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Porous Co3O4 nanoplates as the active material for rechargeable Zn-air batteries with high energy efficiency and cycling stability

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  • Tan, Peng
  • Chen, Bin
  • Xu, Haoran
  • Cai, Weizi
  • He, Wei
  • Ni, Meng

Abstract

Efficient electrocatalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are crucial for rechargeable Zn-air batteries. We report porous Co3O4 nanoplates with the average size and thickness of ∼100 and ∼20 nm, respectively, and a surface area of 98.65 m2 g−1. The mesoporous nanostructure shortens the lengths for ion/electron transport and provides abundant reaction sites. In the alkaline solution, the Co3O4 nanoplates exhibit a comparable limiting current density to that of Pt/C in the ORR and a superior activity in the OER. Redox reactions corresponding to the oxidation/reduction of cobalt species with a high pseudocapacitance and stability are observed, indicating the multifunctional properties. Using Co3O4 nanoplates in the air electrode, the Zn-air battery delivers a maximum power density of 59.7 mW cm−2. At a current density of 1 mA cm−2, a gravimetric energy density of 901.6 Wh kgZn−1 and an energy efficiency of 67.3% are achieved. Moreover, the voltage gaps between discharge and charge as well as the energy efficiency of 58% at 10 mA cm−2 are maintained for 100 cycles. The porous Co3O4 nanoplate is a promising active material for efficient Zn-air batteries with excellent cycling stability and high energy density.

Suggested Citation

  • Tan, Peng & Chen, Bin & Xu, Haoran & Cai, Weizi & He, Wei & Ni, Meng, 2019. "Porous Co3O4 nanoplates as the active material for rechargeable Zn-air batteries with high energy efficiency and cycling stability," Energy, Elsevier, vol. 166(C), pages 1241-1248.
    • Handle: RePEc:eee:energy:v:166:y:2019:i:c:p:1241-1248
    DOI: 10.1016/j.energy.2018.10.161
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    References listed on IDEAS

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    1. Chen, Dongfang & Pan, Lyuming & Pei, Pucheng & Huang, Shangwei & Ren, Peng & Song, Xin, 2021. "Carbon-coated oxygen vacancies-rich Co3O4 nanoarrays grow on nickel foam as efficient bifunctional electrocatalysts for rechargeable zinc-air batteries," Energy, Elsevier, vol. 224(C).
    2. Zhang, Yi-Jie & Gao, Yi-Jun & Wang, Xiaoge & Ye, Qin & Zhang, Ya & Wu, Yu & Chen, Shu-Han & Ruan, Bo & Shi, Dean & Jiang, Tao & Tsai, Fang-Chang & Ma, Ning, 2022. "MoTe2 on metal-organic framework derived MoO2/N-doped carbon rods for enhanced sodium-ion storage properties," Energy, Elsevier, vol. 243(C).

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