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Effect of supercritical CO2 saturation pressures and temperatures on the methane adsorption behaviours of Longmaxi shale

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  • Qin, Chao
  • Jiang, Yongdong
  • Luo, Yahuang
  • Zhou, Junping
  • Liu, Hao
  • Song, Xiao
  • Li, Dong
  • Zhou, Feng
  • Xie, Yingliang

Abstract

To investigate the effects of supercritical CO2 (SC–CO2) saturation pressures and temperatures on the methane adsorption capacity of shale, total organic carbon (TOC) analysis, X-ray diffraction (XRD) analysis, scanning electron microscope and energy dispersive spectrometer (SEM/EDS) analysis, low-pressure N2 adsorption (LP-NA), and high-pressure methane adsorption (HP-MA) were conducted on raw and SC–CO2–saturated (8, 12, 16 MPa; 40, 60, 80 °C) shale collected from the Sichuan Basin. Results indicate that the excess adsorption isotherm of shale to methane clearly exhibited excess adsorption characteristics with increasing adsorption pressures. This excess methane adsorption capacity decreased after SC-CO2 saturation and is mainly attributable to decreases in the TOC content, clay minerals and specific surface area (SSA) in the SC–CO2–saturated shale. The density of adsorbed phase methane was considered at different adsorption models, and the results suggest that the Langmuir-Freundlich (LF) and Dubinin-Astakhov (DA) models better describe methane adsorption behaviours than the Langmuir and Ono-kondo models. The methane adsorption capacity of shale is closely related to the solubility of SC-CO2, which decreased significantly with increasing SC-CO2 saturation time and pressure, while the influence of SC-CO2 saturation temperatures was not evident at low-pressure (8 MPa). This study provides a theoretical reference for CO2 enhanced shale gas recovery.

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  • Qin, Chao & Jiang, Yongdong & Luo, Yahuang & Zhou, Junping & Liu, Hao & Song, Xiao & Li, Dong & Zhou, Feng & Xie, Yingliang, 2020. "Effect of supercritical CO2 saturation pressures and temperatures on the methane adsorption behaviours of Longmaxi shale," Energy, Elsevier, vol. 206(C).
    • Handle: RePEc:eee:energy:v:206:y:2020:i:c:s0360544220312573
    DOI: 10.1016/j.energy.2020.118150
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    1. Wang, Lei & Yao, Bowen & Xie, Haojun & Winterfeld, Philip H. & Kneafsey, Timothy J. & Yin, Xiaolong & Wu, Yu-Shu, 2017. "CO2 injection-induced fracturing in naturally fractured shale rocks," Energy, Elsevier, vol. 139(C), pages 1094-1110.
    2. Lyu, Qiao & Long, Xinping & Ranjith, P.G. & Tan, Jingqiang & Kang, Yong & Wang, Zhanghu, 2018. "Experimental investigation on the mechanical properties of a low-clay shale with different adsorption times in sub-/super-critical CO2," Energy, Elsevier, vol. 147(C), pages 1288-1298.
    3. Yin, Hong & Zhou, Junping & Xian, Xuefu & Jiang, Yongdong & Lu, Zhaohui & Tan, Jingqiang & Liu, Guojun, 2017. "Experimental study of the effects of sub- and super-critical CO2 saturation on the mechanical characteristics of organic-rich shales," Energy, Elsevier, vol. 132(C), pages 84-95.
    4. Feng, Gan & Kang, Yong & Sun, Ze-dong & Wang, Xiao-chuan & Hu, Yao-qing, 2019. "Effects of supercritical CO2 adsorption on the mechanical characteristics and failure mechanisms of shale," Energy, Elsevier, vol. 173(C), pages 870-882.
    5. Ju, Yang & He, Jian & Chang, Elliot & Zheng, Liange, 2019. "Quantification of CH4 adsorption capacity in kerogen-rich reservoir shales: An experimental investigation and molecular dynamic simulation," Energy, Elsevier, vol. 170(C), pages 411-422.
    6. McGlade, Christophe & Speirs, Jamie & Sorrell, Steve, 2013. "Unconventional gas – A review of regional and global resource estimates," Energy, Elsevier, vol. 55(C), pages 571-584.
    7. Umeozor, Evar C. & Jordaan, Sarah M. & Gates, Ian D., 2018. "On methane emissions from shale gas development," Energy, Elsevier, vol. 152(C), pages 594-600.
    8. Lu, Yiyu & Chen, Xiayu & Tang, Jiren & Li, Honglian & Zhou, Lei & Han, Shuaibin & Ge, Zhaolong & Xia, Binwei & Shen, Huajian & Zhang, Jing, 2019. "Relationship between pore structure and mechanical properties of shale on supercritical carbon dioxide saturation," Energy, Elsevier, vol. 172(C), pages 270-285.
    9. Jiang, Yongdong & Luo, Yahuang & Lu, Yiyu & Qin, Chao & Liu, Hui, 2016. "Effects of supercritical CO2 treatment time, pressure, and temperature on microstructure of shale," Energy, Elsevier, vol. 97(C), pages 173-181.
    10. Chen, Shangbin & Zhu, Yanming & Wang, Hongyan & Liu, Honglin & Wei, Wei & Fang, Junhua, 2011. "Shale gas reservoir characterisation: A typical case in the southern Sichuan Basin of China," Energy, Elsevier, vol. 36(11), pages 6609-6616.
    11. Zeng, Bo & Duan, Huiming & Bai, Yun & Meng, Wei, 2018. "Forecasting the output of shale gas in China using an unbiased grey model and weakening buffer operator," Energy, Elsevier, vol. 151(C), pages 238-249.
    12. Middleton, Richard S. & Carey, J. William & Currier, Robert P. & Hyman, Jeffrey D. & Kang, Qinjun & Karra, Satish & Jiménez-Martínez, Joaquín & Porter, Mark L. & Viswanathan, Hari S., 2015. "Shale gas and non-aqueous fracturing fluids: Opportunities and challenges for supercritical CO2," Applied Energy, Elsevier, vol. 147(C), pages 500-509.
    Full references (including those not matched with items on IDEAS)

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    7. Lu, Yanjun & Han, Jinxuan & Yang, Manping & Chen, Xingyu & Zhu, Hongjian & Yang, Zhaozhong, 2023. "Molecular simulation of supercritical CO2 extracting organic matter from coal based on the technology of CO2-ECBM," Energy, Elsevier, vol. 266(C).
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