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Performance of a Solid Oxide Fuel Cell short-stack with biogas feeding

Author

Listed:
  • Papurello, D.
  • Borchiellini, R.
  • Bareschino, P.
  • Chiodo, V.
  • Freni, S.
  • Lanzini, A.
  • Pepe, F.
  • Ortigoza, G.A.
  • Santarelli, M

Abstract

In this study, the main sections required to produce electricity in an SOFC short stack starting from biogas were studied and tested at a lab-scale level. A test-rig including a cleaning unit, a reformer and an SOFC stack was built and used to run a test of 500h. In the plant, an in-house planar SOFC short stack (composed of three nickel based anode-supported cells) was fed by a simulated biogas mixture (60vol.% CH4, 40vol.% CO2) contaminated by 30ppmv of H2S (the main contaminant found in biogas, and deleterious for both the reformer and fuel cells). In the plant, H2S is first removed from the gas stream by adsorption in a fixed bed reactor packed with Na–X zeolites. The mixture was also passed on a ZnO guard bed (heated at 300°C) before feeding the reformer unit in order to guarantee a durable and stable operation of the same. The reformer uses a Ni-based catalyst, and was operated at ∼700°C in a mixed steam-/dry-reforming condition to produce a gas mixture suitable for the Ni-based SOFC with CH4 converted almost entirely to H2 and CO. The 3-cells short stack was operated at 800°C and 0.1Acm−2 for more than 500h. The gas analysis was performed, via a mass spectrometer, in several points of the plant. These measurements indicated that no sulfur breakthrough takes place from the zeolites bed, and furthermore that the catalyst has a quite stable behavior.

Suggested Citation

  • Papurello, D. & Borchiellini, R. & Bareschino, P. & Chiodo, V. & Freni, S. & Lanzini, A. & Pepe, F. & Ortigoza, G.A. & Santarelli, M, 2014. "Performance of a Solid Oxide Fuel Cell short-stack with biogas feeding," Applied Energy, Elsevier, vol. 125(C), pages 254-263.
    • Handle: RePEc:eee:appene:v:125:y:2014:i:c:p:254-263
    DOI: 10.1016/j.apenergy.2014.03.040
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    Citations

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    Cited by:

    1. Costas Athanasiou & Christos Drosakis & Gaylord Kabongo Booto & Costas Elmasides, 2022. "Economic Feasibility of Power/Heat Cogeneration by Biogas–Solid Oxide Fuel Cell (SOFC) Integrated Systems," Energies, MDPI, vol. 16(1), pages 1-30, December.
    2. Papurello, Davide & Lanzini, Andrea & Drago, Davide & Leone, Pierluigi & Santarelli, Massimo, 2016. "Limiting factors for planar solid oxide fuel cells under different trace compound concentrations," Energy, Elsevier, vol. 95(C), pages 67-78.
    3. Papurello, Davide & Chiodo, Vitaliano & Maisano, Susanna & Lanzini, Andrea & Santarelli, Massimo, 2018. "Catalytic stability of a Ni-Catalyst towards biogas reforming in the presence of deactivating trace compounds," Renewable Energy, Elsevier, vol. 127(C), pages 481-494.
    4. Papurello, Davide & Boschetti, Andrea & Silvestri, Silvia & Khomenko, Iuliia & Biasioli, Franco, 2018. "Real-time monitoring of removal of trace compounds with PTR-MS: Biochar experimental investigation," Renewable Energy, Elsevier, vol. 125(C), pages 344-355.
    5. Yan, Dong & Zhang, Chi & Liang, Linjiang & Li, Kai & Jia, Lichao & Pu, Jian & Jian, Li & Li, Xi & Zhang, Tao, 2016. "Degradation analysis and durability improvement for SOFC 1-cell stack," Applied Energy, Elsevier, vol. 175(C), pages 414-420.
    6. Giarola, Sara & Forte, Ornella & Lanzini, Andrea & Gandiglio, Marta & Santarelli, Massimo & Hawkes, Adam, 2018. "Techno-economic assessment of biogas-fed solid oxide fuel cell combined heat and power system at industrial scale," Applied Energy, Elsevier, vol. 211(C), pages 689-704.
    7. Silva-Mosqueda, Dulce María & Elizalde-Blancas, Francisco & Pumiglia, Davide & Santoni, Francesca & Boigues-Muñoz, Carlos & McPhail, Stephen J., 2019. "Intermediate temperature solid oxide fuel cell under internal reforming: Critical operating conditions, associated problems and their impact on the performance," Applied Energy, Elsevier, vol. 235(C), pages 625-640.
    8. Budzianowski, Wojciech M., 2016. "A review of potential innovations for production, conditioning and utilization of biogas with multiple-criteria assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 1148-1171.
    9. Xu, Han & Dang, Zheng, 2016. "Lattice Boltzmann modeling of carbon deposition in porous anode of a solid oxide fuel cell with internal reforming," Applied Energy, Elsevier, vol. 178(C), pages 294-307.
    10. Saadabadi, S. Ali & Thallam Thattai, Aditya & Fan, Liyuan & Lindeboom, Ralph E.F. & Spanjers, Henri & Aravind, P.V., 2019. "Solid Oxide Fuel Cells fuelled with biogas: Potential and constraints," Renewable Energy, Elsevier, vol. 134(C), pages 194-214.
    11. Yeo, Tze Yuen & Ashok, Jangam & Kawi, Sibudjing, 2019. "Recent developments in sulphur-resilient catalytic systems for syngas production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 100(C), pages 52-70.
    12. Habibollahzade, Ali & Gholamian, Ehsan & Behzadi, Amirmohammad, 2019. "Multi-objective optimization and comparative performance analysis of hybrid biomass-based solid oxide fuel cell/solid oxide electrolyzer cell/gas turbine using different gasification agents," Applied Energy, Elsevier, vol. 233, pages 985-1002.
    13. Barelli, L. & Bidini, G. & Cinti, G. & Gallorini, F. & Pöniz, M., 2017. "SOFC stack coupled with dry reforming," Applied Energy, Elsevier, vol. 192(C), pages 498-507.
    14. Qu, Jifa & Wang, Wei & Chen, Yubo & Deng, Xiang & Shao, Zongping, 2016. "Stable direct-methane solid oxide fuel cells with calcium-oxide-modified nickel-based anodes operating at reduced temperatures," Applied Energy, Elsevier, vol. 164(C), pages 563-571.
    15. Muhamed Rasit Atelge & Halil Senol & Mohammed Djaafri & Tulin Avci Hansu & David Krisa & Abdulaziz Atabani & Cigdem Eskicioglu & Hamdi Muratçobanoğlu & Sebahattin Unalan & Slimane Kalloum & Nuri Azbar, 2021. "A Critical Overview of the State-of-the-Art Methods for Biogas Purification and Utilization Processes," Sustainability, MDPI, vol. 13(20), pages 1-39, October.
    16. Abdelkareem, Mohammad Ali & Tanveer, Waqas Hassan & Sayed, Enas Taha & Assad, M. El Haj & Allagui, Anis & Cha, S.W., 2019. "On the technical challenges affecting the performance of direct internal reforming biogas solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 361-375.
    17. Mehr, A.S. & Gandiglio, M. & MosayebNezhad, M. & Lanzini, A. & Mahmoudi, S.M.S. & Yari, M. & Santarelli, M., 2017. "Solar-assisted integrated biogas solid oxide fuel cell (SOFC) installation in wastewater treatment plant: Energy and economic analysis," Applied Energy, Elsevier, vol. 191(C), pages 620-638.
    18. Lee, Sanghyeok & Park, Mansoo & Kim, Hyoungchul & Yoon, Kyung Joong & Son, Ji-Won & Lee, Jong-Ho & Kim, Byung-Kook & Choi, Wonjoon & Hong, Jongsup, 2017. "Thermal conditions and heat transfer characteristics of high-temperature solid oxide fuel cells investigated by three-dimensional numerical simulations," Energy, Elsevier, vol. 120(C), pages 293-305.
    19. Facci, Andrea L. & Cigolotti, Viviana & Jannelli, Elio & Ubertini, Stefano, 2017. "Technical and economic assessment of a SOFC-based energy system for combined cooling, heating and power," Applied Energy, Elsevier, vol. 192(C), pages 563-574.
    20. Davide Papurello & Massimo Santarelli & Sonia Fiorilli, 2018. "Physical Activation of Waste-Derived Materials for Biogas Cleaning," Energies, MDPI, vol. 11(9), pages 1-12, September.
    21. Papurello, Davide & Lanzini, Andrea & Leone, Pierluigi & Santarelli, Massimo, 2016. "The effect of heavy tars (toluene and naphthalene) on the electrochemical performance of an anode-supported SOFC running on bio-syngas," Renewable Energy, Elsevier, vol. 99(C), pages 747-753.

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