IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v12y2019i18p3474-d265523.html
   My bibliography  Save this article

Hydro-Pyrolysis and Catalytic Upgrading of Biomass and Its Hydroxy Residue Fast Pyrolysis Vapors

Author

Listed:
  • Yichen Liu

    (Carbolea Research Group, Department of Chemical Sciences, University of Limerick, Limerick V94T9PX, Ireland)

  • James J. Leahy

    (Carbolea Research Group, Department of Chemical Sciences, University of Limerick, Limerick V94T9PX, Ireland
    Bernall Institute, University of Limerick, Limerick V94 T9PX, Ireland)

  • Jacek Grams

    (Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland)

  • Witold Kwapinski

    (Carbolea Research Group, Department of Chemical Sciences, University of Limerick, Limerick V94T9PX, Ireland
    Bernall Institute, University of Limerick, Limerick V94 T9PX, Ireland)

Abstract

Fast pyrolysis of Miscanthus, its hydrolysis residue and lignin were carried with a pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) followed by online vapor catalytic upgrading with sulfated ZrO 2 , sulfated TiO 2 and sulfated 60 wt.% ZrO 2 -TiO 2 . The most evident influence of the catalyst on the vapor phase composition was observed for aromatic hydrocarbons, light phenols and heavy phenols. A larger amount of light phenols was detected, especially when 60 wt.% ZrO 2 -TiO 2 was present. Thus, a lower average molecular weight and lower viscosity of bio-oil could be obtained with this catalyst. Pyrolysis was also performed at different pressures of hydrogen. The pressure of H2 has a great effect on the overall yield and the composition of biomass vapors. The peak area percentages of both aromatic hydrocarbons and cyclo-alkanes are enhanced with the increasing of H2 pressure. The overall yields are higher with the addition of either H 2 or sulfated catalysts. This is beneficial as phenols are valuable chemicals, thus, increasing the value of bio-oil. The results show that the hydrolysis residue has the potential to become a resource for phenol production.

Suggested Citation

  • Yichen Liu & James J. Leahy & Jacek Grams & Witold Kwapinski, 2019. "Hydro-Pyrolysis and Catalytic Upgrading of Biomass and Its Hydroxy Residue Fast Pyrolysis Vapors," Energies, MDPI, vol. 12(18), pages 1-18, September.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:18:p:3474-:d:265523
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/12/18/3474/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/12/18/3474/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Qiang Lu & Zhi-Fei Zhang & Chang-Qing Dong & Xi-Feng Zhu, 2010. "Catalytic Upgrading of Biomass Fast Pyrolysis Vapors with Nano Metal Oxides: An Analytical Py-GC/MS Study," Energies, MDPI, vol. 3(11), pages 1-16, November.
    2. Xu, Ying & Wang, Tiejun & Ma, Longlong & Zhang, Qi & Liang, Wei, 2010. "Upgrading of the liquid fuel from fast pyrolysis of biomass over MoNi/[gamma]-Al2O3 catalysts," Applied Energy, Elsevier, vol. 87(9), pages 2886-2891, September.
    3. Richard Ahorsu & Francesc Medina & Magda Constantí, 2018. "Significance and Challenges of Biomass as a Suitable Feedstock for Bioenergy and Biochemical Production: A Review," Energies, MDPI, vol. 11(12), pages 1-19, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Li, Tan & Su, Jing & Wang, Huiyuan & Wang, Cong & Xie, Wen & Wang, Kaige, 2022. "Catalytic hydropyrolysis of lignin using NiMo-doped catalysts: Catalyst evaluation and mechanism analysis," Applied Energy, Elsevier, vol. 316(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Kabir, G. & Hameed, B.H., 2017. "Recent progress on catalytic pyrolysis of lignocellulosic biomass to high-grade bio-oil and bio-chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 945-967.
    2. Danilo Arcentales-Bastidas & Carla Silva & Angel D. Ramirez, 2022. "The Environmental Profile of Ethanol Derived from Sugarcane in Ecuador: A Life Cycle Assessment Including the Effect of Cogeneration of Electricity in a Sugar Industrial Complex," Energies, MDPI, vol. 15(15), pages 1-24, July.
    3. Cheng Li & Xiaochen Yue & Jun Yang & Yafeng Yang & Haiping Gu & Wanxi Peng, 2019. "Catalytic Fast Pyrolysis of Forestry Wood Waste for Bio-Energy Recovery Using Nano-Catalysts," Energies, MDPI, vol. 12(20), pages 1-12, October.
    4. Mariana S. T. Amândio & Joana M. Pereira & Jorge M. S. Rocha & Luísa S. Serafim & Ana M. R. B. Xavier, 2022. "Getting Value from Pulp and Paper Industry Wastes: On the Way to Sustainability and Circular Economy," Energies, MDPI, vol. 15(11), pages 1-31, June.
    5. Bogusława Waliszewska & Mieczysław Grzelak & Eliza Gaweł & Agnieszka Spek-Dźwigała & Agnieszka Sieradzka & Wojciech Czekała, 2021. "Chemical Characteristics of Selected Grass Species from Polish Meadows and Their Potential Utilization for Energy Generation Purposes," Energies, MDPI, vol. 14(6), pages 1-14, March.
    6. Theodore Dickerson & Juan Soria, 2013. "Catalytic Fast Pyrolysis: A Review," Energies, MDPI, vol. 6(1), pages 1-25, January.
    7. Małgorzata Hawrot-Paw & Aleksander Stańczuk, 2022. "From Waste Biomass to Cellulosic Ethanol by Separate Hydrolysis and Fermentation (SHF) with Trichoderma viride," Sustainability, MDPI, vol. 15(1), pages 1-10, December.
    8. Lin, Junhao & Sun, Shichang & Cui, Chongwei & Ma, Rui & Fang, Lin & Zhang, Peixin & Quan, Zonggang & Song, Xin & Yan, Jianglong & Luo, Juan, 2019. "Hydrogen-rich bio-gas generation and optimization in relation to heavy metals immobilization during Pd-catalyzed supercritical water gasification of sludge," Energy, Elsevier, vol. 189(C).
    9. Takahiro Nakashima & Keiichiro Ueno & Eisuke Fujita & Shoko Ishikawa, 2020. "Evaluation of Polyethylene Mulching and Sugarcane Cultivar on Energy Inputs and Greenhouse Gas Emissions for Ethanol Production in a Temperate Climate," Energies, MDPI, vol. 13(17), pages 1-17, August.
    10. Zhijun Zhang & Shujuan Sui & Fengqiang Wang & Qingwen Wang & Charles U. Pittman, 2013. "Catalytic Conversion of Bio-Oil to Oxygen-Containing Fuels by Acid-Catalyzed Reaction with Olefins and Alcohols over Silica Sulfuric Acid," Energies, MDPI, vol. 6(9), pages 1-20, September.
    11. Laosiripojana, Weerawan & Kiatkittipong, Worapon & Sakdaronnarong, Chularat & Assabumrungrat, Suttichai & Laosiripojana, Navadol, 2019. "Catalytic hydrotreatment of pyrolysis-oil with bimetallic Ni-Cu catalysts supported by several mono-oxide and mixed-oxide materials," Renewable Energy, Elsevier, vol. 135(C), pages 1048-1055.
    12. Ong, Victor Zhenquan & Wu, Ta Yeong, 2020. "An application of ultrasonication in lignocellulosic biomass valorisation into bio-energy and bio-based products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 132(C).
    13. Rossana Liguori & Anna Pennacchio & Luciana Porto de Souza Vandenberghe & Addolorata De Chiaro & Leila Birolo & Carlos Ricardo Soccol & Vincenza Faraco, 2021. "Screening of Fungal Strains for Cellulolytic and Xylanolytic Activities Production and Evaluation of Brewers’ Spent Grain as Substrate for Enzyme Production by Selected Fungi," Energies, MDPI, vol. 14(15), pages 1-17, July.
    14. Long, Jinxing & Shu, Riyang & Yuan, Zhengqiu & Wang, Tiejun & Xu, Ying & Zhang, Xinghua & Zhang, Qi & Ma, Longlong, 2015. "Efficient valorization of lignin depolymerization products in the present of NixMg1−xO," Applied Energy, Elsevier, vol. 157(C), pages 540-545.
    15. Ma, Wenchao & Liu, Bin & Zhang, Ruixue & Gu, Tianbao & Ji, Xiang & Zhong, Lei & Chen, Guanyi & Ma, Longlong & Cheng, Zhanjun & Li, Xiangping, 2018. "Co-upgrading of raw bio-oil with kitchen waste oil through fluid catalytic cracking (FCC)," Applied Energy, Elsevier, vol. 217(C), pages 233-240.
    16. Zhang, Zhaoxia & Bi, Peiyan & Jiang, Peiwen & Fan, Minghui & Deng, Shumei & Zhai, Qi & Li, Quanxin, 2015. "Production of gasoline fraction from bio-oil under atmospheric conditions by an integrated catalytic transformation process," Energy, Elsevier, vol. 90(P2), pages 1922-1930.
    17. Muley, P.D. & Henkel, C.E. & Aguilar, G. & Klasson, K.T. & Boldor, D., 2016. "Ex situ thermo-catalytic upgrading of biomass pyrolysis vapors using a traveling wave microwave reactor," Applied Energy, Elsevier, vol. 183(C), pages 995-1004.
    18. Qiang Lu & Zhi-Bo Zhang & Hang-Tao Liao & Xiao-Chu Yang & Chang-Qing Dong, 2012. "Lubrication Properties of Bio-Oil and Its Emulsions with Diesel Oil," Energies, MDPI, vol. 5(3), pages 1-11, March.
    19. Oh, Shinyoung & Lee, Jae Hoon & Choi, In-Gyu & Choi, Joon Weon, 2020. "Enhancement of bio-oil hydrodeoxygenation activity over Ni-based bimetallic catalysts supported on SBA-15," Renewable Energy, Elsevier, vol. 149(C), pages 1-10.
    20. Eleni F. Iliopoulou & Kostas S. Triantafyllidis & Angelos A. Lappas, 2019. "Overview of catalytic upgrading of biomass pyrolysis vapors toward the production of fuels and high‐value chemicals," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 8(1), January.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:12:y:2019:i:18:p:3474-:d:265523. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.