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In-situ measurement of electrode kinetics in porous electrode for vanadium flow batteries using symmetrical cell design

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  • Zhang, Kaiyue
  • Xiong, Jing
  • Yan, Chuanwei
  • Tang, Ao

Abstract

Electrode kinetics are crucial to electrochemical performance of vanadium flow battery. However, existing studies on electrode kinetics are mostly performed in ex-situ conditions based on planar electrodes, so the obtained rate constant can neither reflect the kinetics in practically used porous electrode nor be used to predict the activation polarizations of a real flow cell. To address this limitation, an in-situ measurement of electrode kinetics in porous electrode is conducted in this study by a symmetrical cell design for vanadium flow battery. For both V2+/V3+ and VO2+/VO2+ couples, the activation polarization as a function of current density is firstly acquired on the symmetrical cell through measurements of polarization curve, high frequency resistance and local mass transfer coefficient, followed by Tafel fitting that yields both rate constant and transfer coefficient. Based on kinetic parameters of both V2+/V3+ and VO2+/VO2+, the simulated full cell activation polarizations coincide well with the full cell experimental result. By further comparing to simulation results using reported kinetic parameters determined from planar electrodes, the reliability of the proposed method is further highlighted. The electrode evaluation is much more involved than Tafel polarization and stack design is not treated in this contribution.

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  • Zhang, Kaiyue & Xiong, Jing & Yan, Chuanwei & Tang, Ao, 2020. "In-situ measurement of electrode kinetics in porous electrode for vanadium flow batteries using symmetrical cell design," Applied Energy, Elsevier, vol. 272(C).
    • Handle: RePEc:eee:appene:v:272:y:2020:i:c:s030626192030605x
    DOI: 10.1016/j.apenergy.2020.115093
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    References listed on IDEAS

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    1. Zeng, Yikai & Yang, Zhifei & Lu, Fei & Xie, Yongliang, 2019. "A novel tin-bromine redox flow battery for large-scale energy storage," Applied Energy, Elsevier, vol. 255(C).
    2. Oh, Kyeongmin & Yoo, Haneul & Ko, Johan & Won, Seongyeon & Ju, Hyunchul, 2015. "Three-dimensional, transient, nonisothermal model of all-vanadium redox flow batteries," Energy, Elsevier, vol. 81(C), pages 3-14.
    3. Zeng, Yikai & Li, Fenghao & Lu, Fei & Zhou, Xuelong & Yuan, Yanping & Cao, Xiaoling & Xiang, Bo, 2019. "A hierarchical interdigitated flow field design for scale-up of high-performance redox flow batteries," Applied Energy, Elsevier, vol. 238(C), pages 435-441.
    4. Jiang, H.R. & Shyy, W. & Wu, M.C. & Zhang, R.H. & Zhao, T.S., 2019. "A bi-porous graphite felt electrode with enhanced surface area and catalytic activity for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 233, pages 105-113.
    5. Sun, J. & Jiang, H.R. & Zhang, B.W. & Chao, C.Y.H. & Zhao, T.S., 2020. "Towards uniform distributions of reactants via the aligned electrode design for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 259(C).
    6. Wang, Q. & Qu, Z.G. & Jiang, Z.Y. & Yang, W.W., 2018. "Numerical study on vanadium redox flow battery performance with non-uniformly compressed electrode and serpentine flow field," Applied Energy, Elsevier, vol. 220(C), pages 106-116.
    7. Yang, Xiao-Guang & Ye, Qiang & Cheng, Ping & Zhao, Tim S., 2015. "Effects of the electric field on ion crossover in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 145(C), pages 306-319.
    8. Jiang, H.R. & Zeng, Y.K. & Wu, M.C. & Shyy, W. & Zhao, T.S., 2019. "A uniformly distributed bismuth nanoparticle-modified carbon cloth electrode for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 240(C), pages 226-235.
    9. Xu, Q. & Zhao, T.S. & Leung, P.K., 2013. "Numerical investigations of flow field designs for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 105(C), pages 47-56.
    10. Zheng, Qiong & Zhang, Huamin & Xing, Feng & Ma, Xiangkun & Li, Xianfeng & Ning, Guiling, 2014. "A three-dimensional model for thermal analysis in a vanadium flow battery," Applied Energy, Elsevier, vol. 113(C), pages 1675-1685.
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