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Numerical and experimental studies of stack shunt current for vanadium redox flow battery

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  • Yin, Cong
  • Guo, Shaoyun
  • Fang, Honglin
  • Liu, Jiayi
  • Li, Yang
  • Tang, Hao

Abstract

The stack shunt current of VRB (vanadium redox flow battery) was investigated with experiments and 3D (three-dimensional) simulations. In the proposed model, cell voltages and electrolyte conductivities were calculated based on electrochemical reaction distributions and SOC (state of charge) values, respectively, while coulombic loss was estimated according to shunt current and vanadium ionic crossover through membrane. Shunt current distributions and coulombic efficiency are analyzed in terms of electrolyte conductivities and stack cell numbers. The distributions of cell voltages and shunt currents calculated with proposed model are validated with single cell and short stack tests. The model can be used to optimize VRB stack manifold and channel designs to improve VRB system efficiency.

Suggested Citation

  • Yin, Cong & Guo, Shaoyun & Fang, Honglin & Liu, Jiayi & Li, Yang & Tang, Hao, 2015. "Numerical and experimental studies of stack shunt current for vanadium redox flow battery," Applied Energy, Elsevier, vol. 151(C), pages 237-248.
    • Handle: RePEc:eee:appene:v:151:y:2015:i:c:p:237-248
    DOI: 10.1016/j.apenergy.2015.04.080
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    3. Choi, Chanyong & Kim, Soohyun & Kim, Riyul & Choi, Yunsuk & Kim, Soowhan & Jung, Ho-young & Yang, Jung Hoon & Kim, Hee-Tak, 2017. "A review of vanadium electrolytes for vanadium redox flow batteries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 69(C), pages 263-274.
    4. Zeng, Yikai & Li, Fenghao & Lu, Fei & Zhou, Xuelong & Yuan, Yanping & Cao, Xiaoling & Xiang, Bo, 2019. "A hierarchical interdigitated flow field design for scale-up of high-performance redox flow batteries," Applied Energy, Elsevier, vol. 238(C), pages 435-441.
    5. Chou, Yi-Sin & Hsu, Ning-Yih & Jeng, King-Tsai & Chen, Kuan-Hsiang & Yen, Shi-Chern, 2016. "A novel ultrasonic velocity sensing approach to monitoring state of charge of vanadium redox flow battery," Applied Energy, Elsevier, vol. 182(C), pages 253-259.
    6. Trovò, Andrea & Marini, Giacomo & Sutto, Alessandro & Alotto, Piergiorgio & Giomo, Monica & Moro, Federico & Guarnieri, Massimo, 2019. "Standby thermal model of a vanadium redox flow battery stack with crossover and shunt-current effects," Applied Energy, Elsevier, vol. 240(C), pages 893-906.
    7. Lei, Y. & Zhang, B.W. & Zhang, Z.H. & Bai, B.F. & Zhao, T.S., 2018. "An improved model of ion selective adsorption in membrane and its application in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 215(C), pages 591-601.
    8. Cheng, Ziqiang & Tenny, Kevin M. & Pizzolato, Alberto & Forner-Cuenca, Antoni & Verda, Vittorio & Chiang, Yet-Ming & Brushett, Fikile R. & Behrou, Reza, 2020. "Data-driven electrode parameter identification for vanadium redox flow batteries through experimental and numerical methods," Applied Energy, Elsevier, vol. 279(C).
    9. Chen, Hui & Li, Xiangrong & Gao, Hai & Liu, Jianguo & Yan, Chuanwei & Tang, Ao, 2019. "Numerical modelling and in-depth analysis of multi-stack vanadium flow battery module incorporating transport delay," Applied Energy, Elsevier, vol. 247(C), pages 13-23.

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