IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v225y2021ics0360544221004618.html

Species transport and reaction characteristics between gas and solid phases for ex-situ catalytic pyrolysis of biomass

Author

Listed:
  • Zhang, Yuchun
  • Fu, Peng
  • Yi, Weiming
  • Li, Zhihe
  • Li, Zhiyu
  • Wang, Shaoqing
  • Li, Yongjun

Abstract

Simultaneous reaction and separation in ex-situ catalytic pyrolysis of biomass was proposed to increase product yield and reduce carbon residue in short residence time. A novel cyclone reactor was designed to implement this process. The low cyclonic flow in the upper part of the reactor can efficiently increase gas (biomass pyrolysis vapors)-solid (catalysts) two-phase contact efficiency, and further enhance the catalytic effect. The strong cyclonic flow generated under the action of guide vanes in the lower part can ensure good separation effect between catalysts and gaseous products. The results indicate that the mean residence time of catalysts is 1.2–1.5 s. The effects on backflow and reaction characteristics were investigated for various operating conditions. The yield ratio of the desired product bio-oil is 54.2% under the optimal parameters obtained in this article. This work provides theoretical basis for improvement of biomass high-value utilization technology.

Suggested Citation

  • Zhang, Yuchun & Fu, Peng & Yi, Weiming & Li, Zhihe & Li, Zhiyu & Wang, Shaoqing & Li, Yongjun, 2021. "Species transport and reaction characteristics between gas and solid phases for ex-situ catalytic pyrolysis of biomass," Energy, Elsevier, vol. 225(C).
    • Handle: RePEc:eee:energy:v:225:y:2021:i:c:s0360544221004618
    DOI: 10.1016/j.energy.2021.120212
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544221004618
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2021.120212?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to

    for a different version of it.

    References listed on IDEAS

    as
    1. Ren, Xiajin & Cai, Hongzhen & Zhang, Qingfa & Zhang, Donghong & Lin, Xiaona, 2021. "Evaluation of zeolite catalysts on product distribution during sweet sorghum bagasse catalytic pyrolysis," Energy, Elsevier, vol. 214(C).
    2. Cai, Yixi & Fan, Yongsheng & Li, Xiaohua & Chen, Lei & Wang, Jiajun, 2016. "Preparation of refined bio-oil by catalytic transformation of vapors derived from vacuum pyrolysis of rape straw over modified HZSM-5," Energy, Elsevier, vol. 102(C), pages 95-105.
    3. Sorrentino, Giancarlo & Sabia, Pino & Bozza, Pio & Ragucci, Raffaele & de Joannon, Mara, 2017. "Impact of external operating parameters on the performance of a cyclonic burner with high level of internal recirculation under MILD combustion conditions," Energy, Elsevier, vol. 137(C), pages 1167-1174.
    4. Zhang, Donghong & Lin, Xiaona & Zhang, Qingfa & Ren, Xiajin & Yu, Wenfan & Cai, Hongzhen, 2020. "Catalytic pyrolysis of wood-plastic composite waste over activated carbon catalyst for aromatics production: Effect of preparation process of activated carbon," Energy, Elsevier, vol. 212(C).
    5. Bhoi, P.R. & Ouedraogo, A.S. & Soloiu, V. & Quirino, R., 2020. "Recent advances on catalysts for improving hydrocarbon compounds in bio-oil of biomass catalytic pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 121(C).
    6. Khodaei, Hassan & Gonzalez, Luis & Chapela, Sergio & Porteiro, Jacobo & Nikrityuk, Petr & Olson, Chris, 2021. "CFD-based coupled multiphase modeling of biochar production using a large-scale pyrolysis plant," Energy, Elsevier, vol. 217(C).
    7. Zhang, Yuchun & Yi, Weiming & Fu, Peng & Li, Zhihe & Bai, Xueyuan & Tian, Chunyan & Wang, Nana & Li, Yongjun, 2019. "Flow and reaction characteristics on catalytic upgrading of biomass pyrolysis vapors in novel cyclone reactors," Energy, Elsevier, vol. 189(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Pan, Ruming & Martins, Marcio Ferreira & Debenest, Gérald, 2022. "Optimization of oil production through ex-situ catalytic pyrolysis of waste polyethylene with activated carbon," Energy, Elsevier, vol. 248(C).
    2. Zhang, Nan & Pan, Xueer & Yang, Jingxuan & Lian, Wenhao & Fang, Tiancheng & Zhang, Zhonglin & Hao, Xiaogang & Abudula, Abuliti & Guan, Guoqing & Fan, Huiling, 2025. "A compensation strategy to improve gas-solid heat transfer without sacrificing kinetic energy in a cyclone pyrolyzer," Energy, Elsevier, vol. 324(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Tian, Ye & Zhou, Xiong & Ji, Xuanyu & Bai, Jisong & Yuan, Liang, 2019. "Applying moderate or intense low-oxygen dilution combustion to a co-axial-jet I-shaped recuperative radiant tube for further performance enhancement," Energy, Elsevier, vol. 171(C), pages 149-160.
    2. Chen, Xiangmeng & Shafizadeh, Alireza & Shahbeik, Hossein & Nadian, Mohammad Hossein & Golvirdizadeh, Milad & Peng, Wanxi & Lam, Su Shiung & Tabatabaei, Meisam & Aghbashlo, Mortaza, 2025. "Enhanced bio-oil production from biomass catalytic pyrolysis using machine learning," Renewable and Sustainable Energy Reviews, Elsevier, vol. 209(C).
    3. Yang, Youwei & Pan, Ruming & Wu, Yibo & Pan, Qinghui & Shuai, Yong, 2024. "A porous media catalyst for waste polyethylene pyrolysis in a continuous feeding reactor," Energy, Elsevier, vol. 302(C).
    4. Wang, Wei & Zhong, Zhaoping & Zheng, Xiang & Ye, Qihang & Li, Yihui & Yang, Yuxuan & Qi, Renzhi, 2025. "Catalytic co-pyrolysis of hydrolyzed lignin and waste tires over NiMo modified HZSM-5/MCM-41 composite molecular sieve in microwave fluidized bed for monocyclic aromatic hydrocarbons," Energy, Elsevier, vol. 329(C).
    5. Fan, Xudong & Wu, Yujian & Sun, Yan & Tu, Ren & Ren, Zhipeng & Liang, Kaili & Jiang, Enchen & Ren, Yongzhi & Xu, Xiwei, 2022. "Functional groups anchoring-induced Ni/MoOx-Ov interface on rice husk char for hydrodeoxygenation of bio-guaiacol to BTX at ambient-pressure," Renewable Energy, Elsevier, vol. 200(C), pages 579-591.
    6. Fan, Yongsheng & Zhao, Weidong & Shao, Shanshan & Cai, Yixi & Chen, Yuwei & Jin, Lizhu, 2018. "Promotion of the vapors from biomass vacuum pyrolysis for biofuels under Non-thermal Plasma Synergistic Catalysis (NPSC) system," Energy, Elsevier, vol. 142(C), pages 462-472.
    7. Sahar Safarian & Magnus Rydén & Matty Janssen, 2022. "Development and Comparison of Thermodynamic Equilibrium and Kinetic Approaches for Biomass Pyrolysis Modeling," Energies, MDPI, vol. 15(11), pages 1-18, May.
    8. Sorrentino, Giancarlo & Sabia, Pino & Bozza, Pio & Ragucci, Raffaele & de Joannon, Mara, 2019. "Low-NOx conversion of pure ammonia in a cyclonic burner under locally diluted and preheated conditions," Applied Energy, Elsevier, vol. 254(C).
    9. Arnob Das & Susmita Datta Peu, 2022. "A Comprehensive Review on Recent Advancements in Thermochemical Processes for Clean Hydrogen Production to Decarbonize the Energy Sector," Sustainability, MDPI, vol. 14(18), pages 1-42, September.
    10. Jin, Yanghao & Liu, Sirui & Shi, Ziyi & Wang, Shule & Wen, Yuming & Zaini, Ilman Nuran & Tang, Chuchu & Hedenqvist, Mikael S. & Lu, Xincheng & Kawi, Sibudjing & Wang, Chi-Hwa & Jiang, Jianchun & Jönss, 2024. "A novel three-stage ex-situ catalytic pyrolysis process for improved bio-oil yield and quality from lignocellulosic biomass," Energy, Elsevier, vol. 295(C).
    11. Enagi, Ibrahim I. & Al-attab, K.A. & Zainal, Z.A., 2018. "Liquid biofuels utilization for gas turbines: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 43-55.
    12. Che, Yuanjun & Shi, Kunmou & Cui, Zihang & Liu, Hongchen & Wang, Qian & Zhu, Wei & Tian, Yuanyu, 2023. "Conversion of low temperature coal tar into high value-added chemicals based on the coupling process of fast pyrolysis and catalytic cracking," Energy, Elsevier, vol. 264(C).
    13. Pan, Ruming & Martins, Marcio Ferreira & Debenest, Gérald, 2022. "Optimization of oil production through ex-situ catalytic pyrolysis of waste polyethylene with activated carbon," Energy, Elsevier, vol. 248(C).
    14. Gómez, M.A. & Álvarez-Bermúdez, C. & Chapela, S. & Anca-Couce, A. & Porteiro, J., 2023. "Study of the effects of thermally thin and thermally thick particle approaches on the Eulerian modeling of a biomass combustor operating with wood chips," Energy, Elsevier, vol. 281(C).
    15. Caio Campos Ferreira & Lucas Pinto Bernar & Augusto Fernando de Freitas Costa & Haroldo Jorge da Silva Ribeiro & Marcelo Costa Santos & Nathalia Lobato Moraes & Yasmin Santos Costa & Ana Cláudia Fonse, 2022. "Improving Fuel Properties and Hydrocarbon Content from Residual Fat Pyrolysis Vapors over Activated Red Mud Pellets in Two-Stage Reactor: Optimization of Reaction Time and Catalyst Content," Energies, MDPI, vol. 15(15), pages 1-33, August.
    16. Bisen, Divya & Chouhan, Ashish Pratap Singh & Pant, Manish & Chakma, Sankar, 2025. "Advancement of thermochemical conversion and the potential of biomasses for production of clean energy: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 208(C).
    17. Fan, Yongsheng & Lu, Dongsheng & Han, Yue & Yang, Jiaheng & Qian, Cheng & Li, Binyu, 2023. "Production of light aromatics from biomass components co-pyrolyzed with polyethylene via non-thermal plasma synergistic upgrading," Energy, Elsevier, vol. 265(C).
    18. Fan, Yongsheng & Zhu, Mengfeng & Jin, Lizhu & Cui, Entian & Zhu, Lei & Cai, Yixi & Zhao, Weidong, 2020. "Catalytic upgrading of biomass-derived vapors to bio-fuels via modified HZSM-5 coupled with DBD: Effects of different titanium sources," Renewable Energy, Elsevier, vol. 157(C), pages 100-115.
    19. Douvartzides, Savvas & Charisiou, Nikolaos D. & Wang, Wen & Papadakis, Vagelis G. & Polychronopoulou, Kyriaki & Goula, Maria A., 2022. "Catalytic fast pyrolysis of agricultural residues and dedicated energy crops for the production of high energy density transportation biofuels. Part II: Catalytic research," Renewable Energy, Elsevier, vol. 189(C), pages 315-338.
    20. Kwon, Dohee & Kim, Jee Young & Song, Hocheol & Lee, Jaewon & Tsang, Yiu Fai & Kwon, Eilhann E., 2025. "CO2-mediated pyrolysis for syngas generation from wood-plastic composite waste," Energy, Elsevier, vol. 319(C).

    More about this item

    Keywords

    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:225:y:2021:i:c:s0360544221004618. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.