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Design and fabrication of reversible thermochromic microencapsulated phase change materials for thermal energy storage and its antibacterial activity

Author

Listed:
  • Geng, Xiaoye
  • Li, Wei
  • Yin, Qing
  • Wang, Yu
  • Han, Na
  • Wang, Ning
  • Bian, Junmin
  • Wang, Jianping
  • Zhang, Xingxiang

Abstract

In this study, a series of reversible thermochromic microencapsulated phase change materials (TC-MPCMs), exhibiting excellent thermal energy storage performance, were designed and fabricated successfully. The core of TC-MPCMs was comprised of crystal violet lactone employed as thermochromic colorant, bisphenol A as developer and 1-tetradecanol as co-solvent, respectively. The effects of shell materials on reversible thermochromic properties, thermal performance and thermal stability of TC-MPCMs were investigated systematically as well. These influencing factors of encapsulation process such as the dripping speeds, SMA emulsifier and pH were carried out to optimize the encapsulation parameters. Additionally, the TC-MPCMs modified with fabricated silver nano-particles displayed excellent thermal properties, heat transfer and antibacterial activity. Both the microscopic morphology and microstructure of TC-MPCMs were characterized and discussed systematically. The thermal distribution on the TC-MPCMs was exhibited via the infrared camera. The performance of fusion, crystallization, enthalpy and thermal stability of various capsules were measured and studied as well. In the end, ultraviolet–visible spectrophotometry was employed to investigate the antibacterial activity of Ag-TC-MPCMs(B). Furthermore, the TC-MPCMs(B) and Ag-TC-MPCMs(B) exhibited excellent thermal stability and the cyclic durability.

Suggested Citation

  • Geng, Xiaoye & Li, Wei & Yin, Qing & Wang, Yu & Han, Na & Wang, Ning & Bian, Junmin & Wang, Jianping & Zhang, Xingxiang, 2018. "Design and fabrication of reversible thermochromic microencapsulated phase change materials for thermal energy storage and its antibacterial activity," Energy, Elsevier, vol. 159(C), pages 857-869.
    • Handle: RePEc:eee:energy:v:159:y:2018:i:c:p:857-869
    DOI: 10.1016/j.energy.2018.06.218
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    1. Jiang, Fuyun & Wang, Xiaodong & Wu, Dezhen, 2014. "Design and synthesis of magnetic microcapsules based on n-eicosane core and Fe3O4/SiO2 hybrid shell for dual-functional phase change materials," Applied Energy, Elsevier, vol. 134(C), pages 456-468.
    2. Karthick, A. & Murugavel, K. Kalidasa & Ramanan, P., 2018. "Performance enhancement of a building-integrated photovoltaic module using phase change material," Energy, Elsevier, vol. 142(C), pages 803-812.
    3. Nomura, Takahiro & Sheng, Nan & Zhu, Chunyu & Saito, Genki & Hanzaki, Daiki & Hiraki, Takehito & Akiyama, Tomohiro, 2017. "Microencapsulated phase change materials with high heat capacity and high cyclic durability for high-temperature thermal energy storage and transportation," Applied Energy, Elsevier, vol. 188(C), pages 9-18.
    4. Zhang, Xiaoyu & Wang, Xiaodong & Wu, Dezhen, 2016. "Design and synthesis of multifunctional microencapsulated phase change materials with silver/silica double-layered shell for thermal energy storage, electrical conduction and antimicrobial effectivene," Energy, Elsevier, vol. 111(C), pages 498-512.
    5. Cheng Yang & Xiaoya Cui & Zhexu Zhang & Sum Wai Chiang & Wei Lin & Huan Duan & Jia Li & Feiyu Kang & Ching-Ping Wong, 2015. "Fractal dendrite-based electrically conductive composites for laser-scribed flexible circuits," Nature Communications, Nature, vol. 6(1), pages 1-10, November.
    6. Lashgari, Somayeh & Arabi, Hassan & Mahdavian, Ali Reza & Ambrogi, Veronica, 2017. "Thermal and morphological studies on novel PCM microcapsules containing n-hexadecane as the core in a flexible shell," Applied Energy, Elsevier, vol. 190(C), pages 612-622.
    7. Zhang, P. & Xiao, X. & Ma, Z.W., 2016. "A review of the composite phase change materials: Fabrication, characterization, mathematical modeling and application to performance enhancement," Applied Energy, Elsevier, vol. 165(C), pages 472-510.
    8. Geng, Xiaoye & Li, Wei & Wang, Yu & Lu, Jiangwei & Wang, Jianping & Wang, Ning & Li, Jianjie & Zhang, Xingxiang, 2018. "Reversible thermochromic microencapsulated phase change materials for thermal energy storage application in thermal protective clothing," Applied Energy, Elsevier, vol. 217(C), pages 281-294.
    9. Qian, Tingting & Li, Jinhong, 2018. "Octadecane/C-decorated diatomite composite phase change material with enhanced thermal conductivity as aggregate for developing structural–functional integrated cement for thermal energy storage," Energy, Elsevier, vol. 142(C), pages 234-249.
    10. Han, Pengju & Lu, Lixin & Qiu, Xiaolin & Tang, Yali & Wang, Jun, 2015. "Preparation and characterization of macrocapsules containing microencapsulated PCMs (phase change materials) for thermal energy storage," Energy, Elsevier, vol. 91(C), pages 531-539.
    11. Kumarasamy, Karthikeyan & An, Jinliang & Yang, Jinglei & Yang, En-Hua, 2017. "Novel CFD-based numerical schemes for conduction dominant encapsulated phase change materials (EPCM) with temperature hysteresis for thermal energy storage applications," Energy, Elsevier, vol. 132(C), pages 31-40.
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