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Adsorption characteristics and thermodynamic analysis of shale in northern Guizhou, China: Measurement, modeling and prediction

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  • Gao, Zheng
  • Li, Bobo
  • Li, Jianhua
  • Jia, Lidan
  • Wang, Zhonghui

Abstract

The Lower Cambrian Niutitang Formation shale is the principal organic-rich shale formation in the northern Guizhou Province of China, which has great shale gas development prospects. In this study, the isothermal adsorption data from 26 shale samples from Niutitang Formation in northern Guizhou were obtained through the isothermal adsorption experiment of self-sampled specimens, along with published data. On this basis, we analyzed the control effects of temperature and physical parameters on adsorption capacity. An adsorption model with two new physical meaning parameters was constructed, and the accuracy of the model was validated. In addition, the isosteric enthalpy of adsorption in shale was further calculated, and the factors that affected the isosteric enthalpy were discussed. The results showed that the isosteric enthalpy decreased with an increase in temperature, and increased with an increase of TOC, but was controlled at a higher TOC. TOC-normalized heat revealed a more obvious segmental change rule for thermal maturity. Finally, we provided a new method to predict adsorption isotherms at other temperature conditions through the isosteric enthalpy of adsorption, and obtained better prediction results. This study provided a new insight for further understanding of shale adsorption characteristics from the perspective of thermodynamics.

Suggested Citation

  • Gao, Zheng & Li, Bobo & Li, Jianhua & Jia, Lidan & Wang, Zhonghui, 2023. "Adsorption characteristics and thermodynamic analysis of shale in northern Guizhou, China: Measurement, modeling and prediction," Energy, Elsevier, vol. 262(PA).
    • Handle: RePEc:eee:energy:v:262:y:2023:i:pa:s0360544222023155
    DOI: 10.1016/j.energy.2022.125433
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    References listed on IDEAS

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    1. Chen, Yuntian & Jiang, Su & Zhang, Dongxiao & Liu, Chaoyang, 2017. "An adsorbed gas estimation model for shale gas reservoirs via statistical learning," Applied Energy, Elsevier, vol. 197(C), pages 327-341.
    2. Xie, Weidong & Wang, Meng & Chen, Si & Vandeginste, Veerle & Yu, Zhenghong & Wang, Hua, 2022. "Effects of gas components, reservoir property and pore structure of shale gas reservoir on the competitive adsorption behavior of CO2 and CH4," Energy, Elsevier, vol. 254(PB).
    3. Jie Zou & Reza Rezaee, 2019. "A Prediction Model for Methane Adsorption Capacity in Shale Gas Reservoirs," Energies, MDPI, vol. 12(2), pages 1-13, January.
    4. Middleton, Richard S. & Gupta, Rajan & Hyman, Jeffrey D. & Viswanathan, Hari S., 2017. "The shale gas revolution: Barriers, sustainability, and emerging opportunities," Applied Energy, Elsevier, vol. 199(C), pages 88-95.
    5. Zhou, Junping & Tian, Shifeng & Zhou, Lei & Xian, Xuefu & Yang, Kang & Jiang, Yongdong & Zhang, Chengpeng & Guo, Yaowen, 2020. "Experimental investigation on the influence of sub- and super-critical CO2 saturation time on the permeability of fractured shale," Energy, Elsevier, vol. 191(C).
    6. Lin, Kui & Zhao, Ya-Pu, 2021. "Entropy and enthalpy changes during adsorption and displacement of shale gas," Energy, Elsevier, vol. 221(C).
    7. Yang, Xu & Zhou, Wenning & Liu, Xunliang & Yan, Yuying, 2020. "A multiscale approach for simulation of shale gas transport in organic nanopores," Energy, Elsevier, vol. 210(C).
    8. Qin, Chao & Jiang, Yongdong & Luo, Yahuang & Zhou, Junping & Liu, Hao & Song, Xiao & Li, Dong & Zhou, Feng & Xie, Yingliang, 2020. "Effect of supercritical CO2 saturation pressures and temperatures on the methane adsorption behaviours of Longmaxi shale," Energy, Elsevier, vol. 206(C).
    Full references (including those not matched with items on IDEAS)

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