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Renewable lignin-based carbon nanofiber as Ni catalyst support for depolymerization of lignin to phenols in supercritical ethanol/water

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  • Du, Boyu
  • Liu, Chao
  • Wang, Xing
  • Han, Ying
  • Guo, Yanzhu
  • Li, Haiming
  • Zhou, Jinghui

Abstract

Lignin represents the most abundant source of renewable aromatic resources, and depolymerization of lignin has been shown to be a prominent challenge in the production of low-molecular-mass aromatic chemicals. Herein, we report the preparation of Ni/LCNF catalyst by which Ni nanoparticles were inlaid in lignin-based carbon nanofibers (LCNF) to improve stability of the catalyst and adjust the interaction between the metal and its support. We also present its use in lignin depolymerization. The use of 10%Ni/LCNF catalyst resulted in exceptionally high yields of light lignin fragments (87%) and phenols (7%). The average molecular weight (Mw) of light lignin residue was significantly lower than that of the untreated lignin, and there was clear evidence of lignin depolymerization. Preliminary recycling studies showed that the Ni/LCNF catalyst could maintain its activity for over three recycling cycles; its selectivity towards phenols remained unchanged. The present method, in which Ni nanoparticles were inserted or partially embedded in carbon materials to avoid Ni nanoparticle aggregation, sintering and loss during lignin depolymerization, is an alternative way that can be applied to maximize the utilization of lignin.

Suggested Citation

  • Du, Boyu & Liu, Chao & Wang, Xing & Han, Ying & Guo, Yanzhu & Li, Haiming & Zhou, Jinghui, 2020. "Renewable lignin-based carbon nanofiber as Ni catalyst support for depolymerization of lignin to phenols in supercritical ethanol/water," Renewable Energy, Elsevier, vol. 147(P1), pages 1331-1339.
    • Handle: RePEc:eee:renene:v:147:y:2020:i:p1:p:1331-1339
    DOI: 10.1016/j.renene.2019.09.108
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    References listed on IDEAS

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    1. Azadi, Pooya & Inderwildi, Oliver R. & Farnood, Ramin & King, David A., 2013. "Liquid fuels, hydrogen and chemicals from lignin: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 506-523.
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    1. Zhou, Man & Li, Kai & Hu, Jinguang & Tang, Liping & Li, Mingliu & Su, Lifang & Zhao, Hong & Ko, Frank & Cai, Zaisheng & Zhao, Yaping, 2022. "Sustainable production of oxygen-rich hierarchically porous carbon network from corn straw lignin and silk degumming wastewater for high-performance electrochemical energy storage," Renewable Energy, Elsevier, vol. 191(C), pages 141-150.
    2. Zhang, Shuping & Yin, Haoxin & Wang, Jiaxing & Zhu, Shuguang & Xiong, Yuanquan, 2021. "Catalytic cracking of biomass tar using Ni nanoparticles embedded carbon nanofiber/porous carbon catalysts," Energy, Elsevier, vol. 216(C).
    3. Biswas, Bijoy & Kumar, Avnish & Krishna, Bhavya B. & Bhaskar, Thallada, 2021. "Effects of solid base catalysts on depolymerization of alkali lignin for the production of phenolic monomer compounds," Renewable Energy, Elsevier, vol. 175(C), pages 270-280.

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