827-837.
    12. Chen, Dong & Wang, Wenju & Liu, Chenlong, 2020. "Hydrogen production through glycerol steam reforming over beehive-biomimetic graphene-encapsulated nickel catalysts," Renewable Energy, Elsevier, vol. 145(C), pages 2647-2657.
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