IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v329y2025ics0360544225024545.html

Catalytic co-pyrolysis of hydrolyzed lignin and waste tires over NiMo modified HZSM-5/MCM-41 composite molecular sieve in microwave fluidized bed for monocyclic aromatic hydrocarbons

Author

Listed:
  • Wang, Wei
  • Zhong, Zhaoping
  • Zheng, Xiang
  • Ye, Qihang
  • Li, Yihui
  • Yang, Yuxuan
  • Qi, Renzhi

Abstract

High oxygen content is unfavorable for the deoxygenation process during the thermal conversion of hydrolyzed lignin into liquid fuel. This study investigated the effects of nickel and molybdenum supported on molecular sieves, as well as temperature, on the catalytic co-pyrolysis of hydrolyzed lignin and waste tires in a microwave fluidized bed for the production of monocyclic aromatics. Results indicated that the hydrocarbon radicals generated by the added waste tires quenched the oxygen radicals from hydrolyzed lignin, improved the distribution of co-pyrolysis products and mitigated the coking of the catalyst. Compared to the composite molecular sieve carrier, under the action of the bimetallic co-loaded catalyst, at 550 °C and with a Ni:Mo ratio of 2:1, the ideal bio-oil yield reached the highest of 42.64 wt%, and the selectivity of MAHs is 46.15 %. The microwave fluidized bed catalytic co-pyrolysis process provides an efficient approach for converting organic solid wastes, such as hydrolyzed lignin and waste tires, into high-value products, including monoaromatic hydrocarbons.

Suggested Citation

  • Wang, Wei & Zhong, Zhaoping & Zheng, Xiang & Ye, Qihang & Li, Yihui & Yang, Yuxuan & Qi, Renzhi, 2025. "Catalytic co-pyrolysis of hydrolyzed lignin and waste tires over NiMo modified HZSM-5/MCM-41 composite molecular sieve in microwave fluidized bed for monocyclic aromatic hydrocarbons," Energy, Elsevier, vol. 329(C).
    • Handle: RePEc:eee:energy:v:329:y:2025:i:c:s0360544225024545
    DOI: 10.1016/j.energy.2025.136812
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544225024545
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2025.136812?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to

    for a different version of it.

    References listed on IDEAS

    as
    1. Niu, Miaomiao & Sun, Rongyue & Ding, Kuan & Gu, Haiming & Cui, Xiaobo & Wang, Liang & Hu, Jichu, 2022. "Synergistic effect on thermal behavior and product characteristics during co-pyrolysis of biomass and waste tire: Influence of biomass species and waste blending ratios," Energy, Elsevier, vol. 240(C).
    2. Kan, Tao & Strezov, Vladimir & Evans, Tim J., 2016. "Lignocellulosic biomass pyrolysis: A review of product properties and effects of pyrolysis parameters," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1126-1140.
    3. Luo, Juan & Sun, Shichang & Chen, Xing & Lin, Junhao & Ma, Rui & Zhang, Rui & Fang, Lin, 2021. "In-depth exploration of the energy utilization and pyrolysis mechanism of advanced continuous microwave pyrolysis," Applied Energy, Elsevier, vol. 292(C).
    4. Chio, Chonlong & Sain, Mohini & Qin, Wensheng, 2019. "Lignin utilization: A review of lignin depolymerization from various aspects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 232-249.
    5. Xu, Hao & Cheng, Shuo & Hungwe, Douglas & Yoshikawa, Kunio & Takahashi, Fumitake, 2022. "Co-pyrolysis coupled with torrefaction enhances hydrocarbons production from rice straw and oil sludge: The effect of torrefaction on co-pyrolysis synergistic behaviors," Applied Energy, Elsevier, vol. 327(C).
    6. Bhoi, P.R. & Ouedraogo, A.S. & Soloiu, V. & Quirino, R., 2020. "Recent advances on catalysts for improving hydrocarbon compounds in bio-oil of biomass catalytic pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 121(C).
    7. Zeyou Pan & Allen Puente-Urbina & Syeda Rabia Batool & Andras Bodi & Xiangkun Wu & Zihao Zhang & Jeroen A. Bokhoven & Patrick Hemberger, 2023. "Tuning the zeolite acidity enables selectivity control by suppressing ketene formation in lignin catalytic pyrolysis," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    8. Ambursa, Murtala M. & Juan, Joon Ching & Yahaya, Y. & Taufiq-Yap, Y.H. & Lin, Yu-Chuan & Lee, Hwei Voon, 2021. "A review on catalytic hydrodeoxygenation of lignin to transportation fuels by using nickel-based catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    9. Czajczyńska, Dina & Krzyżyńska, Renata & Jouhara, Hussam & Spencer, Nik, 2017. "Use of pyrolytic gas from waste tire as a fuel: A review," Energy, Elsevier, vol. 134(C), pages 1121-1131.
    10. Li, Tan & Su, Jing & Wang, Huiyuan & Wang, Cong & Xie, Wen & Wang, Kaige, 2022. "Catalytic hydropyrolysis of lignin using NiMo-doped catalysts: Catalyst evaluation and mechanism analysis," Applied Energy, Elsevier, vol. 316(C).
    11. Natarianto Indrawan & Betty Simkins & Ajay Kumar & Raymond L. Huhnke, 2020. "Economics of Distributed Power Generation via Gasification of Biomass and Municipal Solid Waste," Energies, MDPI, vol. 13(14), pages 1-18, July.
    12. Wang, Jia & Zhong, Zhaoping & Ding, Kuan & Zhang, Bo & Deng, Aidong & Min, Min & Chen, Paul & Ruan, Roger, 2017. "Co-pyrolysis of bamboo residual with waste tire over dual catalytic stage of CaO and co-modified HZSM-5," Energy, Elsevier, vol. 133(C), pages 90-98.
    13. Fan, Yongsheng & Lu, Dongsheng & Han, Yue & Yang, Jiaheng & Qian, Cheng & Li, Binyu, 2023. "Production of light aromatics from biomass components co-pyrolyzed with polyethylene via non-thermal plasma synergistic upgrading," Energy, Elsevier, vol. 265(C).
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Arabiourrutia, Miriam & Lopez, Gartzen & Artetxe, Maite & Alvarez, Jon & Bilbao, Javier & Olazar, Martin, 2020. "Waste tyre valorization by catalytic pyrolysis – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 129(C).
    2. Chen, Xiangmeng & Shafizadeh, Alireza & Shahbeik, Hossein & Nadian, Mohammad Hossein & Golvirdizadeh, Milad & Peng, Wanxi & Lam, Su Shiung & Tabatabaei, Meisam & Aghbashlo, Mortaza, 2025. "Enhanced bio-oil production from biomass catalytic pyrolysis using machine learning," Renewable and Sustainable Energy Reviews, Elsevier, vol. 209(C).
    3. Luo, Zhongfan & Cao, Danyang & Jiang, Peng & Chen, Jingjing & Ji, Tuo & Lin, Han & Lu, Xiaohua & Mu, Liwen & Zhu, Jiahua, 2025. "Recent progress in microwave-assisted lignin conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 219(C).
    4. Wang, Shaoqing & Li, Zhihe & Yi, Weiming & Fu, Peng & Zhang, Andong & Bai, Xueyuan, 2021. "Renewable aromatic hydrocarbons production from catalytic pyrolysis of lignin with Al-SBA-15 and HZSM-5: Synergistic effect and coke behaviour," Renewable Energy, Elsevier, vol. 163(C), pages 1673-1681.
    5. Angelika Sita Ouedraogo & Robert Scott Frazier & Ajay Kumar, 2021. "Comparative Life Cycle Assessment of Gasification and Landfilling for Disposal of Municipal Solid Wastes," Energies, MDPI, vol. 14(21), pages 1-15, October.
    6. Chen, Mingqiang & Li, Hong & Wang, Yishuang & Tang, Zhiyuan & Dai, Wei & Li, Chang & Yang, Zhonglian & Wang, Jun, 2023. "Lignin depolymerization for aromatic compounds over Ni-Ce/biochar catalyst under aqueous-phase glycerol," Applied Energy, Elsevier, vol. 332(C).
    7. Xu, Hao & Hungwe, Douglas & Yang, Pu & Yu, Mengzhu & Cheng, Shuo & Yoshikawa, Kunio & Takahashi, Fumitake, 2024. "Oil sludge addition enables prediction of biomass pyrolysis product profiles by synergistic behaviors between biomass components and oil sludge," Applied Energy, Elsevier, vol. 362(C).
    8. Qian, Qian & Luo, Zhongyang & Sun, Haoran & Wei, Qi & Shi, Jingkang & Li, Longfei & Wang, Kaige & Zhou, Jinsong, 2024. "Process evaluation of simulated novel cellulosic ethanol biorefineries coupled with lignin thermochemical conversion," Renewable Energy, Elsevier, vol. 231(C).
    9. Liu, Jie & Zhang, Zonghui & Zhang, Mingrui & Kaya, Madalina Georgiana Albu & Wang, Fang & Tang, Keyong, 2024. "Co-pyrolysis of chrome-tanned leather shavings with wheat straw: Thermal behavior, kinetics and pyrolysis products," Energy, Elsevier, vol. 301(C).
    10. Chen, Rongjie & Lun, Liyong & Cong, Kunlin & Li, Qinghai & Zhang, Yanguo, 2019. "Insights into pyrolysis and co-pyrolysis of tobacco stalk and scrap tire: Thermochemical behaviors, kinetics, and evolved gas analysis," Energy, Elsevier, vol. 183(C), pages 25-34.
    11. Reyes, Y.A. & Pérez, M. & Barrera, E.L. & Martínez, Y. & Cheng, K.K., 2022. "Thermochemical conversion processes of Dichrostachys cinerea as a biofuel: A review of the Cuban case," Renewable and Sustainable Energy Reviews, Elsevier, vol. 160(C).
    12. Wang, Shoujun & Cheng, Mingqian & Xie, Ming & Yang, Yanyu & Liu, Tingting & Zhou, Tao & Cen, Qihong & Liu, Zewei & Li, Bin, 2025. "From waste to energy: Comprehensive understanding of the thermal-chemical utilization techniques for waste tire recycling," Renewable and Sustainable Energy Reviews, Elsevier, vol. 211(C).
    13. Liu, Ruo-Ying & Lan, Hai-Na & Liu, Zhi-Hua & Li, Bing-Zhi & Yuan, Ying-Jin, 2024. "Microbial valorization of lignin toward coumarins: Challenges and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 191(C).
    14. Lee, Seokhwan & Woo, Sang Hee & Kim, Yongrae & Choi, Young & Kang, Kernyong, 2020. "Combustion and emission characteristics of a diesel-powered generator running with N-butanol/coffee ground pyrolysis oil/diesel blended fuel," Energy, Elsevier, vol. 206(C).
    15. JoungDu Shin & SangWon Park & Changyoon Jeong, 2020. "Assessment of Agro-Environmental Impacts for Supplemented Methods to Biochar Manure Pellets during Rice ( Oryza sativa L.) Cultivation," Energies, MDPI, vol. 13(8), pages 1-14, April.
    16. Zihao Zhang & Qiang Li & Xiangkun Wu & Claire Bourmaud & Dionisios G. Vlachos & Jeremy Luterbacher & Andras Bodi & Patrick Hemberger, 2024. "A solution for 4-propylguaiacol hydrodeoxygenation without ring saturation," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    17. Yang, Yuhan & Wang, Tiancheng & Hu, Hongyun & Yao, Dingding & Zou, Chan & Xu, Kai & Li, Xian & Yao, Hong, 2021. "Influence of partial components removal on pyrolysis behavior of lignocellulosic biowaste in molten salts," Renewable Energy, Elsevier, vol. 180(C), pages 616-625.
    18. Primaz, Carmem T. & Ribes-Greus, Amparo & Jacques, Rosângela A., 2021. "Valorization of cotton residues for production of bio-oil and engineered biochar," Energy, Elsevier, vol. 235(C).
    19. Qin, Fanzhi & Zhang, Chen & Zeng, Guangming & Huang, Danlian & Tan, Xiaofei & Duan, Abing, 2022. "Lignocellulosic biomass carbonization for biochar production and characterization of biochar reactivity," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    20. Shao, Shanshan & Zhang, Pengfei & Xiang, Xianliang & Li, Xiaohua & Zhang, Huiyan, 2022. "Promoted ketonization of bagasse pyrolysis gas over red mud-based oxides," Renewable Energy, Elsevier, vol. 190(C), pages 11-18.

    More about this item

    Keywords

    ;
    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:329:y:2025:i:c:s0360544225024545. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.