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Effects of SOC-dependent electrolyte viscosity on performance of vanadium redox flow batteries

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  • Xu, Q.
  • Zhao, T.S.
  • Zhang, C.

Abstract

The viscosity of the electrolyte in vanadium redox flow batteries (VRFBs) varies during charge and discharge as the concentrations of acid and vanadium ions in the electrolyte continuously change with the state of charge (SOC). In previous VRFB models, however, the electrolyte has been treated as a constant-viscosity solution. In this work, a mass-transport and electrochemical model taking account of the effect of SOC-dependent electrolyte viscosity is developed. The comparison between the present model and the model with the constant-viscosity simplification indicates that the consideration of the SOC-dependent electrolyte viscosity enables (i) a more realistic simulation of the distributions of overpotential and current density in the electrodes, and (ii) more accurate estimations of pumping work and the system efficiency of VRFBs.

Suggested Citation

  • Xu, Q. & Zhao, T.S. & Zhang, C., 2014. "Effects of SOC-dependent electrolyte viscosity on performance of vanadium redox flow batteries," Applied Energy, Elsevier, vol. 130(C), pages 139-147.
    • Handle: RePEc:eee:appene:v:130:y:2014:i:c:p:139-147
    DOI: 10.1016/j.apenergy.2014.05.034
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    References listed on IDEAS

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    1. Huang, Ke-Long & Li, Xiao-gang & Liu, Su-qin & Tan, Ning & Chen, Li-quan, 2008. "Research progress of vanadium redox flow battery for energy storage in China," Renewable Energy, Elsevier, vol. 33(2), pages 186-192.
    2. Xu, Q. & Zhao, T.S. & Leung, P.K., 2013. "Numerical investigations of flow field designs for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 105(C), pages 47-56.
    3. Vynnycky, M., 2011. "Analysis of a model for the operation of a vanadium redox battery," Energy, Elsevier, vol. 36(4), pages 2242-2256.
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    5. Liu, Le & Li, Zhaohua & Xi, Jingyu & Zhou, Haipeng & Wu, Zenghua & Qiu, Xinping, 2017. "Rapid detection of the positive side reactions in vanadium flow batteries," Applied Energy, Elsevier, vol. 185(P1), pages 452-462.
    6. Zhou, X.L. & Zhao, T.S. & An, L. & Zeng, Y.K. & Yan, X.H., 2015. "A vanadium redox flow battery model incorporating the effect of ion concentrations on ion mobility," Applied Energy, Elsevier, vol. 158(C), pages 157-166.
    7. Wang, Shaoliang & Xu, Zeyu & Wu, Xiaoliang & Zhao, Huan & Zhao, Jinling & Liu, Jianguo & Yan, Chuanwei & Fan, Xinzhuang, 2020. "Analyses and optimization of electrolyte concentration on the electrochemical performance of iron-chromium flow battery," Applied Energy, Elsevier, vol. 271(C).
    8. Singyuk Hou & Long Chen & Xiulin Fan & Xiaotong Fan & Xiao Ji & Boyu Wang & Chunyu Cui & Ji Chen & Chongyin Yang & Wei Wang & Chunzhong Li & Chunsheng Wang, 2022. "High-energy and low-cost membrane-free chlorine flow battery," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    9. Yang, Xiao-Guang & Ye, Qiang & Cheng, Ping & Zhao, Tim S., 2015. "Effects of the electric field on ion crossover in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 145(C), pages 306-319.
    10. Wu, Maochun & Liu, Mingyao & Long, Guifa & Wan, Kai & Liang, Zhenxing & Zhao, Tim S., 2014. "A novel high-energy-density positive electrolyte with multiple redox couples for redox flow batteries," Applied Energy, Elsevier, vol. 136(C), pages 576-581.
    11. Souentie, Stamatios & Amr, Issam & Alsuhaibani, Abdulrahman & Almazroei, Essa & Hammad, Ahmad D., 2017. "Temperature, charging current and state of charge effects on iron-vanadium flow batteries operation," Applied Energy, Elsevier, vol. 206(C), pages 568-576.
    12. Cheng, Ziqiang & Tenny, Kevin M. & Pizzolato, Alberto & Forner-Cuenca, Antoni & Verda, Vittorio & Chiang, Yet-Ming & Brushett, Fikile R. & Behrou, Reza, 2020. "Data-driven electrode parameter identification for vanadium redox flow batteries through experimental and numerical methods," Applied Energy, Elsevier, vol. 279(C).
    13. Li, Xiangrong & Xiong, Jing & Tang, Ao & Qin, Ye & Liu, Jianguo & Yan, Chuanwei, 2018. "Investigation of the use of electrolyte viscosity for online state-of-charge monitoring design in vanadium redox flow battery," Applied Energy, Elsevier, vol. 211(C), pages 1050-1059.
    14. Guarnieri, Massimo & Trovò, Andrea & Picano, Francesco, 2020. "Enhancing the efficiency of kW-class vanadium redox flow batteries by flow factor modulation: An experimental method," Applied Energy, Elsevier, vol. 262(C).

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