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Experimental study of the effects of sub- and super-critical CO2 saturation on the mechanical characteristics of organic-rich shales

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  • Yin, Hong
  • Zhou, Junping
  • Xian, Xuefu
  • Jiang, Yongdong
  • Lu, Zhaohui
  • Tan, Jingqiang
  • Liu, Guojun

Abstract

The interaction between carbon dioxide (CO2) and shale during the process of CO2 sequestration and shale gas recovery could significantly affect mechanical properties of the shale. In the current study, we performed experiments at 38 °C on shale samples from the Sichuan Basin aiming at investigating the effects of sub-critical CO2 (SubCO2) and super-critical CO2 (ScCO2) saturation on shale mechanics. Uniaxial compressive strength (UCS) test, X-ray diffraction (XRD) analysis, energy dispersive X-ray spectroscopy (EDX) analysis and acoustic emission (AE) analysis were conducted on the raw and CO2-saturated (4, 6, 8, 12 and 16 MPa) shale samples. Results indicate that SubCO2 saturation (4 and 6 MPa) causes reduction in UCS and elastic modulus (E) of the shale up to 22.9% and 23.1%, respectively. More significantly, ScCO2 saturation (8, 12 and 16 MPa) causes up to 33.9% reductions of UCS and 34.0% reduction of E. This phenomenon can be attributed to a higher adsorptive potential and dissolution capacity of the ScCO2 fluid. In addition, these two parameters gradually vary with increasing saturation pressure: They slowly decrease and reach minimum values at 12 MPa, and then slightly increase as the saturation pressure increases from 12 to 16 MPa because of the compression effect resulted from higher fluid pressure. Results of AE analysis show that, compared with the raw shale samples, cracks of the CO2-saturated samples have a longer closure stage while a shorter stable and unstable crack propagation stage. It reveals that mechanical weakening of the shale is controlled by microscopic damages that resulted from CO2 saturation. Overall, our study confirms that the influence of CO2 saturation on the mechanical characteristics of organic-rich shale samples is closely related to gas pressure and phase state of CO2.

Suggested Citation

  • Yin, Hong & Zhou, Junping & Xian, Xuefu & Jiang, Yongdong & Lu, Zhaohui & Tan, Jingqiang & Liu, Guojun, 2017. "Experimental study of the effects of sub- and super-critical CO2 saturation on the mechanical characteristics of organic-rich shales," Energy, Elsevier, vol. 132(C), pages 84-95.
    • Handle: RePEc:eee:energy:v:132:y:2017:i:c:p:84-95
    DOI: 10.1016/j.energy.2017.05.064
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    1. Perera, M.S.A. & Ranjith, P.G. & Choi, S.K. & Airey, D., 2011. "The effects of sub-critical and super-critical carbon dioxide adsorption-induced coal matrix swelling on the permeability of naturally fractured black coal," Energy, Elsevier, vol. 36(11), pages 6442-6450.
    2. Wang, Qiang & Li, Rongrong, 2017. "Research status of shale gas: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 715-720.
    3. Zhong, Dong-Liang & Li, Zheng & Lu, Yi-Yu & Wang, Jia-Le & Yan, Jin, 2015. "Evaluation of CO2 removal from a CO2+CH4 gas mixture using gas hydrate formation in liquid water and THF solutions," Applied Energy, Elsevier, vol. 158(C), pages 133-141.
    4. Perera, M.S.A. & Ranjith, P.G. & Viete, D.R., 2013. "Effects of gaseous and super-critical carbon dioxide saturation on the mechanical properties of bituminous coal from the Southern Sydney Basin," Applied Energy, Elsevier, vol. 110(C), pages 73-81.
    5. McGlade, Christophe & Speirs, Jamie & Sorrell, Steve, 2013. "Unconventional gas – A review of regional and global resource estimates," Energy, Elsevier, vol. 55(C), pages 571-584.
    6. Jiang, Yongdong & Luo, Yahuang & Lu, Yiyu & Qin, Chao & Liu, Hui, 2016. "Effects of supercritical CO2 treatment time, pressure, and temperature on microstructure of shale," Energy, Elsevier, vol. 97(C), pages 173-181.
    7. Qiao Lyu & Xinping Long & Pathegama Gamage Ranjith & Yong Kang, 2016. "Unconventional Gas: Experimental Study of the Influence of Subcritical Carbon Dioxide on the Mechanical Properties of Black Shale," Energies, MDPI, vol. 9(7), pages 1-15, July.
    8. Chen, Shangbin & Zhu, Yanming & Wang, Hongyan & Liu, Honglin & Wei, Wei & Fang, Junhua, 2011. "Shale gas reservoir characterisation: A typical case in the southern Sichuan Basin of China," Energy, Elsevier, vol. 36(11), pages 6609-6616.
    9. Middleton, Richard S. & Carey, J. William & Currier, Robert P. & Hyman, Jeffrey D. & Kang, Qinjun & Karra, Satish & Jiménez-Martínez, Joaquín & Porter, Mark L. & Viswanathan, Hari S., 2015. "Shale gas and non-aqueous fracturing fluids: Opportunities and challenges for supercritical CO2," Applied Energy, Elsevier, vol. 147(C), pages 500-509.
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    13. Bai, Bing & Ni, Hong-jian & Shi, Xian & Guo, Xing & Ding, Lu, 2021. "The experimental investigation of effect of supercritical CO2 immersion on mechanical properties and pore structure of shale," Energy, Elsevier, vol. 228(C).
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    17. Qin, Chao & Jiang, Yongdong & Luo, Yahuang & Zhou, Junping & Liu, Hao & Song, Xiao & Li, Dong & Zhou, Feng & Xie, Yingliang, 2020. "Effect of supercritical CO2 saturation pressures and temperatures on the methane adsorption behaviours of Longmaxi shale," Energy, Elsevier, vol. 206(C).
    18. Mohammad H. Bhuiyan & Nicolaine Agofack & Kamila M. Gawel & Pierre R. Cerasi, 2020. "Micro- and Macroscale Consequences of Interactions between CO 2 and Shale Rocks," Energies, MDPI, vol. 13(5), pages 1-30, March.
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    21. Zhou, Junping & Tian, Shifeng & Zhou, Lei & Xian, Xuefu & Yang, Kang & Jiang, Yongdong & Zhang, Chengpeng & Guo, Yaowen, 2020. "Experimental investigation on the influence of sub- and super-critical CO2 saturation time on the permeability of fractured shale," Energy, Elsevier, vol. 191(C).

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