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Novel microstructured polyol–polystyrene composites for seasonal heat storage

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  • Puupponen, Salla
  • Mikkola, Valtteri
  • Ala-Nissila, Tapio
  • Seppälä, Ari

Abstract

We propose a robust route to prepare novel supercooling microstructured phase change materials (PCMs) suitable for seasonal thermal energy storage (STES) or heat protection applications. Two supercooling polyols, erythritol and xylitol, are successfully prepared as novel microencapsulated PCM-polystyrene composites with polyol mass fractions of 62wt% and 67wt%, respectively, and average void diameter of ∼50μm. Thermal properties of the composites and bulk polyols are studied thoroughly with differential scanning calorimetry (DSC) and thermal conductivity analyzer. Significant differences in heat storage properties of microstructured and bulk PCM are observed. The heat release of microstructured erythritol is more controlled than that of bulk PCM, making the novel microengineered PCMs particularly interesting for STES. In the case of bulk PCM, the heat release may occur spontaneously due to crystallization by surface roughnesses or impurities, whereas these factors have only little impact on the crystallization of microstructured erythritol, making the novel composite more reliable for long-term heat storage purposes. In addition, microstructured polyol–polystyrene composites show anomalous enhancement in the specific heat as compared to bulk polyols. This enhancement may originate from strong polyol–surfactant interactions in the composites.

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  • Puupponen, Salla & Mikkola, Valtteri & Ala-Nissila, Tapio & Seppälä, Ari, 2016. "Novel microstructured polyol–polystyrene composites for seasonal heat storage," Applied Energy, Elsevier, vol. 172(C), pages 96-106.
    • Handle: RePEc:eee:appene:v:172:y:2016:i:c:p:96-106
    DOI: 10.1016/j.apenergy.2016.03.023
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    1. Turunen, Konsta & Yazdani, Maryam Roza & Puupponen, Salla & Santasalo-Aarnio, Annukka & Seppälä, Ari, 2020. "Cold-crystallizing erythritol-polyelectrolyte: Scaling up reliable long-term heat storage material," Applied Energy, Elsevier, vol. 266(C).
    2. Englmair, Gerald & Moser, Christoph & Furbo, Simon & Dannemand, Mark & Fan, Jianhua, 2018. "Design and functionality of a segmented heat-storage prototype utilizing stable supercooling of sodium acetate trihydrate in a solar heating system," Applied Energy, Elsevier, vol. 221(C), pages 522-534.
    3. Turunen, Konsta & Mikkola, Valtteri & Laukkanen, Timo & Seppälä, Ari, 2023. "Long-term thermal energy storage prototype of cold-crystallizing erythritol-polyelectrolyte," Applied Energy, Elsevier, vol. 332(C).
    4. Shao, Xue-Feng & Wang, Chao & Yang, Yong-Jian & Feng, Biao & Zhu, Zi-Qin & Wang, Wu-Jun & Zeng, Yi & Fan, Li-Wu, 2018. "Screening of sugar alcohols and their binary eutectic mixtures as phase change materials for low-to-medium temperature latent heat storage. (Ⅰ): Non-isothermal melting and crystallization behaviors," Energy, Elsevier, vol. 160(C), pages 1078-1090.
    5. Chen, J. & Zhang, P., 2017. "Preparation and characterization of nano-sized phase change emulsions as thermal energy storage and transport media," Applied Energy, Elsevier, vol. 190(C), pages 868-879.
    6. Gianluca Coccia & Alessia Aquilanti & Sebastiano Tomassetti & Pio Francesco Muciaccia & Giovanni Di Nicola, 2021. "Experimental Analysis of Nucleation Triggering in a Thermal Energy Storage Based on Xylitol Used in a Portable Solar Box Cooker," Energies, MDPI, vol. 14(18), pages 1-21, September.

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