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Development of reversible and durable thermochromic phase-change microcapsules for real-time indication of thermal energy storage and management

Author

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  • Zhang, Ya
  • Liu, Huan
  • Niu, Jinfei
  • Wang, Xiaodong
  • Wu, Dezhen

Abstract

We reported a design of novel thermochromic phase-change microcapsules (TCMs) with a sandwich-structured shell for reversible and durable indication of thermal energy storage and management in real-time. Two types of TCMs with red and blue color indicators were successfully constructed by fabricating a silica base shell onto the n-docosane core, followed by formation of a thermochromic indication layer and a polymeric protective layer, and their multilayered configuration and well-defined core-shell structure were confirmed by microstructural investigation and chemical composition analysis. These two types of TCMs not only showed an outstanding latent heat-storage/release capability with a high capacity over 150 J/g, but also exhibited a good shape stability, high thermal stability and excellent phase-change reversibility and durability. The optimum operation conditions for thermal energy charge/discharge were also determined by nonisothermal and isothermal differential scanning calorimetric analyses. Most of all, the two types of TCMs presented an entirely reversible thermochromic behavior individually with high-contrast red and blue color indications for the phase-change state of n-docosane core. Both of them exhibited high reversibility and long cycle life in thermochromic indication, which meets the design requirements for durable indication of latent heat storage and thermal management in real-time. In the light of an innovative configuration of sandwich-structured shell and a smart combination of latent heat-storage and thermochromic functions, the TCMs designed by this study has a great potential for applications in smart fibers and textiles, wearable electric devices, energy-saving buildings, temperature-sensitive medical system, safety clothing, smart windows, aerospace engineering and many more.

Suggested Citation

  • Zhang, Ya & Liu, Huan & Niu, Jinfei & Wang, Xiaodong & Wu, Dezhen, 2020. "Development of reversible and durable thermochromic phase-change microcapsules for real-time indication of thermal energy storage and management," Applied Energy, Elsevier, vol. 264(C).
    • Handle: RePEc:eee:appene:v:264:y:2020:i:c:s0306261920302415
    DOI: 10.1016/j.apenergy.2020.114729
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    1. Jiang, Fuyun & Wang, Xiaodong & Wu, Dezhen, 2014. "Design and synthesis of magnetic microcapsules based on n-eicosane core and Fe3O4/SiO2 hybrid shell for dual-functional phase change materials," Applied Energy, Elsevier, vol. 134(C), pages 456-468.
    2. Zhao, C.Y. & Zhang, G.H., 2011. "Review on microencapsulated phase change materials (MEPCMs): Fabrication, characterization and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3813-3832.
    3. Zhou, D. & Zhao, C.Y. & Tian, Y., 2012. "Review on thermal energy storage with phase change materials (PCMs) in building applications," Applied Energy, Elsevier, vol. 92(C), pages 593-605.
    4. Aburas, Marina & Soebarto, Veronica & Williamson, Terence & Liang, Runqi & Ebendorff-Heidepriem, Heike & Wu, Yupeng, 2019. "Thermochromic smart window technologies for building application: A review," Applied Energy, Elsevier, vol. 255(C).
    5. Geng, Xiaoye & Li, Wei & Yin, Qing & Wang, Yu & Han, Na & Wang, Ning & Bian, Junmin & Wang, Jianping & Zhang, Xingxiang, 2018. "Design and fabrication of reversible thermochromic microencapsulated phase change materials for thermal energy storage and its antibacterial activity," Energy, Elsevier, vol. 159(C), pages 857-869.
    6. Yataganbaba, Alptug & Ozkahraman, Bengi & Kurtbas, Irfan, 2017. "Worldwide trends on encapsulation of phase change materials: A bibliometric analysis (1990–2015)," Applied Energy, Elsevier, vol. 185(P1), pages 720-731.
    7. Liu, Huan & Wang, Xiaodong & Wu, Dezhen & Ji, Shengfu, 2019. "Morphology-controlled synthesis of microencapsulated phase change materials with TiO2 shell for thermal energy harvesting and temperature regulation," Energy, Elsevier, vol. 172(C), pages 599-617.
    8. Geng, Xiaoye & Li, Wei & Wang, Yu & Lu, Jiangwei & Wang, Jianping & Wang, Ning & Li, Jianjie & Zhang, Xingxiang, 2018. "Reversible thermochromic microencapsulated phase change materials for thermal energy storage application in thermal protective clothing," Applied Energy, Elsevier, vol. 217(C), pages 281-294.
    9. Yang, Haiyue & Wang, Yazhou & Yu, Qianqian & Cao, Guoliang & Yang, Rue & Ke, Jiaona & Di, Xin & Liu, Feng & Zhang, Wenbo & Wang, Chengyu, 2018. "Composite phase change materials with good reversible thermochromic ability in delignified wood substrate for thermal energy storage," Applied Energy, Elsevier, vol. 212(C), pages 455-464.
    10. Castell, A. & Solé, C., 2015. "An overview on design methodologies for liquid–solid PCM storage systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 289-307.
    11. Sun, Kun & Liu, Huan & Wang, Xiaodong & Wu, Dezhen, 2019. "Innovative design of superhydrophobic thermal energy-storage materials by microencapsulation of n-docosane with nanostructured ZnO/SiO2 shell," Applied Energy, Elsevier, vol. 237(C), pages 549-565.
    12. Fabiani, C. & Pisello, A.L. & Bou-Zeid, E. & Yang, J. & Cotana, F., 2019. "Adaptive measures for mitigating urban heat islands: The potential of thermochromic materials to control roofing energy balance," Applied Energy, Elsevier, vol. 247(C), pages 155-170.
    13. Chandel, S.S. & Agarwal, Tanya, 2017. "Review of current state of research on energy storage, toxicity, health hazards and commercialization of phase changing materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 581-596.
    14. He, Yayue & Li, Wei & Han, Na & Wang, Jianping & Zhang, Xingxiang, 2019. "Facile flexible reversible thermochromic membranes based on micro/nanoencapsulated phase change materials for wearable temperature sensor," Applied Energy, Elsevier, vol. 247(C), pages 615-629.
    15. Jiang, Binbin & Wang, Xiaodong & Wu, Dezhen, 2017. "Fabrication of microencapsulated phase change materials with TiO2/Fe3O4 hybrid shell as thermoregulatory enzyme carriers: A novel design of applied energy microsystem for bioapplications," Applied Energy, Elsevier, vol. 201(C), pages 20-33.
    16. Umair, Malik Muhammad & Zhang, Yuang & Iqbal, Kashif & Zhang, Shufen & Tang, Bingtao, 2019. "Novel strategies and supporting materials applied to shape-stabilize organic phase change materials for thermal energy storage–A review," Applied Energy, Elsevier, vol. 235(C), pages 846-873.
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    1. Sun, Zhao & Han, Zhaoteng & Liu, Huan & Wu, Dezhen & Wang, Xiaodong, 2021. "Nanoflaky nickel-hydroxide-decorated phase-change microcapsules as smart electrode materials with thermal self-regulation function for supercapacitor application," Renewable Energy, Elsevier, vol. 174(C), pages 557-572.
    2. Kočí, J. & Fořt, J. & Černý, R., 2020. "Energy efficiency of latent heat storage systems in residential buildings: Coupled effects of wall assembly and climatic conditions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 132(C).

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