IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v128y2017icp701-712.html
   My bibliography  Save this article

In situ catalytic fast pyrolysis of crude and torrefied Eucalyptus globulus using carbon aerogel-supported catalysts

Author

Listed:
  • Arteaga-Pérez, Luis E.
  • Gómez Cápiro, Oscar
  • Romero, Romina
  • Delgado, Aaron
  • Olivera, Patricia
  • Ronsse, Frederik
  • Jiménez, Romel

Abstract

Nickel and iron supported on thermostable cellulose-derived carbon aerogels (CAG), were used for the catalytic fast pyrolysis (CFP) of crude and torrefied Eucalyptus globulus. Pyrolysis vapors produced from torrefied biomass under non-catalytic conditions were reduced by 70% in carboxylic acids with respect to vapors originating from crude biomass, but also were richer in ketones and aromatics. In the case of CFP of both crude and torrefied E.globulus on CAG-supported iron and nickel (Fe/CAG and Ni/CAG), the metallic clusters were activated for ketonization, while Ni0 provided additional hydrogenation sites, increasing the production of monoaromatics (c.a.18% selectivity), leading to a high acids-to-ketone (ξA-K = 1.3) and heavy-to-light (ξH-L = 1.0) ratios. Accordingly, Ni/CAG and Fe/CAG were more effective than HZSM-5 –a traditional cracking catalysts– for upgrading CFP vapors to light compounds. The combination of zeolite acid sites with the oxophilic Ni0 and Fe0 allows the deoxygenation of vapors while the ratio of polyaromatics to light aromatics (ξPAHs) was reduced by nearly 50%.

Suggested Citation

  • Arteaga-Pérez, Luis E. & Gómez Cápiro, Oscar & Romero, Romina & Delgado, Aaron & Olivera, Patricia & Ronsse, Frederik & Jiménez, Romel, 2017. "In situ catalytic fast pyrolysis of crude and torrefied Eucalyptus globulus using carbon aerogel-supported catalysts," Energy, Elsevier, vol. 128(C), pages 701-712.
    • Handle: RePEc:eee:energy:v:128:y:2017:i:c:p:701-712
    DOI: 10.1016/j.energy.2017.04.024
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544217305893
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2017.04.024?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Chen, Wei-Hsin & Peng, Jianghong & Bi, Xiaotao T., 2015. "A state-of-the-art review of biomass torrefaction, densification and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 847-866.
    2. Arteaga-Pérez, Luis E. & Segura, Cristina & Bustamante-García, Verónica & Gómez Cápiro, Oscar & Jiménez, Romel, 2015. "Torrefaction of wood and bark from Eucalyptus globulus and Eucalyptus nitens: Focus on volatile evolution vs feasible temperatures," Energy, Elsevier, vol. 93(P2), pages 1731-1741.
    3. Wigley, Tansy & Yip, Alex C.K. & Pang, Shusheng, 2016. "Pretreating biomass via demineralisation and torrefaction to improve the quality of crude pyrolysis oil," Energy, Elsevier, vol. 109(C), pages 481-494.
    4. Yildiz, Güray & Ronsse, Frederik & Duren, Ruben van & Prins, Wolter, 2016. "Challenges in the design and operation of processes for catalytic fast pyrolysis of woody biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1596-1610.
    5. Qiang Lu & Zhi-Fei Zhang & Chang-Qing Dong & Xi-Feng Zhu, 2010. "Catalytic Upgrading of Biomass Fast Pyrolysis Vapors with Nano Metal Oxides: An Analytical Py-GC/MS Study," Energies, MDPI, vol. 3(11), pages 1-16, November.
    6. Wang, Duo & Yuan, Wenqiao & Ji, Wei, 2011. "Char and char-supported nickel catalysts for secondary syngas cleanup and conditioning," Applied Energy, Elsevier, vol. 88(5), pages 1656-1663, May.
    7. Theodore Dickerson & Juan Soria, 2013. "Catalytic Fast Pyrolysis: A Review," Energies, MDPI, vol. 6(1), pages 1-25, January.
    8. Shen, Yafei & Zhao, Peitao & Shao, Qinfu & Takahashi, Fumitake & Yoshikawa, Kunio, 2015. "In situ catalytic conversion of tar using rice husk char/ash supported nickel–iron catalysts for biomass pyrolytic gasification combined with the mixing-simulation in fluidized-bed gasifier," Applied Energy, Elsevier, vol. 160(C), pages 808-819.
    9. Asadullah, Mohammad, 2014. "Biomass gasification gas cleaning for downstream applications: A comparative critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 118-132.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Kumar, R. & Strezov, V. & Weldekidan, H. & He, J. & Singh, S. & Kan, T. & Dastjerdi, B., 2020. "Lignocellulose biomass pyrolysis for bio-oil production: A review of biomass pre-treatment methods for production of drop-in fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 123(C).
    2. Tang, Shouhang & Zhou, Sicheng & Li, Ge & Xin, Shanzhi & Huang, Fang & Liu, Xiaoye & Huang, Kai & Zeng, Lixi & Mi, Tie, 2023. "Combination of torrefaction and catalytic fast pyrolysis for aromatic hydrocarbon production from herbaceous medicine waste," Energy, Elsevier, vol. 270(C).
    3. Eleni F. Iliopoulou & Kostas S. Triantafyllidis & Angelos A. Lappas, 2019. "Overview of catalytic upgrading of biomass pyrolysis vapors toward the production of fuels and high‐value chemicals," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 8(1), January.
    4. Dai, Leilei & Wang, Yunpu & Liu, Yuhuan & Ruan, Roger & He, Chao & Yu, Zhenting & Jiang, Lin & Zeng, Zihong & Tian, Xiaojie, 2019. "Integrated process of lignocellulosic biomass torrefaction and pyrolysis for upgrading bio-oil production: A state-of-the-art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 20-36.
    5. Douvartzides, Savvas & Charisiou, Nikolaos D. & Wang, Wen & Papadakis, Vagelis G. & Polychronopoulou, Kyriaki & Goula, Maria A., 2022. "Catalytic fast pyrolysis of agricultural residues and dedicated energy crops for the production of high energy density transportation biofuels. Part II: Catalytic research," Renewable Energy, Elsevier, vol. 189(C), pages 315-338.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Merckel, Ryan D. & Heydenrych, Mike D. & Sithole, Bruce B., 2021. "Pyrolysis oil composition and catalytic activity estimated by cumulative mass analysis using Py-GC/MS EGA-MS," Energy, Elsevier, vol. 219(C).
    2. Moya, Roger & Rodríguez-Zúñiga, Ana & Puente-Urbina, Allen & Gaitán-Álvarez, Johanna, 2018. "Study of light, middle and severe torrefaction and effects of extractives and chemical compositions on torrefaction process by thermogravimetric analysis in five fast-growing plantations of Costa Rica," Energy, Elsevier, vol. 149(C), pages 1-10.
    3. Buentello-Montoya, D.A. & Zhang, X. & Li, J., 2019. "The use of gasification solid products as catalysts for tar reforming," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 399-412.
    4. Zhijun Zhang & Shujuan Sui & Fengqiang Wang & Qingwen Wang & Charles U. Pittman, 2013. "Catalytic Conversion of Bio-Oil to Oxygen-Containing Fuels by Acid-Catalyzed Reaction with Olefins and Alcohols over Silica Sulfuric Acid," Energies, MDPI, vol. 6(9), pages 1-20, September.
    5. Gao, Ningbo & Salisu, Jamilu & Quan, Cui & Williams, Paul, 2021. "Modified nickel-based catalysts for improved steam reforming of biomass tar: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    6. Bonassa, Gabriela & Schneider, Lara Talita & Canever, Victor Bruno & Cremonez, Paulo André & Frigo, Elisandro Pires & Dieter, Jonathan & Teleken, Joel Gustavo, 2018. "Scenarios and prospects of solid biofuel use in Brazil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2365-2378.
    7. Javier Fermoso & Patricia Pizarro & Juan M. Coronado & David P. Serrano, 2017. "Advanced biofuels production by upgrading of pyrolysis bio‐oil," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 6(4), July.
    8. Wang, Na & Chen, Dezhen & Arena, Umberto & He, Pinjing, 2017. "Hot char-catalytic reforming of volatiles from MSW pyrolysis," Applied Energy, Elsevier, vol. 191(C), pages 111-124.
    9. Hervy, Maxime & Weiss-Hortala, Elsa & Pham Minh, Doan & Dib, Hadi & Villot, Audrey & Gérente, Claire & Berhanu, Sarah & Chesnaud, Anthony & Thorel, Alain & Le Coq, Laurence & Nzihou, Ange, 2019. "Reactivity and deactivation mechanisms of pyrolysis chars from bio-waste during catalytic cracking of tar," Applied Energy, Elsevier, vol. 237(C), pages 487-499.
    10. Hanoğlu, Alper & Çay, Ahmet & Yanık, Jale, 2019. "Production of biochars from textile fibres through torrefaction and their characterisation," Energy, Elsevier, vol. 166(C), pages 664-673.
    11. José Airton de Mattos Carneiro-Junior & Giulyane Felix de Oliveira & Carine Tondo Alves & Heloysa Martins Carvalho Andrade & Silvio Alexandre Beisl Vieira de Melo & Ednildo Andrade Torres, 2021. "Valorization of Prosopis juliflora Woody Biomass in Northeast Brazilian through Dry Torrefaction," Energies, MDPI, vol. 14(12), pages 1-17, June.
    12. Zou, Xuehua & Chen, Tianhu & Zhang, Ping & Chen, Dong & He, Junkai & Dang, Yanliu & Ma, Zhiyuan & Chen, Ye & Toloueinia, Panteha & Zhu, Chengzhu & Xie, Jingjing & Liu, Haibo & Suib, Steven L., 2018. "High catalytic performance of Fe-Ni/Palygorskite in the steam reforming of toluene for hydrogen production," Applied Energy, Elsevier, vol. 226(C), pages 827-837.
    13. Wang, L. & Barta-Rajnai, E. & Skreiberg, Ø. & Khalil, R. & Czégény, Z. & Jakab, E. & Barta, Z. & Grønli, M., 2018. "Effect of torrefaction on physiochemical characteristics and grindability of stem wood, stump and bark," Applied Energy, Elsevier, vol. 227(C), pages 137-148.
    14. Wang, Ziliang & Lim, C. Jim & Grace, John R., 2019. "A comprehensive study of sawdust torrefaction in a dual-compartment slot-rectangular spouted bed reactor," Energy, Elsevier, vol. 189(C).
    15. Shahbaz, Muhammad & Al-Ansari, Tareq & Inayat, Muddasser & Sulaiman, Shaharin A. & Parthasarathy, Prakash & McKay, Gordon, 2020. "A critical review on the influence of process parameters in catalytic co-gasification: Current performance and challenges for a future prospectus," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    16. Álvarez, Ana & Nogueiro, Dositeo & Pizarro, Consuelo & Matos, María & Bueno, Julio L., 2018. "Non-oxidative torrefaction of biomass to enhance its fuel properties," Energy, Elsevier, vol. 158(C), pages 1-8.
    17. ABM Abdul Malek & M Hasanuzzaman & Nasrudin A Rahim & Yusuf A Al–Turki, 2021. "Energy, economic, and environmental analysis of 10-MW biomass gasification based power generation in Malaysia," Energy & Environment, , vol. 32(2), pages 295-337, March.
    18. Saraeian, Alireza & Nolte, Michael W. & Shanks, Brent H., 2019. "Deoxygenation of biomass pyrolysis vapors: Improving clarity on the fate of carbon," Renewable and Sustainable Energy Reviews, Elsevier, vol. 104(C), pages 262-280.
    19. Kabir, G. & Hameed, B.H., 2017. "Recent progress on catalytic pyrolysis of lignocellulosic biomass to high-grade bio-oil and bio-chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 945-967.
    20. Ong, Hwai Chyuan & Chen, Wei-Hsin & Farooq, Abid & Gan, Yong Yang & Lee, Keat Teong & Ashokkumar, Veeramuthu, 2019. "Catalytic thermochemical conversion of biomass for biofuel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:128:y:2017:i:c:p:701-712. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.