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Preparation and thermal properties of sodium acetate trihydrate as a novel phase change material for energy storage

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  • Wang, Yan
  • Yu, Kaixiang
  • Peng, Hao
  • Ling, Xiang

Abstract

As phase change thermal storage material, sodium acetate trihydrate (CH3COONa·3H2O) exhibits large thermal capacity and holds tremendous promise. However, main problems of undercooling of solidification and phase stratification constrained its application in energy storage. Thus, present work prepared a new composite phase change thermal storage material of sodium acetate trihydrate mixed with nucleating agent and thickening agent. The initial research results showed that addition of an appropriate proportion of nucleating agent tetrasodium pyrophosphate decahydrate led to a good restrain to the undercooling of CH3COONa·3H2O. A certain amount of thickening agent polyacrylamide could also avoid the phenomenon of phase stratification and maintain the heat storage capacity of samples. Meanwhile, the additions little affected the melting point and would not decrease the enthalpy of fusion of sodium acetate trihydrate as established from Differential Scanning Calorimetry study, which indicated that this novel composite material possessed excellent and stable performance suitable for its application for thermal energy storage systems.

Suggested Citation

  • Wang, Yan & Yu, Kaixiang & Peng, Hao & Ling, Xiang, 2019. "Preparation and thermal properties of sodium acetate trihydrate as a novel phase change material for energy storage," Energy, Elsevier, vol. 167(C), pages 269-274.
    • Handle: RePEc:eee:energy:v:167:y:2019:i:c:p:269-274
    DOI: 10.1016/j.energy.2018.10.164
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    5. Zhao, B.C. & Li, T.X. & Gao, J.C. & Wang, R.Z., 2020. "Latent heat thermal storage using salt hydrates for distributed building heating: A multi-level scale-up research," Renewable and Sustainable Energy Reviews, Elsevier, vol. 121(C).
    6. Hu, Yige & Wang, Hang & Chen, Hu & Ding, Yang & Liu, Changtian & Jiang, Feng & Ling, Xiang, 2023. "A novel hydrated salt-based phase change material for medium- and low-thermal energy storage," Energy, Elsevier, vol. 274(C).
    7. Chao, Weixiang & Yang, Haiyue & Cao, Guoliang & Sun, Xiaohan & Wang, Xin & Wang, Chengyu, 2020. "Carbonized wood flour matrix with functional phase change material composite for magnetocaloric-assisted photothermal conversion and storage," Energy, Elsevier, vol. 202(C).
    8. Jin, Xin & Wu, Fengping & Xu, Tao & Huang, Gongsheng & Wu, Huijun & Zhou, Xiaoqing & Wang, Dengjia & Liu, Yanfeng & Lai, Alvin CK., 2021. "Experimental investigation of the novel melting point modified Phase–Change material for heat pump latent heat thermal energy storage application," Energy, Elsevier, vol. 216(C).
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    10. Rajendran Prabakaran & Palanisamy Dhamodharan & Anbalagan Sathishkumar & Paride Gullo & Muthuraman Ponrajan Vikram & Saravanan Pandiaraj & Abdullah Alodhayb & Ghada A. Khouqeer & Sung-Chul Kim, 2023. "An Overview of the State of the Art and Challenges in the Use of Gelling and Thickening Agents to Create Stable Thermal Energy Storage Materials," Energies, MDPI, vol. 16(8), pages 1-24, April.

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