IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v179y2016icp601-608.html
   My bibliography  Save this article

Enhancement on thermal properties of paraffin/calcium carbonate phase change microcapsules with carbon network

Author

Listed:
  • Wang, Tingyu
  • Wang, Shuangfeng
  • Geng, Lixia
  • Fang, Yutang

Abstract

For latent heat storage with phase change materials (PCM), heat transfer rate and energy storage efficiency are often limited by the low PCM thermal conductivity. Therefore, this paper develops a sort of new phase change composites (PCC) with double-layer network to enhance the thermal conductivity and thermal stability. Different mass fractions of expanded graphite (EG) as heat transfer promoter were added in the spindle microencapsulated phase change materials (MicroPCM). The relationship between the PCC thermal conductivity and carbon network structure was investigated. The thermal conductivity was measured by transient plane source method. The carbon network structure of PCC was detected by energy dispersive spectroscopy. Temperature-regulated property was captured by infrared imager. As a result, distinct carbon network structure in PCC was observed with 20% mass fraction of EG, the corresponding thermal conductivity was increased up to 7.5 times of the pristine paraffin. Negligible change in thermal properties of the PCC was confirmed after 100 times thermal cycling and 7days serving durability tests. The enhancement on thermal properties of the PCC is a promising route to achieve high energy storage efficiency targets of numerous thermal applications.

Suggested Citation

  • Wang, Tingyu & Wang, Shuangfeng & Geng, Lixia & Fang, Yutang, 2016. "Enhancement on thermal properties of paraffin/calcium carbonate phase change microcapsules with carbon network," Applied Energy, Elsevier, vol. 179(C), pages 601-608.
  • Handle: RePEc:eee:appene:v:179:y:2016:i:c:p:601-608
    DOI: 10.1016/j.apenergy.2016.07.026
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261916309679
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2016.07.026?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Sarı, Ahmet & Alkan, Cemil & Bilgin, Cahit, 2014. "Micro/nano encapsulation of some paraffin eutectic mixtures with poly(methyl methacrylate) shell: Preparation, characterization and latent heat thermal energy storage properties," Applied Energy, Elsevier, vol. 136(C), pages 217-227.
    2. Chai, Luxiao & Wang, Xiaodong & Wu, Dezhen, 2015. "Development of bifunctional microencapsulated phase change materials with crystalline titanium dioxide shell for latent-heat storage and photocatalytic effectiveness," Applied Energy, Elsevier, vol. 138(C), pages 661-674.
    3. Yang, Jialin & Yang, Lijun & Xu, Chao & Du, Xiaoze, 2016. "Experimental study on enhancement of thermal energy storage with phase-change material," Applied Energy, Elsevier, vol. 169(C), pages 164-176.
    4. Wang, Xianglei & Guo, Quangui & Wang, Junzhong & Zhong, Yajuan & Wang, Liyong & Wei, Xinghai & Liu, Lang, 2013. "Thermal conductivity enhancement of form-stable phase-change composites by milling of expanded graphite, micro-capsules and polyethylene," Renewable Energy, Elsevier, vol. 60(C), pages 506-509.
    5. Pereira da Cunha, Jose & Eames, Philip, 2016. "Thermal energy storage for low and medium temperature applications using phase change materials – A review," Applied Energy, Elsevier, vol. 177(C), pages 227-238.
    6. Jiang, Fuyun & Wang, Xiaodong & Wu, Dezhen, 2014. "Design and synthesis of magnetic microcapsules based on n-eicosane core and Fe3O4/SiO2 hybrid shell for dual-functional phase change materials," Applied Energy, Elsevier, vol. 134(C), pages 456-468.
    7. Li, Min & Chen, Meirong & Wu, Zhishen, 2014. "Enhancement in thermal property and mechanical property of phase change microcapsule with modified carbon nanotube," Applied Energy, Elsevier, vol. 127(C), pages 166-171.
    8. Liu, Lingkun & Su, Di & Tang, Yaojie & Fang, Guiyin, 2016. "Thermal conductivity enhancement of phase change materials for thermal energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 305-317.
    9. Wang, Tingyu & Wang, Shuangfeng & Luo, Ruilian & Zhu, Chunyu & Akiyama, Tomohiro & Zhang, Zhengguo, 2016. "Microencapsulation of phase change materials with binary cores and calcium carbonate shell for thermal energy storage," Applied Energy, Elsevier, vol. 171(C), pages 113-119.
    10. Tahan Latibari, Sara & Mehrali, Mohammad & Mehrali, Mehdi & Indra Mahlia, Teuku Meurah & Cornelis Metselaar, Hendrik Simon, 2013. "Synthesis, characterization and thermal properties of nanoencapsulated phase change materials via sol–gel method," Energy, Elsevier, vol. 61(C), pages 664-672.
    11. Nomura, Takahiro & Tabuchi, Kazuki & Zhu, Chunyu & Sheng, Nan & Wang, Shuangfeng & Akiyama, Tomohiro, 2015. "High thermal conductivity phase change composite with percolating carbon fiber network," Applied Energy, Elsevier, vol. 154(C), pages 678-685.
    12. Ma, Yanjie & Zong, Jiwen & Li, Wei & Chen, Long & Tang, Xiaofen & Han, Na & Wang, Jianping & Zhang, Xingxiang, 2015. "Synthesis and characterization of thermal energy storage microencapsulated n-dodecanol with acrylic polymer shell," Energy, Elsevier, vol. 87(C), pages 86-94.
    13. Rao, Zhonghao & Wang, Qingchao & Huang, Congliang, 2016. "Investigation of the thermal performance of phase change material/mini-channel coupled battery thermal management system," Applied Energy, Elsevier, vol. 164(C), pages 659-669.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Palacios, Anabel & Cong, Lin & Navarro, M.E. & Ding, Yulong & Barreneche, Camila, 2019. "Thermal conductivity measurement techniques for characterizing thermal energy storage materials – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 32-52.
    2. Wu, Shaofei & Yan, Ting & Kuai, Zihan & Pan, Weiguo, 2020. "Preparation and thermal property analysis of a novel phase change heat storage material," Renewable Energy, Elsevier, vol. 150(C), pages 1057-1065.
    3. Gondora, Wayne & Doudin, Khalid & Nowakowski, Daniel J. & Xiao, Bo & Ding, Yulong & Bridgwater, Tony & Yuan, Qingchun, 2016. "Encapsulation of phase change materials using rice-husk-char," Applied Energy, Elsevier, vol. 182(C), pages 274-281.
    4. Tu, Yubin & Zhu, Wei & Lu, Tianqi & Deng, Yuan, 2017. "A novel thermoelectric harvester based on high-performance phase change material for space application," Applied Energy, Elsevier, vol. 206(C), pages 1194-1202.
    5. Liu, Huan & Niu, Jinfei & Wang, Xiaodong & Wu, Dezhen, 2019. "Design and construction of mesoporous silica/n-eicosane phase-change nanocomposites for supercooling depression and heat transfer enhancement," Energy, Elsevier, vol. 188(C).
    6. Zhao, Yafei & Kong, Weixiao & Jin, Zunlong & Fu, Ye & Wang, Wencai & Zhang, Yatao & Liu, Jindun & Zhang, Bing, 2018. "Storing solar energy within Ag-Paraffin@Halloysite microspheres as a novel self-heating catalyst," Applied Energy, Elsevier, vol. 222(C), pages 180-188.
    7. Liu, Huan & Tian, Xinxin & Ouyang, Mize & Wang, Xiang & Wu, Dezhen & Wang, Xiaodong, 2021. "Microencapsulating n-docosane phase change material into CaCO3/Fe3O4 composites for high-efficient utilization of solar photothermal energy," Renewable Energy, Elsevier, vol. 179(C), pages 47-64.
    8. Yu, Qinghua & Jiang, Zhu & Cong, Lin & Lu, Tiejun & Suleiman, Bilyaminu & Leng, Guanghui & Wu, Zhentao & Ding, Yulong & Li, Yongliang, 2019. "A novel low-temperature fabrication approach of composite phase change materials for high temperature thermal energy storage," Applied Energy, Elsevier, vol. 237(C), pages 367-377.
    9. Zhu, Wei & Tu, Yubin & Deng, Yuan, 2018. "Multi-parameter optimization design of thermoelectric harvester based on phase change material for space generation," Applied Energy, Elsevier, vol. 228(C), pages 873-880.
    10. Tao, Jialu & Luan, Jingde & Liu, Yue & Qu, Daoyu & Yan, Zheng & Ke, Xin, 2022. "Technology development and application prospects of organic-based phase change materials: An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    11. Liu, Xianjie & Feng, Qian & Peng, Zhigang & Zheng, Yong & Liu, Huan, 2020. "Preparation and evaluation of micro-encapsulated thermal control materials for oil well cement slurry," Energy, Elsevier, vol. 208(C).
    12. Wang, Tingyu & Jiang, Yan & Huang, Jin & Wang, Shuangfeng, 2018. "High thermal conductive paraffin/calcium carbonate phase change microcapsules based composites with different carbon network," Applied Energy, Elsevier, vol. 218(C), pages 184-191.
    13. Huanpei Zheng & Changhong Wang, 2017. "Numerical and Experimental Studies on the Heat Transfer Performance of Copper Foam Filled with Paraffin," Energies, MDPI, vol. 10(7), pages 1-13, July.
    14. Feng, Qian & Liu, Xian-jie & Peng, Zhi-gang & Zheng, Yong & Huo, Jin-hua & Liu, Huan, 2019. "Preparation of low hydration heat cement slurry with micro-encapsulated thermal control material," Energy, Elsevier, vol. 187(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Tingyu & Wang, Shuangfeng & Luo, Ruilian & Zhu, Chunyu & Akiyama, Tomohiro & Zhang, Zhengguo, 2016. "Microencapsulation of phase change materials with binary cores and calcium carbonate shell for thermal energy storage," Applied Energy, Elsevier, vol. 171(C), pages 113-119.
    2. Umair, Malik Muhammad & Zhang, Yuang & Iqbal, Kashif & Zhang, Shufen & Tang, Bingtao, 2019. "Novel strategies and supporting materials applied to shape-stabilize organic phase change materials for thermal energy storage–A review," Applied Energy, Elsevier, vol. 235(C), pages 846-873.
    3. Geng, Xiaoye & Li, Wei & Wang, Yu & Lu, Jiangwei & Wang, Jianping & Wang, Ning & Li, Jianjie & Zhang, Xingxiang, 2018. "Reversible thermochromic microencapsulated phase change materials for thermal energy storage application in thermal protective clothing," Applied Energy, Elsevier, vol. 217(C), pages 281-294.
    4. Wang, Tingyu & Jiang, Yan & Huang, Jin & Wang, Shuangfeng, 2018. "High thermal conductive paraffin/calcium carbonate phase change microcapsules based composites with different carbon network," Applied Energy, Elsevier, vol. 218(C), pages 184-191.
    5. Huanmei Yuan & Sitong Liu & Tonghe Li & Liyun Yang & Dehong Li & Hao Bai & Xiaodong Wang, 2024. "Review on Thermal Properties with Influence Factors of Solid–Liquid Organic Phase-Change Micro/Nanocapsules," Energies, MDPI, vol. 17(3), pages 1-51, January.
    6. Lin, Yaxue & Jia, Yuting & Alva, Guruprasad & Fang, Guiyin, 2018. "Review on thermal conductivity enhancement, thermal properties and applications of phase change materials in thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2730-2742.
    7. Lin, Yaxue & Zhu, Chuqiao & Alva, Guruprasad & Fang, Guiyin, 2018. "Microencapsulation and thermal properties of myristic acid with ethyl cellulose shell for thermal energy storage," Applied Energy, Elsevier, vol. 231(C), pages 494-501.
    8. He, Lijuan & Mo, Songping & Lin, Pengcheng & Jia, Lisi & Chen, Ying & Cheng, Zhengdong, 2020. "D-mannitol@silica/graphene oxide nanoencapsulated phase change material with high phase change properties and thermal reliability," Applied Energy, Elsevier, vol. 268(C).
    9. Ahmed Hassan & Mohammad Shakeel Laghari & Yasir Rashid, 2016. "Micro-Encapsulated Phase Change Materials: A Review of Encapsulation, Safety and Thermal Characteristics," Sustainability, MDPI, vol. 8(10), pages 1-32, October.
    10. Cui, Hongzhi & Tang, Waiching & Qin, Qinghua & Xing, Feng & Liao, Wenyu & Wen, Haibo, 2017. "Development of structural-functional integrated energy storage concrete with innovative macro-encapsulated PCM by hollow steel ball," Applied Energy, Elsevier, vol. 185(P1), pages 107-118.
    11. Yataganbaba, Alptug & Ozkahraman, Bengi & Kurtbas, Irfan, 2017. "Worldwide trends on encapsulation of phase change materials: A bibliometric analysis (1990–2015)," Applied Energy, Elsevier, vol. 185(P1), pages 720-731.
    12. Liu, Yang & Zheng, Ruowei & Li, Ji, 2022. "High latent heat phase change materials (PCMs) with low melting temperature for thermal management and storage of electronic devices and power batteries: Critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    13. Bashiri Rezaie, Ali & Montazer, Majid, 2019. "One-step preparation of magnetically responsive nano CuFe2O4/fatty acids/polyester composite for dynamic thermal energy management applications," Renewable Energy, Elsevier, vol. 143(C), pages 1839-1851.
    14. Jiang, Binbin & Wang, Xiaodong & Wu, Dezhen, 2017. "Fabrication of microencapsulated phase change materials with TiO2/Fe3O4 hybrid shell as thermoregulatory enzyme carriers: A novel design of applied energy microsystem for bioapplications," Applied Energy, Elsevier, vol. 201(C), pages 20-33.
    15. Siecker, J. & Kusakana, K. & Numbi, B.P., 2017. "A review of solar photovoltaic systems cooling technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 192-203.
    16. Amaral, C. & Vicente, R. & Marques, P.A.A.P. & Barros-Timmons, A., 2017. "Phase change materials and carbon nanostructures for thermal energy storage: A literature review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1212-1228.
    17. Palacios, Anabel & Cong, Lin & Navarro, M.E. & Ding, Yulong & Barreneche, Camila, 2019. "Thermal conductivity measurement techniques for characterizing thermal energy storage materials – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 32-52.
    18. Zhang, Li & Yang, Wenbin & Jiang, Zhuoni & He, Fangfang & Zhang, Kai & Fan, Jinghui & Wu, Juying, 2017. "Graphene oxide-modified microencapsulated phase change materials with high encapsulation capacity and enhanced leakage-prevention performance," Applied Energy, Elsevier, vol. 197(C), pages 354-363.
    19. Gondora, Wayne & Doudin, Khalid & Nowakowski, Daniel J. & Xiao, Bo & Ding, Yulong & Bridgwater, Tony & Yuan, Qingchun, 2016. "Encapsulation of phase change materials using rice-husk-char," Applied Energy, Elsevier, vol. 182(C), pages 274-281.
    20. Li, Songlin & Dong, Beibei & Wang, Jinghang & Li, Juan & Shen, Tongtong & Peng, Hao & Ling, Xiang, 2019. "Synthesis and characterization of mixed alkanes microcapsules with phase change temperature below ice point for cryogenic thermal energy storage," Energy, Elsevier, vol. 187(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:179:y:2016:i:c:p:601-608. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.