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Synthesis and characterization of mixed alkanes microcapsules with phase change temperature below ice point for cryogenic thermal energy storage

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  • Li, Songlin
  • Dong, Beibei
  • Wang, Jinghang
  • Li, Juan
  • Shen, Tongtong
  • Peng, Hao
  • Ling, Xiang

Abstract

The purpose of this study was to synthesize microencapsulated phase change materials (MEPCMs) with C12-C14 binary alkanes as phase change materials (PCMs) and melamine-formaldehyde resins (MF resins) as shell materials by in-situ polymerization. SDS, Span80 and Tween80 were used as the compound emulsifiers. The effects of emulsifier concentrations, core/shell ratio and compound emulsifier Hydrophilic Lipophilic Balance (HLB) value on the performance of MEPCMs were investigated. The morphology, chemical structure, thermodynamic properties and thermal stability of MEPCMs were determined by SEM, FT-IR, DSC and TGA. Results show that the emulsifier concentration and HLB value have significant impact on the MEPCMs synthesis. The emulsifier concentration of 8 wt%, HLB value of 12.15 are recommended to obtain the MEPCMs with smoother and more regular morphologies. Generally, the enthalpy and encapsulation efficiency are increasing with the increase of core/shell ratio, and the supercooling degree of MEPCMs increases by increasing the emulsifier concentration. The synthesized MEPCMs present good thermal durability and excellent cycling characteristics during the 100 thermal cycles. Moreover, they also have an appreciable thermal stability and can withstand temperatures no higher than 315 °C.

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  • Li, Songlin & Dong, Beibei & Wang, Jinghang & Li, Juan & Shen, Tongtong & Peng, Hao & Ling, Xiang, 2019. "Synthesis and characterization of mixed alkanes microcapsules with phase change temperature below ice point for cryogenic thermal energy storage," Energy, Elsevier, vol. 187(C).
    • Handle: RePEc:eee:energy:v:187:y:2019:i:c:s0360544219315762
    DOI: 10.1016/j.energy.2019.115898
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    References listed on IDEAS

    as
    1. Chai, Luxiao & Wang, Xiaodong & Wu, Dezhen, 2015. "Development of bifunctional microencapsulated phase change materials with crystalline titanium dioxide shell for latent-heat storage and photocatalytic effectiveness," Applied Energy, Elsevier, vol. 138(C), pages 661-674.
    2. Lin, Yaxue & Alva, Guruprasad & Fang, Guiyin, 2018. "Review on thermal performances and applications of thermal energy storage systems with inorganic phase change materials," Energy, Elsevier, vol. 165(PA), pages 685-708.
    3. Peng, Hao & Yang, Yu & Li, Rui & Ling, Xiang, 2016. "Thermodynamic analysis of an improved adiabatic compressed air energy storage system," Applied Energy, Elsevier, vol. 183(C), pages 1361-1373.
    4. Wang, Tingyu & Wang, Shuangfeng & Luo, Ruilian & Zhu, Chunyu & Akiyama, Tomohiro & Zhang, Zhengguo, 2016. "Microencapsulation of phase change materials with binary cores and calcium carbonate shell for thermal energy storage," Applied Energy, Elsevier, vol. 171(C), pages 113-119.
    5. He, Fang & Wang, Xiaodong & Wu, Dezhen, 2014. "New approach for sol–gel synthesis of microencapsulated n-octadecane phase change material with silica wall using sodium silicate precursor," Energy, Elsevier, vol. 67(C), pages 223-233.
    6. Peng, Hao & Shan, Xuekun & Yang, Yu & Ling, Xiang, 2018. "A study on performance of a liquid air energy storage system with packed bed units," Applied Energy, Elsevier, vol. 211(C), pages 126-135.
    7. SarI, Ahmet & Alkan, Cemil & Karaipekli, Ali, 2010. "Preparation, characterization and thermal properties of PMMA/n-heptadecane microcapsules as novel solid-liquid microPCM for thermal energy storage," Applied Energy, Elsevier, vol. 87(5), pages 1529-1534, May.
    8. Yu, Qinghua & Tchuenbou-Magaia, Fideline & Al-Duri, Bushra & Zhang, Zhibing & Ding, Yulong & Li, Yongliang, 2018. "Thermo-mechanical analysis of microcapsules containing phase change materials for cold storage," Applied Energy, Elsevier, vol. 211(C), pages 1190-1202.
    9. Kenisarin, Murat & Mahkamov, Khamid, 2007. "Solar energy storage using phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(9), pages 1913-1965, December.
    10. Sarı, Ahmet & Alkan, Cemil & Bilgin, Cahit, 2014. "Micro/nano encapsulation of some paraffin eutectic mixtures with poly(methyl methacrylate) shell: Preparation, characterization and latent heat thermal energy storage properties," Applied Energy, Elsevier, vol. 136(C), pages 217-227.
    11. She, Xiaohui & Cong, Lin & Nie, Binjian & Leng, Guanghui & Peng, Hao & Chen, Yi & Zhang, Xiaosong & Wen, Tao & Yang, Hongxing & Luo, Yimo, 2018. "Energy-efficient and -economic technologies for air conditioning with vapor compression refrigeration: A comprehensive review," Applied Energy, Elsevier, vol. 232(C), pages 157-186.
    12. Al-Shannaq, Refat & Kurdi, Jamal & Al-Muhtaseb, Shaheen & Dickinson, Michelle & Farid, Mohammed, 2015. "Supercooling elimination of phase change materials (PCMs) microcapsules," Energy, Elsevier, vol. 87(C), pages 654-662.
    Full references (including those not matched with items on IDEAS)

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