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Prediction of fast pyrolysis products yields using lignocellulosic compounds and ash contents

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  • Trubetskaya, Anna
  • Timko, Michael T
  • Umeki, Kentaro

Abstract

The effects of lignocellulosic biomass composition on product yields and distributions were studied under high-temperature pyrolysis conditions (800–1250 °C) in a drop tube reactor. Several types of biomass were studied along with xylan, cellulose, and two types of lignin as model feeds. Among the model feeds, soot yields obtained from lignin pyrolysis were greater than those obtained from cellulose or xylan. Cellulose pyrolysis produced mostly gaseous products, along with small amounts of tars. Impregnation of lignin with alkali metals greatly reduced tar and soot formation, simultaneously increasing the hydrogen content of the syngas product. An empirical model predicted with reasonable accuracy trends in the product yields obtained from pyrolysis of whole biomass samples using as input data obtained from model feeds composition data and the pyrolysis temperature. Reaction temperature and ash content both have a strong influences on char yield, whereas gas yields were mostly affected by the reaction temperature.

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  • Trubetskaya, Anna & Timko, Michael T & Umeki, Kentaro, 2020. "Prediction of fast pyrolysis products yields using lignocellulosic compounds and ash contents," Applied Energy, Elsevier, vol. 257(C).
  • Handle: RePEc:eee:appene:v:257:y:2020:i:c:s0306261919315843
    DOI: 10.1016/j.apenergy.2019.113897
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    References listed on IDEAS

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    1. Costa, Juliana E.B. & Barbosa, Andrey S. & Melo, Marcus A.F. & Melo, Dulce M.A. & Medeiros, Rodolfo L.B.A. & Braga, Renata M., 2022. "Renewable aromatics through catalytic pyrolysis of coconut fiber (Cocos nucífera Linn.) using low cost HZSM-5," Renewable Energy, Elsevier, vol. 191(C), pages 439-446.
    2. He, Qing & Guo, Qinghua & Umeki, Kentaro & Ding, Lu & Wang, Fuchen & Yu, Guangsuo, 2021. "Soot formation during biomass gasification: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    3. Wu, Kai & Yang, Ke & Zhu, Yiwen & Luo, Bingbing & Chu, Chenyang & Li, Mingfan & Zhang, Yuanjian & Zhang, Huiyan, 2023. "The co-pyrolysis interactionsof isolated lignins and cellulose by experiments and theoretical calculations," Energy, Elsevier, vol. 263(PC).
    4. Chen, Tao & Sjöblom, Jonas & Ström, Henrik, 2022. "Numerical investigations of soot generation during wood-log combustion," Applied Energy, Elsevier, vol. 325(C).
    5. Zhang, Huiyan & Zhu, Yiwen & Liu, Qingyu & Li, Xiaowen, 2022. "Preparation of porous carbon materials from biomass pyrolysis vapors for hydrogen storage," Applied Energy, Elsevier, vol. 306(PB).
    6. Kim, Hoyong & Sriram, Subash & Fang, Tiegang & Kelley, Stephen & Park, Sunkyu, 2021. "An eco-friendly approach for blending of fast-pyrolysis bio-oil in petroleum-derived fuel by controlling ash content of loblolly pine," Renewable Energy, Elsevier, vol. 179(C), pages 2063-2070.

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