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Rapid detection of the positive side reactions in vanadium flow batteries

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  • Liu, Le
  • Li, Zhaohua
  • Xi, Jingyu
  • Zhou, Haipeng
  • Wu, Zenghua
  • Qiu, Xinping

Abstract

We present an optical detection method for rapid measurement of the positive side reactions in vanadium flow batteries (VFB). By measuring the transmittance of the positive electrolytes in VFB, the states of charge (SOC) of the positive electrolytes can be detected at very high resolution (better than 0.002% in the SOC range from 98% to 100%), due to the nonlinear transmittance spectra caused by the interactions between V(IV) and V(V) ions. The intensity of the positive side reactions of a VFB can be rapidly measured by a few steps, attributing to the fact that the positive side reactions occur only during the high voltage charging process. The ratios of the positive side reactions at different charge currents and different flow rates are obtained while causing no damage to the battery. This optical detection method can rapidly determine the optimal parameters of the VFB system, providing new means for studying the electrochemical reactions in the VFB system and rapid test in industrial production of VFBs.

Suggested Citation

  • Liu, Le & Li, Zhaohua & Xi, Jingyu & Zhou, Haipeng & Wu, Zenghua & Qiu, Xinping, 2017. "Rapid detection of the positive side reactions in vanadium flow batteries," Applied Energy, Elsevier, vol. 185(P1), pages 452-462.
    • Handle: RePEc:eee:appene:v:185:y:2017:i:p1:p:452-462
    DOI: 10.1016/j.apenergy.2016.10.141
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    References listed on IDEAS

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    1. Xu, Q. & Zhao, T.S. & Zhang, C., 2014. "Effects of SOC-dependent electrolyte viscosity on performance of vanadium redox flow batteries," Applied Energy, Elsevier, vol. 130(C), pages 139-147.
    2. Huamin Zhang, 2014. "Vanadium batteries will be cost-effective," Nature, Nature, vol. 508(7496), pages 319-319, April.
    3. Yang, Xiao-Guang & Ye, Qiang & Cheng, Ping & Zhao, Tim S., 2015. "Effects of the electric field on ion crossover in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 145(C), pages 306-319.
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    2. Shi, Yu & Eze, Chika & Xiong, Binyu & He, Weidong & Zhang, Han & Lim, T.M. & Ukil, A. & Zhao, Jiyun, 2019. "Recent development of membrane for vanadium redox flow battery applications: A review," Applied Energy, Elsevier, vol. 238(C), pages 202-224.
    3. Kalvin Schofield & Petr Musilek, 2022. "State of Charge and Capacity Tracking in Vanadium Redox Flow Battery Systems," Clean Technol., MDPI, vol. 4(3), pages 1-12, June.
    4. Li, Xiangrong & Xiong, Jing & Tang, Ao & Qin, Ye & Liu, Jianguo & Yan, Chuanwei, 2018. "Investigation of the use of electrolyte viscosity for online state-of-charge monitoring design in vanadium redox flow battery," Applied Energy, Elsevier, vol. 211(C), pages 1050-1059.
    5. Zhang, Yunong & Liu, Le & Xi, Jingyu & Wu, Zenghua & Qiu, Xinping, 2017. "The benefits and limitations of electrolyte mixing in vanadium flow batteries," Applied Energy, Elsevier, vol. 204(C), pages 373-381.

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