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Photocatalytic conversion of CO2 and CH4 over immobilized titania nanoparticles coated on mesh: Optimization and kinetic study

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  • Delavari, Saeed
  • Amin, Nor Aishah Saidina

Abstract

The study on immobilized titania (TiO2) nanoparticles semiconductor on stainless steel mesh for photocatalytic conversion of CO2 and CH4 has been investigated. Properties of commercial and calcinated photocatalysts on mesh surface were characterized using UV–vis spectra, BET, FESEM and XRD. The photoreduction products were identified with FTIR and GC. The process conditions was optimized using experimental design and process optimization tools to determine the maximum desired response via Response Surface Methodology (RSM) in conjunction with central composite rotatable design (CCRD). The experimental parameters were stainless steel mesh size, amount of titania nanoparticles, calcination temperature, UV light power and initial ratios of CO2:CH4:N2 in feed. Calcination of coated titania nanoparticles increased the absorption of UV–vis light while uniform photocatalyst structure commensurate with decreasing agglomeration. The optimal conditions for maximum CO2 conversion of 37.9% were determined as stainless steel mesh size of 140, coated titania nanoparticles on mesh of 4g, calcination temperature of 600°C, UV light power of 250W and 10% of CO2 in feed. Correspondingly, the selectivity of products were 4.7%, 4.3%, 3.9%, 41.4% and 45.7% for ethane, acetic acid, formic acid, methyl acetate and methyl formate, respectively. The kinetic model, based on Langmuir–Hinshelwood, incorporated photocatalytic adsorptive reduction and oxidation reactions over the catalyst surface, and fitted-well with the experimental data.

Suggested Citation

  • Delavari, Saeed & Amin, Nor Aishah Saidina, 2016. "Photocatalytic conversion of CO2 and CH4 over immobilized titania nanoparticles coated on mesh: Optimization and kinetic study," Applied Energy, Elsevier, vol. 162(C), pages 1171-1185.
    • Handle: RePEc:eee:appene:v:162:y:2016:i:c:p:1171-1185
    DOI: 10.1016/j.apenergy.2015.03.125
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    References listed on IDEAS

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    1. Liao, Yu-Te & Huang, Chao-Wei & Liao, Chi-Hung & Wu, Jeffery C.-S. & Wu, Kevin C.-W., 2012. "Synthesis of mesoporous titania thin films (MTTFs) with two different structures as photocatalysts for generating hydrogen from water splitting," Applied Energy, Elsevier, vol. 100(C), pages 75-80.
    2. Li, Bingyun & Duan, Yuhua & Luebke, David & Morreale, Bryan, 2013. "Advances in CO2 capture technology: A patent review," Applied Energy, Elsevier, vol. 102(C), pages 1439-1447.
    3. Chou, Chuen-Shii & Huang, Yan-Hao & Wu, Ping & Kuo, Yi-Ting, 2014. "Chemical-photo-electricity diagrams by Ohm’s law – A case study of Ni-doped TiO2 solutions in dye-sensitized solar cells," Applied Energy, Elsevier, vol. 118(C), pages 12-21.
    4. Kihara, Isanobu & Inoue, Takashi, 2002. "CO2 emissions per individual based on a survey of university students," Applied Energy, Elsevier, vol. 72(3-4), pages 645-658, July.
    5. Liu, Shou-Heng & Syu, Han-Ren, 2012. "One-step fabrication of N-doped mesoporous TiO2 nanoparticles by self-assembly for photocatalytic water splitting under visible light," Applied Energy, Elsevier, vol. 100(C), pages 148-154.
    6. Du, Kerui & Lu, Huang & Yu, Kun, 2014. "Sources of the potential CO2 emission reduction in China: A nonparametric metafrontier approach," Applied Energy, Elsevier, vol. 115(C), pages 491-501.
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