IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v212y2018icp1489-1500.html
   My bibliography  Save this article

Characterization and reactivity of soot from fast pyrolysis of lignocellulosic compounds and monolignols

Author

Listed:
  • Trubetskaya, Anna
  • Brown, Avery
  • Tompsett, Geoffrey A.
  • Timko, Michael T.
  • Kling, Jens
  • Broström, Markus
  • Andersen, Mogens Larsen
  • Umeki, Kentaro

Abstract

This study presents the effect of lignocellulosic compounds and monolignols on the yield, nanostructure and reactivity of soot generated at 1250 °C in a drop tube furnace. The structure of soot was characterized by electron microscopy techniques, Raman spectroscopy and electron spin resonance spectroscopy. The CO2 reactivity of soot was investigated by thermogravimetric analysis. Soot from cellulose was more reactive than soot produced from extractives, lignin and monolignols. Soot reactivity was correlated with the separation distances between adjacent graphene layers, as measured using transmission electron microscopy. Particle size, free radical concentration, differences in a degree of curvature and multi-core structures influenced the soot reactivity less than the interlayer separation distances. Soot yield was correlated with the lignin content of the feedstock. The selection of the extraction solvent had a strong influence on the soot reactivity. The Soxhlet extraction of softwood and wheat straw lignin soot using methanol decreased the soot reactivity, whereas acetone extraction had only a modest effect.

Suggested Citation

  • Trubetskaya, Anna & Brown, Avery & Tompsett, Geoffrey A. & Timko, Michael T. & Kling, Jens & Broström, Markus & Andersen, Mogens Larsen & Umeki, Kentaro, 2018. "Characterization and reactivity of soot from fast pyrolysis of lignocellulosic compounds and monolignols," Applied Energy, Elsevier, vol. 212(C), pages 1489-1500.
    • Handle: RePEc:eee:appene:v:212:y:2018:i:c:p:1489-1500
    DOI: 10.1016/j.apenergy.2017.12.068
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S030626191731783X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2017.12.068?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Trubetskaya, Anna & Jensen, Peter Arendt & Jensen, Anker Degn & Garcia Llamas, Angel David & Umeki, Kentaro & Gardini, Diego & Kling, Jens & Bates, Richard B. & Glarborg, Peter, 2016. "Effects of several types of biomass fuels on the yield, nanostructure and reactivity of soot from fast pyrolysis at high temperatures," Applied Energy, Elsevier, vol. 171(C), pages 468-482.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Trubetskaya, Anna & Timko, Michael T & Umeki, Kentaro, 2020. "Prediction of fast pyrolysis products yields using lignocellulosic compounds and ash contents," Applied Energy, Elsevier, vol. 257(C).
    2. Wu, Shaohua & Zhou, Dezhi & Yang, Wenming, 2019. "Implementation of an efficient method of moments for treatment of soot formation and oxidation processes in three-dimensional engine simulations," Applied Energy, Elsevier, vol. 254(C).
    3. He, Qing & Guo, Qinghua & Umeki, Kentaro & Ding, Lu & Wang, Fuchen & Yu, Guangsuo, 2021. "Soot formation during biomass gasification: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    4. Wu, Shaohua & Lao, Chung Ting & Akroyd, Jethro & Mosbach, Sebastian & Yang, Wenming & Kraft, Markus, 2020. "A joint moment projection method and maximum entropy approach for simulation of soot formation and oxidation in diesel engines," Applied Energy, Elsevier, vol. 258(C).
    5. Chen, Tao & Sjöblom, Jonas & Ström, Henrik, 2022. "Numerical investigations of soot generation during wood-log combustion," Applied Energy, Elsevier, vol. 325(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Li, Dun & Gao, Jianmin & Zhao, Ziqi & Du, Qian & Dong, Heming & Cui, Zhaoyang, 2022. "Effects of iron on coal pyrolysis-derived soot formation," Energy, Elsevier, vol. 249(C).
    2. He, Qing & Guo, Qinghua & Umeki, Kentaro & Ding, Lu & Wang, Fuchen & Yu, Guangsuo, 2021. "Soot formation during biomass gasification: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    3. Wu, Zhiqiang & Yang, Wangcai & Meng, Haiyu & Zhao, Jun & Chen, Lin & Luo, Zhengyuan & Wang, Shuzhong, 2017. "Physicochemical structure and gasification reactivity of co-pyrolysis char from two kinds of coal blended with lignocellulosic biomass: Effects of the carboxymethylcellulose sodium," Applied Energy, Elsevier, vol. 207(C), pages 96-106.
    4. Wu, Shaohua & Yang, Wenming & Xu, Hongpeng & Jiang, Yu, 2019. "Investigation of soot aggregate formation and oxidation in compression ignition engines with a pseudo bi-variate soot model," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    5. Lee, Jechan & Yang, Xiao & Cho, Seong-Heon & Kim, Jae-Kon & Lee, Sang Soo & Tsang, Daniel C.W. & Ok, Yong Sik & Kwon, Eilhann E., 2017. "Pyrolysis process of agricultural waste using CO2 for waste management, energy recovery, and biochar fabrication," Applied Energy, Elsevier, vol. 185(P1), pages 214-222.
    6. Wu, Shaohua & Zhou, Dezhi & Yang, Wenming, 2019. "Implementation of an efficient method of moments for treatment of soot formation and oxidation processes in three-dimensional engine simulations," Applied Energy, Elsevier, vol. 254(C).
    7. Trubetskaya, Anna & Souihi, Nabil & Umeki, Kentaro, 2019. "Categorization of tars from fast pyrolysis of pure lignocellulosic compounds at high temperature," Renewable Energy, Elsevier, vol. 141(C), pages 751-759.
    8. Cui, Tongmin & Fan, Wenke & Dai, Zhenghua & Guo, Qinghua & Yu, Guangsuo & Wang, Fuchen, 2016. "Variation of the coal chemical structure and determination of the char molecular size at the early stage of rapid pyrolysis," Applied Energy, Elsevier, vol. 179(C), pages 650-659.
    9. Shirazi, Yaser & Viamajala, Sridhar & Varanasi, Sasidhar, 2016. "High-yield production of fuel- and oleochemical-precursors from triacylglycerols in a novel continuous-flow pyrolysis reactor," Applied Energy, Elsevier, vol. 179(C), pages 755-764.
    10. Trubetskaya, Anna & Timko, Michael T & Umeki, Kentaro, 2020. "Prediction of fast pyrolysis products yields using lignocellulosic compounds and ash contents," Applied Energy, Elsevier, vol. 257(C).
    11. Wu, Shaohua & Lao, Chung Ting & Akroyd, Jethro & Mosbach, Sebastian & Yang, Wenming & Kraft, Markus, 2020. "A joint moment projection method and maximum entropy approach for simulation of soot formation and oxidation in diesel engines," Applied Energy, Elsevier, vol. 258(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:212:y:2018:i:c:p:1489-1500. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.