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Preparation of refined bio-oil by catalytic transformation of vapors derived from vacuum pyrolysis of rape straw over modified HZSM-5

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  • Cai, Yixi
  • Fan, Yongsheng
  • Li, Xiaohua
  • Chen, Lei
  • Wang, Jiajun

Abstract

This work aimed to develop an in-situ upgrading process for production of refined bio-oil from primary biomass pyrolysis vapors. The phosphorus, zinc and titanium modified HZSM-5 were developed and first employed in the process. The yield of refined bio-oil was in the range of 17.85–19.97% along with low oxygen content (18.06–20.04%), high pH value (4.96–5.02), low dynamic viscosity (5.85–6.02 mm2/s), high HHV (higher heating value) (32.70–33.98 MJ/kg) and high hydrocarbon content. However, the composition of hydrocarbon varied with modified elements, so the catalytic mechanism of modified HZSM-5 was discussed. Simultaneously, anti-coking performance of modified catalyst was investigated to evaluate sustainability of the process. This work demonstrated that the refined bio-oil produced in this study basically met the technical requirements of combustion in power machinery, which provided a useful way to utilize renewable lignocellulose biomass. Though anti-coking capability of modified HZSM-5 was enhanced, coke deposition still hindered the continuous production of refined bio-oil to a certain extent.

Suggested Citation

  • Cai, Yixi & Fan, Yongsheng & Li, Xiaohua & Chen, Lei & Wang, Jiajun, 2016. "Preparation of refined bio-oil by catalytic transformation of vapors derived from vacuum pyrolysis of rape straw over modified HZSM-5," Energy, Elsevier, vol. 102(C), pages 95-105.
    • Handle: RePEc:eee:energy:v:102:y:2016:i:c:p:95-105
    DOI: 10.1016/j.energy.2016.02.051
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    References listed on IDEAS

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    1. Su Shiung Lam & Howard A. Chase, 2012. "A Review on Waste to Energy Processes Using Microwave Pyrolysis," Energies, MDPI, vol. 5(10), pages 1-24, October.
    2. Qiang Lu & Zhi-Fei Zhang & Chang-Qing Dong & Xi-Feng Zhu, 2010. "Catalytic Upgrading of Biomass Fast Pyrolysis Vapors with Nano Metal Oxides: An Analytical Py-GC/MS Study," Energies, MDPI, vol. 3(11), pages 1-16, November.
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    Cited by:

    1. Caio Campos Ferreira & Lucas Pinto Bernar & Augusto Fernando de Freitas Costa & Haroldo Jorge da Silva Ribeiro & Marcelo Costa Santos & Nathalia Lobato Moraes & Yasmin Santos Costa & Ana Cláudia Fonse, 2022. "Improving Fuel Properties and Hydrocarbon Content from Residual Fat Pyrolysis Vapors over Activated Red Mud Pellets in Two-Stage Reactor: Optimization of Reaction Time and Catalyst Content," Energies, MDPI, vol. 15(15), pages 1-33, August.
    2. Long, Lin & Zhou, Weixing & Qiu, Yunfeng & Lan, Zhenzhong, 2020. "Coking and gas products behavior of supercritical n-decane over NiO nanoparticle/nanosheets modified HZSM-5," Energy, Elsevier, vol. 192(C).
    3. Li, Bingshuo & Yang, Tianhua & Li, Rundong & Kai, Xingping, 2020. "Co-generation of liquid biofuels from lignocellulose by integrated biochemical and hydrothermal liquefaction process," Energy, Elsevier, vol. 200(C).
    4. Fan, Yongsheng & Zhao, Weidong & Shao, Shanshan & Cai, Yixi & Chen, Yuwei & Jin, Lizhu, 2018. "Promotion of the vapors from biomass vacuum pyrolysis for biofuels under Non-thermal Plasma Synergistic Catalysis (NPSC) system," Energy, Elsevier, vol. 142(C), pages 462-472.
    5. Fan, Yongsheng & Lu, Dongsheng & Han, Yue & Yang, Jiaheng & Qian, Cheng & Li, Binyu, 2023. "Production of light aromatics from biomass components co-pyrolyzed with polyethylene via non-thermal plasma synergistic upgrading," Energy, Elsevier, vol. 265(C).
    6. Fan, Yongsheng & Zhu, Mengfeng & Jin, Lizhu & Cui, Entian & Zhu, Lei & Cai, Yixi & Zhao, Weidong, 2020. "Catalytic upgrading of biomass-derived vapors to bio-fuels via modified HZSM-5 coupled with DBD: Effects of different titanium sources," Renewable Energy, Elsevier, vol. 157(C), pages 100-115.
    7. Fan, Yongsheng & Zhu, Lei & Fan, Lele & Zhao, Weidong & Cai, Yixi & Chen, Yuwei & Jin, Lizhu & Xiong, Yonglian, 2018. "Catalytic upgrading of biomass pyrolysis volatiles to bio-fuel under pre-plasma enhanced catalysis (PPEC) system," Energy, Elsevier, vol. 162(C), pages 224-236.
    8. Zhang, Yuchun & Fu, Peng & Yi, Weiming & Li, Zhihe & Li, Zhiyu & Wang, Shaoqing & Li, Yongjun, 2021. "Species transport and reaction characteristics between gas and solid phases for ex-situ catalytic pyrolysis of biomass," Energy, Elsevier, vol. 225(C).

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