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Improved methods to measure hydrogen crossover current in proton exchange membrane fuel cell

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  • Pei, Pucheng
  • Wu, Ziyao
  • Li, Yuehua
  • Jia, Xiaoning
  • Chen, Dongfang
  • Huang, Shangwei

Abstract

Hydrogen crossover current has a great influence on the performance and durability of proton exchange membrane (PEM) fuel cells. The common measuring method is linear sweep voltammetry (LSV). But some usual approximations, such as ignoring the influence of scan rates or short-circuit resistances, can lead to greater measurement deviations. Therefore, in this study to accurately measure hydrogen crossover current, LSV is improved by building a novel charging model based on fitted zero scan rate curves and on taking effects of short circuit into consideration. On the basis of this new model, galvanostatic charging method is improved by taking short circuit of PEMs into consideration and a mass spectrometry assisted with hydrogen pump is proposed with no need of calibration with standard gas. Hydrogen crossover current and short-circuit resistance of a 34 cm2 single cell are measured by three improved methods, which are then compared with methods previously available. It is found that hydrogen crossover currents are reduced and more accurate than those obtained by previous methods, and values obtained by different improved methods are highly consistent with each other. So the proposed charging model is valid and can be used to optimize other electrochemical measurements of fuel cells.

Suggested Citation

  • Pei, Pucheng & Wu, Ziyao & Li, Yuehua & Jia, Xiaoning & Chen, Dongfang & Huang, Shangwei, 2018. "Improved methods to measure hydrogen crossover current in proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 215(C), pages 338-347.
    • Handle: RePEc:eee:appene:v:215:y:2018:i:c:p:338-347
    DOI: 10.1016/j.apenergy.2018.02.002
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    References listed on IDEAS

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    1. Mark K. Debe, 2012. "Electrocatalyst approaches and challenges for automotive fuel cells," Nature, Nature, vol. 486(7401), pages 43-51, June.
    2. Baik, Kyung Don & Hong, Bo Ki & Kim, Min Soo, 2013. "Effects of operating parameters on hydrogen crossover rate through Nafion® membranes in polymer electrolyte membrane fuel cells," Renewable Energy, Elsevier, vol. 57(C), pages 234-239.
    3. Cao, Tao-Feng & Lin, Hong & Chen, Li & He, Ya-Ling & Tao, Wen-Quan, 2013. "Numerical investigation of the coupled water and thermal management in PEM fuel cell," Applied Energy, Elsevier, vol. 112(C), pages 1115-1125.
    4. Wang, Yun & Chen, Ken S. & Mishler, Jeffrey & Cho, Sung Chan & Adroher, Xavier Cordobes, 2011. "A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research," Applied Energy, Elsevier, vol. 88(4), pages 981-1007, April.
    5. Chakraborty, Uttara, 2016. "Fuel crossover and internal current in proton exchange membrane fuel cell modeling," Applied Energy, Elsevier, vol. 163(C), pages 60-62.
    6. Nam, Jinmoo & Chippar, Purushothama & Kim, Whangi & Ju, Hyunchul, 2010. "Numerical analysis of gas crossover effects in polymer electrolyte fuel cells (PEFCs)," Applied Energy, Elsevier, vol. 87(12), pages 3699-3709, December.
    7. Pei, Pucheng & Li, Yuehua & Xu, Huachi & Wu, Ziyao, 2016. "A review on water fault diagnosis of PEMFC associated with the pressure drop," Applied Energy, Elsevier, vol. 173(C), pages 366-385.
    8. Chen, Huicui & Pei, Pucheng & Song, Mancun, 2015. "Lifetime prediction and the economic lifetime of Proton Exchange Membrane fuel cells," Applied Energy, Elsevier, vol. 142(C), pages 154-163.
    9. Baik, Kyung Don & Kong, Im Mo & Hong, Bo Ki & Kim, Sae Hoon & Kim, Min Soo, 2013. "Local measurements of hydrogen crossover rate in polymer electrolyte membrane fuel cells," Applied Energy, Elsevier, vol. 101(C), pages 560-566.
    10. Kong, Im Mo & Choi, Jong Won & Kim, Sung Il & Lee, Eun Sook & Kim, Min Soo, 2015. "Experimental study on the self-humidification effect in proton exchange membrane fuel cells containing double gas diffusion backing layer," Applied Energy, Elsevier, vol. 145(C), pages 345-353.
    11. Jung, Aeri & Oh, Jongkil & Han, Kookil & Kim, Min Soo, 2016. "An experimental study on the hydrogen crossover in polymer electrolyte membrane fuel cells for various current densities," Applied Energy, Elsevier, vol. 175(C), pages 212-217.
    12. Lin, Chien-Hung & Tsai, Sung-Ying, 2012. "An investigation of coated aluminium bipolar plates for PEMFC," Applied Energy, Elsevier, vol. 100(C), pages 87-92.
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    Cited by:

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    3. Li, Yuehua & Pei, Pucheng & Ma, Ze & Ren, Peng & Huang, Hao, 2020. "Analysis of air compression, progress of compressor and control for optimal energy efficiency in proton exchange membrane fuel cell," Renewable and Sustainable Energy Reviews, Elsevier, vol. 133(C).
    4. Zheng Huang & Laisuo Su & Yunjie Yang & Linsong Gao & Xinyu Liu & Heng Huang & Yubai Li & Yongchen Song, 2023. "Three-Dimensional Simulation on the Effects of Different Parameters and Pt Loading on the Long-Term Performance of Proton Exchange Membrane Fuel Cells," Sustainability, MDPI, vol. 15(4), pages 1-22, February.
    5. Ren, Peng & Pei, Pucheng & Chen, Dongfang & Li, Yuehua & Wu, Ziyao & Zhang, Lu & Li, Zizhao & Wang, Mingkai & Wang, He & Wang, Bozheng & Wang, Xizhong, 2022. "Novel analytic method of membrane electrode assembly parameters for fuel cell consistency evaluation by micro-current excitation," Applied Energy, Elsevier, vol. 306(PB).
    6. Li, Bing & Wan, Kechuang & Xie, Meng & Chu, Tiankuo & Wang, Xiaolei & Li, Xiang & Yang, Daijun & Ming, Pingwen & Zhang, Cunman, 2022. "Durability degradation mechanism and consistency analysis for proton exchange membrane fuel cell stack," Applied Energy, Elsevier, vol. 314(C).
    7. Huo, Sen & Jiao, Kui & Park, Jae Wan, 2019. "On the water transport behavior and phase transition mechanisms in cold start operation of PEM fuel cell," Applied Energy, Elsevier, vol. 233, pages 776-788.
    8. Pan, Mingzhang & Pan, Chengjie & Li, Chao & Zhao, Jian, 2021. "A review of membranes in proton exchange membrane fuel cells: Transport phenomena, performance and durability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    9. Li, Sida & Wei, Xuezhe & Jiang, Shangfeng & Yuan, Hao & Ming, Pingwen & Wang, Xueyuan & Dai, Haifeng, 2022. "Hydrogen crossover diagnosis for fuel cell stack: An electrochemical impedance spectroscopy based method," Applied Energy, Elsevier, vol. 325(C).
    10. Yang, Zirong & Du, Qing & Jia, Zhiwei & Yang, Chunguang & Xuan, Jin & Jiao, Kui, 2019. "A comprehensive proton exchange membrane fuel cell system model integrating various auxiliary subsystems," Applied Energy, Elsevier, vol. 256(C).
    11. Ren, Peng & Meng, Yining & Pei, Pucheng & Fu, Xi & Chen, Dongfang & Li, Yuehua & Zhu, Zijing & Zhang, Lu & Wang, Mingkai, 2023. "Rapid synchronous state-of-health diagnosis of membrane electrode assemblies in fuel cell stacks," Applied Energy, Elsevier, vol. 330(PA).
    12. Wu, Ziyao & Pei, Pucheng & Xu, Huachi & Jia, Xiaoning & Ren, Peng & Wang, Bozheng, 2019. "Study on the effect of membrane electrode assembly parameters on polymer electrolyte membrane fuel cell performance by galvanostatic charging method," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    13. Chang, Huawei & Cai, Fengyang & Yu, Xianxian & Duan, Chen & Chan, Siew Hwa & Tu, Zhengkai, 2023. "Experimental study on the thermal management of an open-cathode air-cooled proton exchange membrane fuel cell stack with ultra-thin metal bipolar plates," Energy, Elsevier, vol. 263(PA).

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